Phthalic acid diamide derivatives, fluorine-containing aniline compounds as starting material, agricultural and horticultural insecticides, and a method for application of the insecticides

ABSTRACT

The present invention provides a phthalic acid diamide derivative represented by the general formula (I)  
                 
 
     (wherein R 1 , R 2  and R 3  are each H, C 3 -C 6  cycloalkyl group, group of the formula -A 1 -Q l  or the like; X may be the same or different and are each halogen atom, nitro group, phenyl group, group of the formula -A 2 -R 7  or the like; n is 1 to 4; Y may be same or different and are each halogen atom, cyano group, phenyl group, group of the formula -A 2 -R 7  or the like; m is 1 to 5; Z 1  and Z 2  are each O or S), fluorine-containing aniline compound represented by the general formula (ST-I) as starting material for said phthalic acid diamide derivative  
                 
 
     (wherein R a  is halogen atom, C 1 -C 6  alkyl group or the like and R b , R c  and R d  is H or C 2 -C 6  perfluoroalkyl group), and an agricultural and horticultural insecticide containing said phthaldiamide derivative, as well as to provide a method for use of said insecticide. The agricultural and horticultural insecticides of the present invention show excellent activities for controlling injurious insects.

CROSS-REFERENCE TO RELATED APPLICATION

[0001] This application is a continuation-in-part application of earlierU.S. application Ser. No. 09/198,391 filed Nov. 24, 1998 of whichcontents are all incorporated herein by reference.

BACKGROUND OF THE INVENTION

[0002] 1. Field of the Invention

[0003] The present invention relates to phthalic acid diamidederivatives, fluorine-containing aniline compounds as starting materialfor said derivative, agricultural and horticultural insecticidescontaining said derivative as an active ingredient, and a method forapplication of the insecticides.

[0004] 2. Related Art

[0005] Japanese Patent Application Nos. 59-163353 and 61-180753 and J.C. S. Perkin I, 1338-1350, (1978), etc. disclose some of the phthalicacid diamide derivatives of the present invention but neither describenor suggest their usefulness as agricultural and horticulturalinsecticides. JP-A-63-99046 and JP-A-6-184065 describe the fact thatanilines similar to the fluorine-containing aniline compound of thepresent invention are useful as intermediates of benzoylurea typeinsecticides.

SUMMARY OF THE INVENTION

[0006] The present inventors earnestly studied in order to develop anovel agricultural and horticultural insecticide, and consequently foundthat the phthalic acid diamide derivatives represented by the generalformula (I) of the present invention are novel compounds not known asagricultural and horticultural insecticides in any literature and thatsaid derivatives including the compounds disclosed in the abovereferences can be used for a new purpose as agricultural andhorticultural insecticides. Further, the present inventors found thatthe fluorine-containing aniline compounds represented by the generalformula (ST-I) of the present invention are novel compounds which havenot been known in any literature and is useful as an intermediate of amedicine, agrochemical, chemical product etc. In particular, they foundthat the fluorine-containing aniline compound of the general formula(ST-I) is useful as a starting material for the agricultural andhorticultural insecticide containing the phthalic acid diamidederivative of the general formula (I) as an active ingredient. Thus, thepresent invention has been accomplished.

DETAILED DESCRIPTION OF THE INVENTION

[0007] The present invention relates to phthalic acid diamidederivatives of the general formula (I),

[0008] wherein R¹, R² and R³ may be the same or different, and are eacha hydrogen atom, a cyano group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₃-C₆ cycloalkenyl group, a halo-C₃-C₆ cycloalkenylgroup or a group of the formula -A¹-Q_(l) (wherein A¹ is —O—, —S—,—SO₂—, —C(═O)—, a group of the formula —N(R⁴)— (wherein R⁴ is a C₁-C₆alkyl-carbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, or a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different, and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different), a C₁-C₈ alkylene group, a C₃-C₆ alkenylene groupor a C₃-C₆ alkynylene group;

[0009] (1) when A¹ is —O— or a group of the formula —N(R⁴)— (wherein R⁴is the same as defined above), then Q is a hydrogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆alkenyl group, a C₃-C₆ alkynyl group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkyl sulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenyl-C₁-C₄ alkyl group or a substitutedphenyl-C₁-C₄ alkyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different;

[0010] (2) when A¹ is —S—, —SO₂— or —C(═O)—, then Q is a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆alkenyl group, a C₃-C₆ alkynyl group, a C₁-C₆ alkoxy group, a mono-C₁-C₆alkylamino group, a di-C₁-C₆ alkylamino group which may be the same ordifferent, a C₁-C₆ alkoxycarbonylamino group, a C₁-C₆alkoxycarbonyl-C₁-C₆ alkylamino group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenylamino group, a substituted phenylaminogroup having at least one substituent, in the phenyl ring, which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydro-furylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or a pyrazolyl group), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different,

[0011] (3) when A¹ is a C₁-C₈ alkylene group, a C₃-C₆ alkenylene groupor a C₃-C₆ alkynylene group, then Q is a hydrogen atom, a halogen atom,a cyano group, a nitro group, a halo-C₁-C₆ alkyl group, a C₃-C₆cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxycarbonylgroup, a di-C₁-C₆ alkoxyphosphoryl group which may be the same ordifferent, a di-C₁-C₆ alkoxythiophosphoryl group which may be the sameor different, a diphenylphosphino group, a diphenyl-phosphono group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -Z³-R⁵ (wherein Z³ is—O—, —S—, —SO—, —SO₂— or a group of the formula —N(R⁶)— (wherein R⁶ is ahydrogen atom, a C₁-C₆ alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonylgroup, a C₁-C₆ alkoxycarbonyl group, a phenylcarbonyl group, asubstituted phenylcarbonyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenyl C₁-C₄ alkoxycarbonyl group, or asubstituted phenyl C₁-C₄ alkoxycarbonyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different); and

[0012] R⁵ is a hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenyl group, a C₃-C₆alkynyl group, a halo-C₃-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkylcarbonyl group, a halo C₁-C₆alkylcarbonyl group, a C₁-C₆ alkoxycarbonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenyl C₁-C₄ alkyl group, a substituted phenylC₁-C₄ alkyl group having at least one substituent, in the phenyl ring,which may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkysulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different);

[0013] l is an integer of 1 to 4); further,

[0014] R¹ and R² may form a 4 to 7 membered ring by combining to eachother, in which the ring may contain the same or different 1 to 3 heteroatoms selected from the group consisting of oxygen atom, sulfur atom andnitrogen atom;

[0015] X may be the same or different, and is a hydrogen atom, a halogenatom, a cyano group, a nitro group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenyl grouphaving at least one substituents which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkysulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a naphthyl group, a substituted naphthyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined the above), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A²-R⁷ (wherein A² is—O—, —S—, —SO—, —SO₂—, —C(═O)—, —C(═NOR⁸)— (wherein R⁸ is a hydrogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenylgroup, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a C₃-C₆cycloalkyl group, a phenyl-C₁-C₄ alkyl group, or a substitutedphenyl-C₁-C₄ alkyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different), a C₁-C₆alkylene group, a halo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, ahalo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆alkynylene group;

[0016] (1) when A² is —O—, —S—, —SO— or —SO₂—, then R⁷ is a hydrogenatom, a C₁-C₆ alkyl group, a halo C₁-C₆ alkyl group, a C₃-C₆ alkenylgroup, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a halo-C₃-C₆alkynyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group,a C₃-C₆ cycloalkenyl group, a halo-C₃-C₆ cycloalkenyl group, a di-C₁-C₆alkoxy-phosphoryl group which may be the same or different, a di-C₁-C₆alkoxythiophosphoryl group which may be the same or different, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),a substituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituents which may be thesame or different and are selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆-alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A³-R⁹ (wherein A³ is—C(═O)—, —SO₂—, a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₃-C₆alkynylene group or a halo-C₃-C₆ alkynylene group,

[0017] (i) when A³ is —C(═O)— or —SO₂—, then R⁹ is a C₁-C₆ alkyl group,a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a mono-C₁-C₆ alkylaminogroup, a di-C₁-C₆ alkylamino group which may be the same or different, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined the above) having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkyl- thio group, a C₁-C₆ alkysulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and a di-C₁-C₆alkylamino group which may be the same or different,

[0018] (ii) when A³ is a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylenegroup, a C₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₃-C₆alkynylene group or a halo-C₃-C₆ alkynylene group, then R⁹ is a hydrogenatom, a halogen atom, a cyano group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A⁴-R¹⁰ (wherein A⁴ is—O—, —S—, —SO—, —SO₂—, —C(═O)—, or a group of the formula —N(R¹¹)—(wherein R¹¹ is a hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a C₃-C₆ cyclo-alkylgroup, a phenyl group, a substituted phenyl group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different); and

[0019] R¹⁰ is a hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenyl group, a C₃-C₆alkynyl group, a halo-C₃-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a C₃-C₆ cycloalkenyl group, a halo-C₃-C₆cycloalkenyl group, a phenyl group, a substituted phenyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined the above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined the above) having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different));

[0020] (2) when A² is —C(═O)— or a group of the formula —C(═NOR⁸)—(wherein R⁸ is the same as defined above), then R⁷ is a C₁-C₆ alkylgroup, a halo C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆alkenyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group,a C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a mono-C₁-C₆ alkylaminogroup, a di-C₁-C₆ alkylamino group which may be the same or different, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aphenylamino group, a substituted phenylamino group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkysulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having one or more substituentswhich may be the same or different and are selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different,

[0021] (3) when A2 is a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylenegroup, C₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group or a halo-C₃-C₆ alkynylene group, then R⁷ is a hydrogenatom, a halogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkylgroup, a C₁-C₆ alkoxycarbonyl group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),a substituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A⁵-R¹² (wherein A⁵ is—O—, —S—, —SO—, —SO₂— or a group of the formula —N(R¹³ )— (wherein R¹³is a hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituents which may be thesame or different and are selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different); and R¹² is a hydrogen atom, a C₃-C₆ cycloalkylgroup, a halo-C₃-C₆ cycloalkyl group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a naphthyl group, a substituted naphthyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituents which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A⁶-R¹⁴ (wherein A⁶ is—C(═O)—, —SO₂—, a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group or a halo-C₃-C₆ alkynylene group;

[0022] (i) when A⁶ is —C(═O)— or —SO₂—, then R¹⁴ is a C₁-C₆ alkyl group,a halo-C₁-C₆ alkyl group, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a naphthyl group, a substituted naphthyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined the above) having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different;

[0023] (ii) when A⁶ is a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylenegroup, a C₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group or a halo-C₃-C₆ alkynylene group, then R¹⁴ is ahydrogen atom, a halogen atom, a cyano group, a C₃-C₆ cycloalkyl group,a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a C₁-C₆alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and areselected from the group consisting of a halogen atom, a cyano group, anitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a phenoxy group, a substituted phenoxy group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aphenylthio group, a substituted phenylthio group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆-alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different)));

[0024] n is an integer of 1 to 4;

[0025] further, X may form a condensed ring (which means naphthalene,tetrahydronaphthalene, indene, indane, quinoline, quinazoline, chroman,isochroman, indole, indoline, benzodioxane, benzodioxole, benzofuran,dihydrobenzofuran, benzothiophene, dihydrobenzothiophene, benzoxazole,benzothiazole, benzimidazole or indazole), by combining together withthe adjacent carbon atoms in the phenyl ring, and said condensed ringmay have at least one substituents, which may be the same or different,and selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group, a di-C₁-C₆ alkylamino group which may be the same ordifferent, a phenyl group, a substituted phenyl group having at leastone substituent which may be the same or different and is selected fromthe group consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), and asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo- C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different;

[0026] Y is the same or different, and is a hydrogen atom, a halogenatom, a cyano group, a nitro group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a di-C₁-C₆ alkoxyphosphoryl group which maybe the same or different, a di-C₁-C₆ alkoxythiophosphoryl group whichmay be the same or different, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a naphthyl group, a substituted naphthyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined the above), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A²-R⁷ (wherein A² andR⁷ are the same as defined above);

[0027] m is an integer of 1 to 5;

[0028] further, Y may form a condensed ring (the condensed ring is thesame as defined above), by combining together with the adjacent carbonatoms in the phenyl ring, said condensed ring may have at least onesubstituents, which may be the same or different, and selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group, adi-C₁-C₆ alkylamino group which may be the same or different, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),and a substituted heterocyclic group (wherein said heterocyclic group isthe same as defined above) having at lease one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different;

[0029] Z¹ and Z² are each represents an oxygen atom or a sulfur atom;provided that,

[0030] (1) when X, R¹ and R³ are hydrogen atoms at the same time; m isan integer of 2; Y at 2-position is a fluorine atom and Y at 3-positionis a chlorine atom; then R² is not ethyl group, isopropyl group,cyclohexyl group, 2-propenyl group, methylthiopropyl group anda-methylbenzyl group,

[0031] (2) when X and R³ are hydrogen atoms at the same time; m is aninteger of 2; Y at 2-position is a fluorine atom and Y at 3-position isa chlorine atom; then the 4 to 7 membered ring by combining R¹ and R³ toeach other, in which the ring may contain the same or different 1 to 3hetero atoms selected from the group consisting of oxygen atom, sulfuratom and nitrogen atom is not morpholino group,

[0032] (3) when X, R¹ and R³ are hydrogen atoms at the same time; and R²is 1,2,2-trimethylpropyl group; then Y is not a hydrogen atom,

[0033] (4) when X, R¹ and R³ are hydrogen atoms at the same time; R² is2,2-dimethylpropyl group; and m is an integer of 1; then Y is not2-ethoxy group, and

[0034] (5) when X, R¹ and R³ are hydrogen atoms at the same time; and R²is tert-butyl group group; and m is an integer of 1; then Y is not4-chlorine atom, 2-nitro group, 4-nitro group, 3-methoxy group,4-methoxy group and 2,6-dimethyl groups;

[0035] fluorine-containing aniline compounds represented by the generalformula (ST-I) as starting material for the phthalic acid diamidederivatives:

[0036] (wherein R^(a) is a halogen atom, a C₁-C₆ alkyl group, a C₁-C₆alkoxy group or a trifluoromethyl group, and each of R^(b), R^(c) andR^(d) is a hydrogen atom or a C₂-C₆ perfluoroalkyl group, provided thatat least one of R^(b), R^(c) and R^(d) is not a hydrogen atom and thatR^(c) is neither a pentafluoroethyl group nor a n-heptafluoropropylgroup when R^(a) is a fluorine atom and each of R^(b) and R^(d) is ahydrogen atom);

[0037] agricultural and horticultural insecticides containing as anactive ingredient any of the phthalic acid diamide derivatives of thegeneral formula (I) including known compounds; and a method forapplication of the insecticides.

[0038] In the definition of the general formula (I) representing thephthalic acid diamide derivative of the present invention, the halogenatom includes chlorine atom, bromine atom, iodine atom and fluorineatom. The term “C₁-C₆ alkyl” means a linear or branched alkyl group of 1to 6 carbon atoms, such as methyl, ethyl, n-propyl, i-propyl, n-butyl,i-butyl, s-butyl, t-butyl, n-pentyl, n-hexyl, or the like. The term“C₁-C₈ alkylene” means a linear or branched alkylene group of 1 to 8carbon atoms, such as methylene, ethylene, propylene, trimethylene,dimethylmethylene, tetramethylene, i-butylene, dimethylethylene,pentamethylene, hexamethylene, heptamethylene, octamethylene or thelike. The term “halo-C₁-C₆ alkyl” means a substituted and linear orbranched alkyl group of 1 to 6 carbon atoms having as the substituent(s)one or more halogen atoms which may be the same or different.

[0039] As the ring which R¹ and R² form by combining to each other,i.e., the 4- to 7-membered ring by combining to each other, in which thering may contain the same or different 1 to 3 hetero atoms selected fromthe group consisting of oxygen atom, sulfur atom and nitrogen atom,there can be exemplified azetidine ring, pyrrolidine ring, pyrrolinering, piperidine ring, imidazolidine ring, imidazoline ring, oxazolidinering, thiazolidine ring, isoxazolidine ring, isothiazolidine ring,tetrahydropyridine ring, piperazine ring, morpholine ring,thiomorpholine ring, dioxazine ring, dithiazine ring, etc.

[0040] The phthalic acid diamide derivative of the general formula (I)of the present invention contains an asymmetric carbon atom or someasymmetric center in the structural formula in some cases or has twooptical isomers in some cases. The present invention includes theseoptical isomers and all mixtures containing the optical isomers inarbitrary proportions.

[0041] Preferable examples of each substituent of the phthalic aciddiamide derivative of the general formula (I) of the present inventionare as follows. Preferable examples of each of R¹ and R² which may bethe same or different are hydrogen atom, C₁-C₆ alkyl groups such asmethyl, ethyl, i-propyl, etc. Preferable examples of R³ are hydrogenatom, and C₁-C₆ alkyl groups such as methyl, ethyl, n-propyl, i-propyl,n-butyl, etc. Preferable examples of X are halogen atoms, nitro group,halo-C₁-C₆ alkyl groups, halo-C₁-C₆ alkoxy groups, halo-C₁-C₆ alkylthiogroups, etc. Preferable examples of Y are halo-C₁-C₆ alkyl groups,halo-C₁-C₆ alkoxy groups, halo-C₁-C₆ alkylthio groups, etc.

[0042] The phthalic acid diamide derivative of the general formula (I)of the present invention can be produced, for example, by any of theprocesses illustrated below.

Production Process 1

[0043]

[0044] wherein R¹, R², X, n, Y and m are as defined above.

[0045] A phthalic anhydride derivative of the general formula (V) isreacted with an aniline of the general formula (IV) in the presence ofan inert solvent to obtain a phthalimide derivative of the generalformula (III). The phthalimide derivative (III) is reacted with an amineof the general formula (II) after or without being isolated, whereby aphthalic acid diamide derivative of the general formula (I-1) can beproduced.

General formula (V)→general formula (III)  (1)

[0046] As the inert solvent used in this reaction, any solvent may beused so long as it does not markedly inhibit the progress of thereaction. There can be exemplified aromatic hydrocarbons such asbenzene, toluene, xylene, etc.; halogenated hydrocarbons such asdichloromethane, chloroform, carbon tetrachloride, etc., chlorinatedaromatic hydrocarbons such as chlorobenzene, dichlorobenzene, etc.; acyclic or cyclic ethers such as diethyl ether, dioxane, tetrahydrofuran,etc., esters such as ethyl acetate, etc.; amides such asdimethylformamide, dimethylacetamide, etc.; acids such as acetic acid,etc.; dimethyl sulfoxide; and 1,3-dimethyl-2-imidazolidinone. Theseinert solvents may be used alone or as a mixture thereof.

[0047] Since the reaction is an equimolar reaction, it is sufficientthat the reactants are used in equimolar amounts, though either of themmay be used in excess. If necessary, the reaction may be carried outunder dehydrating conditions.

[0048] As to the reaction temperature, the reaction can be carried outin a temperature range of room temperature to the reflux temperature ofthe inert solvent used. Although the reaction time is varied dependingon the scale of reaction, the reaction temperature, etc., it may beproperly chosen in a range of several minutes to 48-hours.

[0049] After completion of the reaction, the desired compound isisolated from the reaction solution containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beproduced. The desired compound can be subjected to the subsequentreaction without isolation from the reaction solution.

[0050] The phthalic anhydride derivative of the general formula (V) canbe produced by the process described in J. Org. Chem., 52, 129 (1987),J. Am. Chem. Soc., 51, 1865 (1929), J. Am. Chem. Soc., 63, 1542 (1941),etc. The aniline of the general formula (IV) can be produced by theprocess described in J. Org. Chem., 29, 1 (1964), Angew. Chem. Int. Ed.Engl., 24, 871 (1985), Synthesis, 1984, 667, Bulletin of the ChemicalSociety of Japan, 1973, 2351, DE-2606982, JP-A-1-90163, etc.

General formula (III)→general formula (I-1)  (2)

[0051] In this reaction, there can be used the inert solventsexemplified above as the inert solvent used in the reaction (1).

[0052] Since the reaction is an equimolar reaction, it is sufficientthat the reactants are used in equimolar amounts, though the amine ofthe general formula (II) may be used in excess.

[0053] As to the reaction temperature, the reaction can be carried outin a temperature range of room temperature to the reflux temperature ofthe inert solvent used. Although the reaction time is varied dependingon the scale of reaction, the reaction temperature, etc., it may beproperly chosen in a range of several minutes to 48 hours.

[0054] After completion of the reaction, the desired compound isisolated from the reaction solution containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beproduced.

Production Process 2

[0055]

[0056] wherein R¹, R², n, X, Y and m are as defined above, and X′ is ahalogen atom or a nitro group, provided that X is other than a hydrogenatom or a nitro group.

[0057] A phthalimide derivative of the general formula (III-1) isreacted with a reactant corresponding to X in the presence of an inertsolvent to obtain a phthalimide derivative of the general formula (III).The phthalimide derivative (III) is reacted with an amine of the generalformula (II) after or without being isolated, whereby a phthalic aciddiamide derivative of the general formula (I-1) can be produced.

General formula (III-1)→general formula (III)  (1)

[0058] This reaction can be carried out according to the methodsdescribed in J. Org. Chem., 42, 3415 (1977), Tetrahedron, 25, 5921(1969), Synthesis, 1984, 667, Chem. Lett., 1973, 471, J. Org. Chem., 39,3318 (1974), J. Org. Chem., 39, 3327 (1974), etc.

General formula (III)→general formula (I-1)  (2)

[0059] This reaction can be carried out according to production process1-(2).

Production Process 3

[0060]

[0061] wherein R¹, R², X, Y, m and n are as defined above.

[0062] A phthalic anhydride of the general formula (V-1) is reacted withan aniline of the general formula (IV) in the presence of an inertsolvent to obtain a phthalimide derivative of the general formula(III-2). The phthalimide derivative (III-2) is subjected to catalyticreduction with hydrogen after or without isolation to obtain aphthalimide derivative of the general formula (III-3). The phthalimidederivative (III-3) is converted to a phthalimide derivative of thegeneral formula (III) by adding a diazotizing agent and then a metalsalt after or without isolation of the phthalimide derivative (III-3).The phthalimide derivative (III) is reacted with an amine of the generalformula (II) after or without being isolated, whereby a phthalic aciddiamide derivative of the general formula (I-1) can be produced.

General formula (V-1)→general formula (III-2)  (1)

[0063] The desired compound can be produced by this reaction in the samemanner as in production process I-(1).

General formula (III-2)→general formula (III-3)  (2)

[0064] Any solvent may be used in this reaction so long as it does notmarkedly inhibit the progress of the reaction. There can be exemplifiedalcohols such as methanol, ethanol, propanol, etc.; acyclic or cyclicethers such as diethyl ether, dioxane, tetrahydrofuran, etc., and acidssuch as acetic acid, etc. These inert solvents may be used alone or as amixture thereof.

[0065] As the catalyst for catalytic reduction used in this reaction,there can be exemplified palladium carbon, Raney nickel, palladiumblack, platinum black, etc. The amount of the catalyst used may beproperly chosen in a range of 0.1 to 10% by weight based on the weightof the phthalimide derivative of the general formula (III-2). Thisreaction is carried out under a hydrogen atmosphere and the hydrogenpressure may be properly chosen in a range of 1 to 10 atmosphericpressure.

[0066] As to the reaction temperature, the reaction can be carried outin a temperature range of room temperature to the reflux temperature ofthe inert solvent used. Although the reaction time is varied dependingon the scale of reaction, the reaction temperature, etc., it may beproperly chosen in a range of several minutes to 48 hours.

[0067] After completion of the reaction, the desired compound isisolated from the reaction mixture containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beproduced. The desired compound can be subjected to the subsequentreaction without isolation from the reaction mixture.

General formula (III-3)→general formula (III)  (3)

[0068] In this reaction, an acidic solvent can be used as an inertsolvent. The acidic solvent includes, for example, an aqueoushydrochloric acid solution, an aqueous hydrobromic acid solution, anaqueous hydroiodic acid solution, an aqueous sulfuric acid solution,acetic acid and trifluoroacetic acid. These acidic solvents may be usedalone or as a mixture thereof. In addition, these acidic solvents may beused in admixture with ethers such as tetrahydrofuran, dioxane, etc.

[0069] The diazotizing agent includes, for example, sodium nitrite,nitrosyl hydrogensulfate and alkyl nitrites. The amount of thediazotizing agent used may be properly chosen in a range of equal amountto excess amount relative to the amount of the phthalimide derivative ofthe general formula (III-3).

[0070] As to the reaction temperature, the reaction can be carried outin a temperature range of −50° C. to the ref lux temperature of theinert solvent used. Although the reaction time is varied depending onthe scale of reaction, the reaction temperature, etc., it may beproperly chosen in a range of several minutes to 48 hours.

[0071] As the metal salt added after the production of a diazonium salt,there can be used, for example, cuprous chloride, cuprous bromide,potassium iodide, copper cyanide, potassium xanthate and sodiumthiorate. The amount of the metal salt used may be properly chosen in arange of 1 equivalent to excess equivalents per equivalent of thephthalimide derivative of the general formula (III-3).

[0072] After completion of the reaction, the desired compound isisolated from the reaction mixture containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beproduced. The desired compound can be subjected to the subsequentreaction without isolation from the reaction mixture.

[0073] The reaction can be carried out according to the method describedin Org. Synth., IV, 160 (1963), org. Synth., III, 809 (1959), J. Am.Chem. Soc., 92, 3520 (1970), etc.

General formula (III)→general formula (I-1)  (4)

[0074] The desired compound can be produced by this reaction in the samemanner as in production process 1-(2).

Production Process 4

[0075]

[0076] wherein R¹, R², X, Y, m and n are as defined above.

[0077] A phthalimide derivative of the general formula (III-2) isreacted with an amine of the general formula (II) in the presence of aninert solvent to obtain a phthalic acid diamide derivative of thegeneral formula (I-3). The phthalic acid diamide derivative (I-3) issubjected to catalytic reduction with hydrogen after or withoutisolation to obtain a phthalic acid diamide derivative of the generalformula (I-2). A phthalic acid diamide derivative of the general formula(I-1) can be produced from the phthalic acid diamide derivative (I-2) byadding a diazotizing agent and then a metal salt after or withoutisolating the phthalic acid diamide derivative (I-2).

General formula (III-2)→general formula (I-3)  (1)

[0078] The desired compound can be produced by this reaction in the samemanner as in production process 1-(2).

General formula (I-3)→general formula (I-2)  (2)

[0079] The desired compound can be produced by this reaction in the samemanner as in production process 3-(2).

General formula (1-2)→general formula (I-1)  (3)

[0080] The desired compound can be produced by this reaction in the samemanner as in production process 3-(3).

Production Process 5

[0081]

[0082] wherein R¹, R², R³, X, n, Y and m are as defined above.

[0083] A phthalic anhydride derivative of the general formula (V) isreacted with an amine of the general formula (II) in the presence of aninert solvent to obtain a phthalamide of the general formula (III-4).The phthalamide (III-4) is treated as follows after or withoutisolation. When R² of the phthalamide (III-4) is a hydrogen atom, thephthalamide (III-4) is condensed into a compound of the general formula(VI) in the presence of a condensing agent, and the compound (VI) isreacted with an aniline of the general formula (IV) in the presence ofan inert solvent after or without being isolated. When R² of thephthalamide (III-4) is other than a hydrogen atom, the phthalamide(III-4) is condensed with an aniline of the general formula (IV) in thepresence of a condensing agent. Thus, a phthalic acid diamide derivativeof the general formula (I) can be produced.

[0084] Alternatively, a phthalic anhydride derivative of the generalformula (V) is reacted with an aniline of the general formula (IV) inthe presence of an inert solvent to obtain a phthalanilide of thegeneral formula (III-5). The phthalanilide (III-5) is treated as followsafter or without isolation. When R³ of the phthalanilide (III-5) is ahydrogen atom, the phthalanilide (III-5) is condensed into a compound ofthe general formula (VI-1) in the presence of a condensing agent, andthe compound (VI-1) is reacted with an amine of the general formula (II)in the presence of an inert solvent after or without being isolated.When R³ of the phthalanilide (III-5) is other than a hydrogen atom, thephthalanilide (III-5) is condensed with an amine of the general formula(II) in the presence of a condensing agent. Thus, a phthalic aciddiamide derivative of the general formula (I) can be produced.

General formula (V) or general formula (VI-1)→general formula (III-4) orgeneral formula (I), respectively  (1)

[0085] The desired compound can be produced by this reaction in the samemanner as in production process 1-(2).

General formula (III-4) or general formula (III-5)→general formula (VI)or general formula (VI-1), respectively  (2)

[0086] The desired compound can be produced by this reaction accordingto the method described in J. Med. Chem., 10, 982 (1967).

General formula (VI) or general formula (V)→general formula (I) orgeneral formula (III-5), respectively  (3)

[0087] The desired compound can be produced by this reaction in the samemanner as in production process 1-(2).

General formula (III-4) or general formula (III-5)→general formula(I)  (4)

[0088] The desired compound can be produced by reacting the phthalamidederivative of the general formula (III-4) or the general formula (III-5)with the aniline of the general formula (IV) or the amine of the generalformula (II), respectively, in the presence of a condensing agent and aninert solvent. If necessary, the reaction can be carried out in thepresence of a base.

[0089] The inert solvent used in the reaction includes, for example,tetrahydrofuran, diethyl ether, dioxane, chloroform and dichloromethane.As the condensing agent used in the reaction, any condensing agent maybe used so long as it is used in usual amide synthesis. The condensingagent includes, for example, Mukaiyama reagent (e.g.2-chloro-N-methylpyridinium iodide), 1,3-dicyclohexylcarbodiimide (DCC),carbonyldiimidazole (CDI) and diethyl phosphorocyanidate (DEPC). Theamount of the condensing agent used may be properly chosen in a range of1 mole to excess moles per mole of the phthalamide derivative of thegeneral formula (III-4) or the general formula (III-5).

[0090] As the base usable in the reaction, there can be exemplifiedorganic bases such as triethylamine, pyridine, etc. and inorganic basessuch as potassium carbonate, etc. The amount of the base used may beproperly chosen in a range of 1 mole to excess moles per mole of thephthalamide derivative of the general formula (III-4) or the generalformula (III-5).

[0091] As to the reaction temperature, the reaction can be carried outin a temperature range of 0° C. to the boiling point of the inertsolvent used. Although the reaction time is varied depending on thescale of reaction, the reaction temperature, etc., it ranges fromseveral minutes to 48 hours.

[0092] After completion of the reaction, the desired compound isisolated from the reaction solution containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beproduced.

Production Process 6

[0093]

[0094] wherein R¹, R², X, n, Y and m are as defined above, Hal is ahalogen atom, and R¹⁵ is a (C₁-C₃)alkyl group.

[0095] A phthalic acid ester derivative of the general formula (VII) ishalogenated into a phthaloyl halide of the general formula (VII-1) inthe presence or absence of an inert solvent. The phthaloyl halide(VII-1) is reacted with an aniline of the general formula (IV) in thepresence of an inert solvent and a base after or without being isolated,to obtain a phthalanilide of the general formula (III-6). Thephthalanilide (III-6) is hydrolyzed into a phthalanilide of the generalformula (III-5) in the presence or absence of an inert solvent after orwithout being isolated. The phthalanilide (III-5) is condensed into aphthalic anhydride derivative of the general formula (VI-1)-after orwithout being isolated. The phthalic anhydride derivative (VI-1) isreacted with an amine of the general formula (II), whereby a phthalicacid diamide derivative of the general formula (I-1) can be produced.

General formula (VII)→general formula (VII-1)  (1)

[0096] As the inert solvent usable in this reaction, any solvent may beused so long as it does not markedly inhibit the progress of thereaction. There can be exemplified aromatic hydrocarbons such asbenzene, toluene, xylene, etc.; halogenated hydrocarbons such asdichloromethane, chloroform, carbon tetrachloride, etc., chlorinatedaromatic hydrocarbons such as chlorobenzene, dichlorobenzene, etc.;acyclic or cyclic ethers such as diethyl ether, dioxane,tetrahydrofuran, etc., and esters such as ethyl acetate, etc. Theseinert solvents may be used alone or as a mixture thereof.

[0097] As the halogenating agents, there can be used, for example,thionyl chloride, phosphoryl chloride, and phosphorus trichloride. Theamount of the halogenating agent used may be properly chosen in a rangeof 1 to 10 equivalents per equivalent of the phthalic acid ester of thegeneral formula (VII).

[0098] As to the reaction temperature, the reaction can be carried outin a temperature range of 0° C. to the ref lux temperature of the inertsolvent used. Although the reaction time is varied depending on thescale of reaction, the reaction temperature, etc., it may be properlychosen in a range of several minutes to 48 hours.

[0099] After completion of the reaction, the desired compound isisolated from the reaction solution containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beproduced. The desired compound can be subjected to the subsequentreaction without isolation from the reaction solution.

[0100] The phthalic acid ester of the general formula (VII) can beproduced, for example, by the process described in J. Med. Chem., 31,1466 (1988).

General formula (VII-1)→general formula (III-6)  (2)

[0101] As the inert solvent used in this reaction, there may be used,for example, the inert solvents exemplified in production process 1-(1).

[0102] As the base, an inorganic base or an organic base may be used. Asthe inorganic base, there may be used, for example, hydroxides of alkalimetals, such as sodium hydroxide, potassium hydroxide, etc. As theorganic base, there may be used triethylamine, pyridine, etc. The amountOf the base used may be properly chosen in a range of 0.5 to 3equivalents per equivalent of the phthaloyl halide of the generalformula (VII-1).

[0103] Since the reaction is an equimolar reaction, it is sufficientthat the reactants are used in equimolar amounts, though the amount ofthe aniline of the general formula (IV) used may be properly chosen in arange of 0.5 to 2 equivalents per equivalent of the phthaloyl halide ofthe general formula (VII-1).

[0104] As to the reaction temperature, the reaction can be carried outin a temperature range of 0° C. to the reflux temperature of the inertsolvent used. Although the reaction time is varied depending on thescale of reaction, the reaction temperature, etc., it may be properlychosen in a range of several minutes to 48 hours.

[0105] After completion of the reaction, the desired compound isisolated from the reaction solution containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beproduced. The desired compound can be subjected to the subsequentreaction without isolation from the reaction solution.

General formula (III-6)→general formula (III-5)  (3)

[0106] As the inert solvent usable in this reaction, there may be usedwater, alcohols (e.g. methanol, ethanol and propanol) as water-solublesolvents, and mixed solvents of water and a water-soluble solvent.

[0107] As the base used for the hydrolysis, there may be used, forexample, hydroxides of alkali metals, such as sodium hydroxide,potassium hydroxide, etc. The amount of the base used may be properlychosen in a range of 1 to 10 equivalents per equivalent of thephthalanilide of the general formula (III-6).

[0108] As to the reaction temperature, the reaction can be carried outin a temperature range of 0° C. to the reflux temperature of the inertsolvent used. Although the reaction time is varied depending on thescale of reaction, the reaction temperature, etc., it may be properlychosen in a range of several minutes to 48 hours.

[0109] After completion of the reaction, the desired compound isisolated from the reaction solution containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beproduced. The desired compound can be subjected to the subsequentreaction without isolation from the reaction solution.

General formula (III-5)→general formula (VI-1)  (4)

[0110] The desired compound can be produced by this reaction accordingto production process 5-(2).

General formula (VI-1)→general formula (I-1)  (5)

[0111] The desired compound can be produced by this reaction accordingto production process 1-(2).

Production process 7

[0112]

[0113] wherein R¹, R², R³, X, Y, m, n, Z¹ and Z² are as defined above.

[0114] A benzamide derivative of the general formula (VIII-1) or thegeneral formula (VIII-2) or a thiobenzamide derivative of the generalformula (VIII-3) or the general formula (VIII-4) obtained bythiocarbonylation of the benzamide derivative of the general formula(VIII-1) or the general formula (VIII-2), respectively, is subjected toortho-metallation by using a metal reagent such as butyllithium. Thecompound thus obtained is directly reacted with an isocyanate orisothiocyanate derivative of the general formula (IX-1) or (IX-2), orthe compound is reacted with carbon dioxide to obtain a phthalamidederivative of the general formula (III-4′) or the general formula(III-5′), which is treated in the same manner as in production processes5-(1) to 5-(4). Thus, a phthalic acid diamide derivative of the generalformula (I) can be produced.

General formula (VIII-1) or general formula (VIII-2)→general formula(VIII-3) or general formula (VIII-4), respectively  (1)

[0115] The desired compound can be produced by this reaction accordingto the method described in J. org. Chem., 46, 3558 (1981).

General formula (VIII-1), general formula (VIII-2), general formula(VIII-3) or general formula (VIII-4)→general formula (I)  (2)

[0116] In this step, the benzamide derivative of the general formula(VIII-1) or the general formula (VIII-2) or the thiobenzamide derivativeof the general formula (VIII-3) or the general formula (VIII-4) obtainedby thiocarbonylation of the benzamide derivative of the general formula(VIII-1) or the general formula (VIII-2), respectively, is subjected toortho-lithiation according to the method described in J. Org. Chem., 29,853 (1964). The compound thus obtained is reacted with the isocyanate orisothiocyanate derivative of the general formula (IX-1) or (IX-2) at−80° C. to room temperature, whereby the desired compound can beproduced.

[0117] After completion of the reaction, the desired compound isisolated from the reaction solution containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beobtained.

General formula (VIII-1), general formula (VIII-2), general formula(VIII-3) or general formula (VIII-4)→general formula (III-4′) or thegeneral formula (III-5′)  (3)

[0118] In this step, the desired compound can be produced by carryingout the same ortho-lithiation as in the above step (2) and introducingcarbon dioxide into the ortho-lithiation product at −80° C. to roomtemperature.

[0119] After completion of the reaction, the desired compound isisolated from the reaction solution containing the desired compound by aconventional method, and if necessary, purified by recrystallization,column chromatography, etc., whereby the desired compound can beobtained.

General formula (III-4′) or general formula (III-5′)→general formula(I)  (4)

[0120] In this step, the desired compound can be produced in the samemanner as in production process 1-(2) or 5-(4).

[0121] Tables 1 and 2 show typical examples of the phthalic acid diamidederivative of the general formula (I) used as the active ingredient ofthe agricultural and horticultural insecticide of the present invention,but the examples are not intended in any way to limit the scope of thepresent invention.

General Formula (I)

[0122] TABLE 1 (Z¹, Z² = O) (I)

Physical Properties No R¹ R² R³ Xn Ym (melting point: ° C. 1 H H H 3-NO₂2-CH₃-5-Cl 173-175 2 CH₃ H H H 4-CF₃ 129-131 3 CH₃ H H 3-NO₂ 2-CH₃-5-Cl169-171 4 CH₃ H H 3-NO₂ 2-CH₃-4-OCHF₂ 167-169 5 CH₃ CH₃ H 6-NO₂2-CH₃-5-Cl 171-173 6 CH₃ CH₃ H 6-NO₂ 2-CH₃-4-OCHF₂ 167-169 7 C₂H₅ H H H4-CF₃ 134-136 8 C₂H₅ H H 3-Cl 2-CH₃-4-OCHF₂ 179-180 9 C₂H₅ H H 6-Cl2-CH₃-4-OCHF₂ 189-190 10 C₂H₅ H H 3-NO₂ 2-CH₃-5-Cl 175-177 11 C₂H₅ H H3-NO₂ 2-CH₃-4-OCHF₂ 207-208 12 C₂H₅ C₂H₅ H H 4-CF₃ 148-150 13 C₂H₅ C₂H₅H 3-NO₂ 2-CH₃-5-Cl 175-177 14 n-C₃H₇ H H H 4-CF₃ 138-140 15 n-C₃H₇ H H3-Cl 2-CH₃-4-OCHF₂ 171-173 16 n-C₃H₇ H H 6-Cl 2-CH₃-4-OCHF₂ 189-191 17n-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCHF₂ 184-186 18 n-C₃H₇ H H 3-NO₂ 2-CH₃-5-Cl187-189 19 n-C₃H₇ H H 5-CF₃ 2,6-(C₂H₅)₂ 230-232 20 i-C₃H₇ H H H H192-194 21 i-C₃H₇ H H H 2-NO₂ 198-200 22 i-C₃H₇ H H H 4-NO₂ 139-141 23i-C₃H₇ H H H 4-F 199-201 24 i-C₃H₇ H H H 2-CH₃ 191-193 25 i-C₃H₇ H H H4-CF₃ 198-200 26 i-C₃H₇ H H H 3-CF₃ 174-176 27 i-C₃H₇ H H H 4-CF₂CF₂CF₃237-238 28 i-C₃H₇ H H H 4-(CF₂)₃CF₃ 137-139 29 i-C₃H₇ H H H 4-OCF₃155-157 30 i-C₃H₇ H H H 4-OCF₂CHFOC₃F₃-n 220-222 31 i-C₃H₇ H H H 3-SCF₃176-178 32 i-C₃H₇ H H H 4-SCHF₂ 169-170 33 i-C₃H₇ H H H 4-SCH₂CF₃166-167 34 i-C₃H₇ H H H 4-SCF₂CHF₂ 169-170 35 i-C₃H₇ H H H 4-S(CF₂)₃CF₃159-161 36 i-C₃H₇ H H H 4-SCF(CF₃)₂ 145-147 37 i-C₃H₇ H H H 4-SCF₂CBrF₂158-160 38 i-C₃H₇ H H H 4-SOCF₂CBrF₂ 180-182 39 i-C₃H₇ H H H4-SO(CF₂)₃CF₃ 192-193 40 i-C₃H₇ H H H 4-SO₂CH₂CF₃ 169-170 41 i-C₃H₇ H HH 2,3-Cl₂ 151-153 42 i-C₃H₇ H H H 2,4-Cl₂ 162-164 43 i-C₃H₇ H H H 3,4-F₂172-174 44 i-C₃H₇ H H H 2,4-(CH₃)₂ 162-163 45 i-C₃H₇ H H H 2-Cl-4-CF₃197-199 46 i-C₃H₇ H H H 2-Cl-4-CF(CF₃)₂ 201-202 47 i-C₃H₇ H H H2-Cl-4-OCF₃ 151-153 48 i-C₃H₇ H H H 2-Br-4-OCF₃ 146-147 49 i-C₃H₇ H H H2-CH₃-3-Cl 196-198 50 i-C₃H₇ H H H 2-CH₃-4-Cl 180-182 51 i-C₃H₇ H H H2-CH₃-5-Cl 161-162 52 i-C₃H₇ H H H 2-CH₃-4-Br 159-261 53 i-C₃H₇ H H H2-CH₃-5-F 168-170 54 i-C₃H₇ H H H 2-CH₃-5-C₄H₉-t 203-204 55 i-C₃H₇ H H H2-CH₃-4-CF₂CF₃ 157-159 56 i-C₃H₇ H H H 2-CH₃-4-CF₂CF₂CF₃ 177-178 57i-C₃H₇ H H H 2-CH₃-4-CF(CF₃)₂ 230-231 58 i-C₃H₇ H H H 2-CH₃-4-OCHF₂135-137 59 i-C₃H₇ H H H 2-CH₃-4-OCF₃ 172-173 60 i-C₃H₇ H H H2-CH₃-4-OCF₂CHF₂ 145-146 61 i-C₃H₇ H H H 2-CH₃-3-OCF₂CHClF 172-174 62i-C₃H₇ H H H 2-CH₃-4-OCF₂CHClF 142-144 63 i-C₃H₇ H H H 2-CH₃-4-CF₂CBrF₂164-166 64 i-C₃H₇ H H H 2-CH₃-4-CF₂CCl₂F 172-173 65 i-C₃H₇ H H H2-CH₃-4-OCF₂CHFCF₃ 151-152 66 i-C₃H₇ H H H 2-CH₃-4-OCF₂CBrFCF₃ 163-16467 i-C₃H₇ H H H 2-CH₃-4-OCF₂CHFOCF₃ 146-148 68 i-C₃H₇ H H H2-CH₃-4-SC₃H₇-i 178-180 69 i-C₃H₇ H H H 2-CH₃-4-OCH₂OCH₃ 165-166 70i-C₃H₇ H H H 2-CH₃-4-OCH₂SCH₃ 160-162 71 i-C₃H₇ H H H 2-CH₃-4-COOCH₃163-165 72 i-C₃H₇ H H H 2-CH₃-4-OCH₂COOCH₃ 121-122 73 i-C₃H₇ H H H2-CH₃-4-(F₅—PhO) 185-187 74 i-C₃H₇ H H H 2-CH₃-4-(3-CF₃—PhO) 150-152 75i-C₃H₇ H H H 2-CH₃-4-(2-Cl-4-CF₃—PhO) 183-185 76 i-C₃H₇ H H H2-CH₃-4-(4-Cl—Ph—CH₂O) 188-189 77 i-C₃H₇ H H H 2-CH₃-4-(4-Cl—PhS)181-182 78 i-C₃H₇ H H H 2-CH₃-4-(5-CF₃-2-Pyi-O) 165-167 79 i-C₃H₇ H H H2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 184-185 80 i-C₃H₇ H H H4-(3-Cl-5-CF₃-2-Pyi-S) 173-175 81 i-C₃H₇ H H H 2-CH₃-4-P═O(OC₂H₅)₂134-136 82 i-C₃H₇ H H H 2-CH₃-4-OP═S(OCH₃)₂ 132-134 83 i-C₃H₇ H H H2-CF₃-4-OCHF₂ 147-149 84 i-C₃H₇ H H H 3,5-Cl₂-4-OCHF₂ 183-185 85 i-C₃H₇H H H 3-N═C(CF₃)—NH-4 217-218 86 i-C₃H₇ H H H 3-N═C(CF₃)—N(CH₃)-4171-173 87 i-C₃H₇ H H 3-Cl 4-C₄H₉-n 169-171 88 i-C₃H₇ H H 3-Cl 4-C₄H₉-t224-226 89 i-C₃H₇ H H 3-Cl 4-CF(CF₃)₂ 198-200 90 i-C₃H₇ H H 3-Cl4-CF₂CF₂CF₃ 203-204 91 i-C₃H₇ H H 3-Cl 4-(CF₂)₃CF₃ 176-178 92 i-C₃H₇ H H3-Cl 4-OCHF₂ 205-207 93 i-C₃H₇ H H 3-Cl 4-OCF₂CHFOC₃F₇-n 169-171 94i-C₃H₇ H H 3-Cl 4-SCH₃ 231-232 95 i-C₃H₇ H H 6-Cl 4-SCH₃ 193-195 96i-C₃H₇ H H 3-Cl 4-SOCH₃ 178-182 97 i-C₃H₇ H H 3-Cl 4-SO₂CH₃ 208-210 98i-C₃H₇ H H 3-Cl 4-SCHF₂ 220-222 99 i-C₃H₇ H H 3-Cl 3-SCF₃ 189-191 100i-C₃H₇ H H 3-Cl 3-SOCF₃ 183-187 101 i-C₃H₇ H H 3-Cl 4-SCH₂CF₃ 191-193102 i-C₃H₇ H H 3-Cl 4-SCF₂CHF₂ 198-200 103 i-C₃H₇ H H 3-Cl 4-SCF₂CBrF₂201-203 104 i-C₃H₇ H H 3-Cl 4-SCF(CF₃)₂ 221-223 105 i-C₃H₇ H H 3-Cl4-S(CF₂)₃CF₃ 199-200 106 i-C₃H₇ H H 3-Cl 4-SOCF(CF₃)₂ 204-206 107 i-C₃H₇H H 3-Cl 4-SO₂CH₂CF₃ 202-204 108 i-C₃H₇ H H 3-Cl 4-SO₂CF₂CHF₂ 227-230109 i-C₃H₇ H H 3-Cl 4-COCH₃ 217-219 110 i-C₃H₇ H H 3-Cl 4-Ph 215-217 111i-C₃H₇ H H 3-Cl 2,3-Cl₂ 168-169 112 i-C₃H₇ H H 3-Cl 2,4-Cl₂ 190-192 113i-C₃H₇ H H 3-Cl 2,4-F₂ 188-190 114 i-C₃H₇ H H 3-Cl 2-Cl-4-F 172-173 115i-C₃H₇ H H 3-Cl 2-F-4-Cl 181-182 116 i-C₃H₇ H H 3-Cl 2,3,4-F₃ 174-176117 i-C₃H₇ H H 3-Cl 2,3-(CH₃)₂ 187-189 118 i-C₃H₇ H H 3-Cl 2-CH₃-3-Cl200-202 119 i-C₃H₇ H H 3-Cl 2-CH₃-4-Cl 213-215 120 i-C₃H₇ H H 3-Cl2-CH₃-5-Cl 183-185 121 i-C₃H₇ H H 3-Cl 2-CH₃-4-Br 210-212 122 i-C₃H₇ H H3-Cl 2-CH₃-4-I 206-208 123 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCH₃ 191-192 124i-C₃H₇ H H 3-Cl 2,3-(CH₃)₂-4-OCH₃ 208-210 125 i-C₃H₇ H H 3-Cl 2-Cl-4-CF₃156-157 126 i-C₃H₇ H H 3-Cl 2-Cl-4-CF(CF₃)₂ 204-206 127 i-C₃H₇ H H 3-Cl2-CH₃-4-CF₃ 219-220 128 i-C₃H₇ H H 3-Cl 2-CH₃-4-CF₂CF₃ 199-200 129i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₂CCl₃ 169-171 130 i-C₃H₇ H H 3-Cl2-CH₃-4-CF₂CF₂CF₃ 214-215 131 i-C₃H₇ H H 3-Cl 2-CH₃-4-CF(CF₃)₂ 220-222132 i-C₃H₇ H H 3-Cl 2-CH₃-4-(CF₂)₃CF₃ 188-189 133 i-C₃H₇ H H 3-Cl2-CH₃-4-(CF₂)₅CF₃ 161-163 134 i-C₃H₇ H H 3-Cl 3-Cl-4-OCHF₂ 197-199 135i-C₃H₇ H H 3-Cl 2-Cl-4-OCF₃ 158-159 136 i-C₃H₇ H H 3-Cl 2-Br-4-OCF₃169-170 137 i-C₃H₇ H H 3-Cl 3-F-4-OCHF₂ 211-212 138 i-C₃H₇ H H 3-Cl2-CH₃-4-OCHF₂ 193-195 139 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₃ 199-201 140i-C₃H₇ H H 3-Cl 2-CH₃-4-OCBrF₂ 181-182 141 i-C₃H₇ H H 3-Cl2-CH₃-4-OCF₂CHF₂ 202-204 142 i-C₃H₇ H H 3-Cl 2-CH₃-3-OCF₂CHClF 169-171143 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₂CHClF 194-196 144 i-C₃H₇ H H 3-Cl2-CH₃-4-OCF₂CBrF₂ 193-194 145 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₂CCl₂F 202-203146 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₂CHFCF₃ 186-187 147 i-C₃H₇ H H 3-Cl2-CH₃-4-OCH₂CF₂CHF₂ 207-208 148 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₂CBrFCF₃205-206 149 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₂CHFOCF₃ 179-181 150 i-C₃H₇ H H3-Cl 2-CH₃-4-OCHF₂-5-Cl 191-192 151 i-C₃H₇ H H 3-Cl 3,5-Cl₂-4-OCHF₂205-207 152 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₂CHF₂-5-Cl 211-212 153 i-C₃H₇ H H3-Cl 2-CH₃-4-SC₃H₇-i 189-191 154 i-C₃H₇ H H 3-Cl 2-CH₃-4-SCHF₂ 189-191155 i-C₃H₇ H H 3-Cl 2-CH₃-4-SOCHF₂ 173-176 156 i-C₃H₇ H H 3-Cl2-CH₃-4-SO₂CHF₂ 168-170 157 i-C₃H₇ H H 3-Cl 2-CH₃-4-(F₅—PhO) 224-226 158i-C₃H₇ H H 3-Cl 2-CH₃-4-(5-CF₃-2-Pyi-O) 189-191 159 i-C₃H₇ H H 3-Cl2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 204-205 160 i-C₃H₇ H H 3-Cl4-(3-Cl-5-CF₃-2-Pyi-S) 213-215 161 i-C₃H₇ H H 3-Cl 2-CH₃-4-P═O(OC₂H₅)₂71-73 162 i-C₃H₇ H H 3-Cl 2-CH₃-4-OP═S(OCH₃)₂ 168-170 163 i-C₃H₇ H H3-Cl 2-CF₃-4-OCHF₂ 194-196 164 i-C₃H₇ H H 3-Cl 3-CF₃-4-OCHF₂ 208-209 165i-C₃H₇ H H 3-Cl 3-N═C(CF₃)—O-4 248-250 166 i-C₃H₇ H H 3-Cl3-N═C(CF₃)—NH-4 194-196 167 i-C₃H₇ H H 3-Cl 3-N═C(CF₃)—N(CH₃)-4 225-227168 i-C₃H₇ H H 4-Cl H 190-192 169 i-C₃H₇ H H 4-Cl 4-F 213-215 170 i-C₃H₇H H 4-Cl 2-CH₃ 208-210 171 i-C₃H₇ H H 4-Cl 3-CF₃ 196-198 172 i-C₃H₇ H H4-Cl 4-OCF₃ 192-194 173 i-C₃H₇ H H 4-Cl 2,4-Cl₂ 174-176 174 i-C₃H₇ H H4-Cl 3,4-F₂ 231-233 175 i-C₃H₇ H H 4-Cl 2,3-Cl₂ 186-188 176 i-C₃H₇ H H4-Cl 2-CH₃-3-Cl 203-205 177 i-C₃H₇ H H 4-Cl 2-CH₃-4-Cl 206-208 178i-C₃H₇ H H 4-Cl 2-CH₃-5-Cl 207-208 179 i-C₃H₇ H H 4-Cl 2-CH₃-5-F 229-231180 i-C₃H₇ H H 4-Cl 2-CH₃-4-OCHF₂ 223-224 181 i-C₃H₇ H H 5-Cl H 186-188182 i-C₃H₇ H H 5-Cl 4-F 209-211 183 i-C₃H₇ H H 5-Cl 2-CH₃ 187-189 184i-C₃H₇ H H 5-Cl 3-CF₃ 198-200 185 i-C₃H₇ H H 5-Cl 4-OCF₃ 180-182 186i-C₃H₇ H H 5-Cl 2,3-Cl₂ 167-169 187 i-C₃H₇ H H 5-Cl 2,4-Cl₂ 165-167 188i-C₃H₇ H H 5-Cl 3,4-F₂ 207-209 189 i-C₃H₇ H H 5-Cl 2-CH₃-3-Cl 204-206190 i-C₃H₇ H H 5-Cl 2-CH₃-4-Cl 202-204 191 i-C₃H₇ H H 5-Cl 2-CH₃-5-Cl209-210 192 i-C₃H₇ H H 5-Cl 2-CH₃-5-F 192-194 193 i-C₃H₇ H H 5-Cl2-CH₃-4-OCHF₂ 188-189 194 i-C₃H₇ H H 5-Cl 2,3,4-F₃ 224-226 195 i-C₃H₇ HH 6-Cl 4-C₄H₉-n 194-196 196 i-C₃H₇ H H 6-Cl 4-C₄H₉-t 235-237 197 i-C₃H₇H H 6-Cl 4-CF₂CF₂CF₃ 216-217 198 i-C₃H₇ H H 6-Cl 4-CF(CF₃)₂ 209-211 199i-C₃H₇ H H 6-Cl 4-(CF₂)₃CF₃ 196-198 200 i-C₃H₇ H H 6-Cl 4-OCHF₂ 223-225201 i-C₃H₇ H H 6-Cl 4-OCF₂CHFOC₃F₇-n 205-207 202 i-C₃H₇ H H 6-Cl4-SCH₂CF₃ 189-190 203 i-C₃H₇ H H 6-Cl 4-SCF₂CHF₂ 211-213 204 i-C₃H₇ H H6-Cl 4-SCF(CF₃)₂ 250-252 205 i-C₃H₇ H H 6-Cl 4-S(CF₂)₃CF₃ 210-212 206i-C₃H₇ H H 6-Cl 3-SOCF₃ 212-215 207 i-C₃H₇ H H 6-Cl 4-COCH₃ 230-232 208i-C₃H₇ H H 6-Cl 2,3-Cl₂ 179-180 209 i-C₃H₇ H H 6-Cl 2,4-Cl₂ 199-200 210i-C₃H₇ H H 6-Cl 2,4-F₂ 196-198 211 i-C₃H₇ H H 6-Cl 2-Cl-4-F 196-197 212i-C₃H₇ H H 6-Cl 2-F-4-Cl 184-186 213 i-C₃H₇ H H 6-Cl 2,3-(CH₃)₂ 214-216214 i-C₃H₇ H H 6-Cl 2-CH₃-4-Cl 233-235 215 i-C₃H₇ H H 6-Cl 2-CH₃-5-Cl204-206 216 i-C₃H₇ H H 6-Cl 2-CH₃-4-Br 242-244 217 i-C₃H₇ H H 6-Cl2-CH₃-4-I 236-238 218 i-C₃H₇ H H 6-Cl 2-CH₃-4-OCH₃ 195-197 219 i-C₃H₇ HH 6-Cl 2,3-(CH₃)₂-4-OCH₃ 242-244 220 i-C₃H₇ H H 6-Cl 2-Cl-4-CF₃ 171-172221 i-C₃H₇ H H 6-Cl 2-CH₃-4-CF₃ 234-236 222 i-C₃H₇ H H 6-Cl2-CH₃-4-OCF₂CCl₃ 169-171 223 i-C₃H₇ H H 6-Cl 2-CH₃-4-CF₂CF₃ 215-217 224i-C₃H₇ H H 6-Cl 2-CH₃-4-CF(CF₃)₂ 238-240 225 i-C₃H₇ H H 6-Cl2-CH₃-4-(CF₂)₃CF₃ 177-178 226 i-C₃H₇ H H 6-Cl 2-CH₃-4-(CF₂)₅CF₃ 167-169227 i-C₃H₇ H H 6-Cl 3,5-Cl₂-4-OCHF₂ 196-198 228 i-C₃H₇ H H 6-Cl2-CH₃-4-OCF₂CCl₂F 218-220 229 i-C₃H₇ H H 6-Cl 2-CH₃-4-OCF₂CBrF₂ 214-215230 i-C₃H₇ H H 6-Cl 2-CH₃-4-OCH₂CF₂CHF₂ 212-213 231 i-C₃H₇ H H 6-Cl2-Cl-4-CF(CF₂)₂ 212-214 232 i-C₃H₇ H H 6-Cl 3-Cl-4-OCHF₂ 204-206 233i-C₃H₇ H H 6-Cl 3-F-4-OCHF₂ 225-227 234 i-C₃H₇ H H 6-Cl 2-Cl-4-OCF₃161-162 235 i-C₃H₇ H H 6-Cl 2-Br-4-OCF₃ 188-189 236 i-C₃H₇ H H 6-Cl2-CH₃-4-OCHF₂ 213-215 237 i-C₃H₇ H H 6-Cl 2-CH₃-4-OCF₃ 212-214 238i-C₃H₇ H H 6-Cl 2-CH₃-4-OCBrF₂ 195-196 239 i-C₃H₇ H H 6-Cl2-CH₃-4-OCF₂CHF₂ 199-201 240 i-C₃H₇ H H 6-Cl 2-CH₃-3-OCF₂CHClF 195-197241 i-C₃H₇ H H 6-Cl 2-CH₃-4-OCF₂CHClF 204-213 242 i-C₃H₇ H H 6-Cl2-CH₃-4-OCF₂CHFCF₃ 199-200 243 i-C₃H₇ H H 6-Cl 2-CH₃-4-OCF₂CBrFCF₃226-227 244 i-C₃H₇ H H 6-Cl 2-CH₃-4-OCF₂CHFOCF₃ 210-212 245 i-C₃H₇ H H6-Cl 2-CH₃-4-OCHF₂-5-Cl 234-235 246 i-C₃H₇ H H 6-Cl2-CH₃-4-OCF₂CHF₂-5-Cl 230-232 247 i-C₃H₇ H H 6-Cl 2-CH₃-4-SCHF₂ 199-201248 i-C₃H₇ H H 6-Cl 2-CH₃-4-(F₅—PhO) 243-245 249 i-C₃H₇ H H 6-Cl2-CH₃-4-(5-CF₃-2-Pyi-O) 116-120 250 i-C₃H₇ H H 6-Cl2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 219-221 251 i-C₃H₇ H H 6-Cl2-CH₃-4-P═O(OC₂H₅)₂ 146-147 252 i-C₃H₇ H H 6-Cl 2-CH₃-4-OP═S(OCH₃)₂183-185 253 i-C₃H₇ H H 6-Cl 2-CF₃-4-OCHF₂ 234-236 254 i-C₃H₇ H H 6-Cl3-CF₃-4-OCHF₂ 204-205 255 i-C₃H₇ H H 6-Cl 3-N═C(CF₃)—O-4 270-272 256i-C₃H₇ H H 6-Cl 3-N═C(CF₃)—NH-4 213-215 257 i-C₃H₇ H H 6-Cl3-N═C(CF₃)—N(CH₃)-4 239-241 258 i-C₃H₇ H H 3,6-Cl₂ 2-CH₃-4-OCHF₂ 221-222259 i-C₃H₇ H H 3,6-Cl₂ 2-CH₃-4-Cl 234-235 260 i-C₃H₇ H H 3,4,5,6-Cl₄2-CH₃-4-Cl 265-266 261 i-C₃H₇ H H 3-Br 4-CF₃ 221-223 262 i-C₃H₇ H H 3-Br4-OCF₃ 208-210 263 i-C₃H₇ H H 3-Br 2,3-(CH₃)₂ 248-250 264 i-C₃H₇ H H3-Br 2,4-(CH₃)₂ 223-224 265 i-C₃H₇ H H 3-Br 2,4,6-(CH₃)₃ 254-255 266i-C₃H₇ H H 3-Br 2-CH₃-3-Cl 215-217 267 i-C₃H₇ H H 3-Br 2-CH₃-4-Cl176-178 268 i-C₃H₇ H H 3-Br 2-CH₃-5-Cl 196-198 269 i-C₃H₇ H H 3-Br2,3-(CH₃)₂-4-Cl 222-224 270 i-C₃H₇ H H 3-Br 2,4-(CH₃)₂-3-Cl 236-238 271i-C₃H₇ H H 3-Br 2-C₂H₅-4-Cl 205-207 272 i-C₃H₇ H H 3-Br 2-CH₃-4-Br220-222 273 i-C₃H₇ H H 3-Br 2,3-(CH₃)₂-4-Br 200-202 274 i-C₃H₇ H H 3-Br2-CH₃-4-I 203-205 275 i-C₃H₇ H H 3-Br 2-CH₃-4-F 223-224 276 i-C₃H₇ H H3-Br 2-Cl-4-CF₃ 156-157 277 i-C₃H₇ H H 3-Br 2-CH₃-4-CF₃ 227-228 278i-C₃H₇ H H 3-Br 2-CH₃-4-CF₂CF₃ 201-202 279 i-C₃H₇ H H 3-Br2-CH₃-4-CF₂CF₂CF₃ 199-200 280 i-C₃H₇ H H 3-Br 2-CH₃-4-CF(CF₃)₂ 222-224281 i-C₃H₇ H H 3-Br 2-CH₃-4-(CF₂)₃CF₃ 190-191 282 i-C₃H₇ H H 3-Br2-CH₃-4-OCH₃ 199-200 283 i-C₃H₇ H H 3-Br 2-CH₃-4-OCH₂CF₂CHF₂ 206-207 284i-C₃H₇ H H 3-Br 2,4-(CH₃)₂-3-OCHF₂ 187-189 285 i-C₃H₇ H H 3-Br2,3-(CH₃)₂-4-OCH₃ 206-208 286 i-C₃H₇ H H 3-Br 2-Cl-4-OCF₃ 165-167 287i-C₃H₇ H H 3-Br 2-Br-4-OCF₃ 179-180 288 i-C₃H₇ H H 3-Br 2-CH₃-4-OCHF₂205-207 289 i-C₃H₇ H H 3-Br 2-CH₃-4-OCF₃ 211-213 290 i-C₃H₇ H H 3-Br2-CH₃-4-OCBrF₂ 178-180 291 i-C₃H₇ H H 3-Br 2-CH₃-4-OCF₂CHFCF₃ 196-197292 i-C₃H₇ H H 3-Br 2-CH₃-4-OCF₂CHClF 194-195 293 i-C₃H₇ H H 3-Br2-CH₃-4-OCF₂CHF₂ 205-207 294 i-C₃H₇ H H 3-Br 2-CH₃-3-Cl-4-OCHF₂ 229-230295 i-C₃H₇ H H 3-Br 2,3-(CH₃)₂-4-OCHF₂ 219-220 296 i-C₃H₇ H H 3-Br2-CH₃-4-SCH₃ 215-217 297 i-C₃H₇ H H 3-Br 2-CH₃-4-(3-CF₃—PhO) 156-158 298i-C₃H₇ H H 3-Br 2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 206-208 299 i-C₃H₇ H H 3-Br2-CH₃-4-(5-CF₃-2-Pyi-O) 182-184 300 i-C₃H₇ H H 3-Br -3-OCH₂O-4- 195-198301 i-C₃H₇ H H 6-Br 4-OCF₃ 210-212 303 i-C₃H₇ H H 6-Br 2,3-(CH₃)₂250-252 304 i-C₃H₇ H H 6-Br 2,4,6-(CH₃)₃ 272-274 205 i-C₃H₇ H H 6-Br2-CH₃-3-Cl 214-216 306 i-C₃H₇ H H 6-Br 2-CH₃-4-Cl 198-200 307 i-C₃H₇ H H6-Br 2-CH₃-5-Cl 194-196 308 i-C₃H₇ H H 6-Br 2,3-(CH₃)₂-4-Cl 227-229 309i-C₃H₇ H H 6-Br 2,4-(CH₃)₂-3-Cl 249-251 310 i-C₃H₇ H H 6-Br 2-C₂H₅-4-Cl243-245 311 i-C₃H₇ H H 6-Br 2-CH₃-4-Br 227-228 312 i-C₃H₇ H H 6-Br2,3-(CH₃)₂-4-Br 209-211 313 i-C₃H₇ H H 6-Br 2-CH₃-4-I 227-229 314 i-C₃H₇H H 6-Br 2-CH₃4-F 231-232 315 i-C₃H₇ H H 6-Br 2-Cl-4-CF₃ 169-170 316i-C₃H₇ H H 6-Br 2-CH₃-4-CF₃ 232-234 317 i-C₃H₇ H H 6-Br 2-CH₃-4-CF(CF₃)₂236-238 318 i-C₃H₇ H H 6-Br 2-CH₃-4-(CF₂)₃CF₃ 208-210 319 i-C₃H₇ H H6-Br 2-CH₃-4-OCH₂CF₂CHF₂ 209-211 320 i-C₃H₇ H H 6-Br 2,4-(CH₃)₂-3-OCHF₂247-249 321 i-C₃H₇ H H 6-Br 2,3-(CH₃)₂-4-OCH₃ 250-252 322 i-C₃H₇ H H6-Br 2-CH₃-4-OCH₃ 220-222 323 i-C₃H₇ H H 6-Br 2-Cl-4-OCF₃ 182-183 324i-C₃H₇ H H 6-Br 2-Br-4-OCF₃ 195-196 325 i-C₃H₇ H H 6-Br 2-CH₃-4-OCHF₂225-226 326 i-C₃H₇ H H 6-Br 2-CH₃-4-OCF₃ 223-225 327 i-C₃H₇ H H 6-Br2-CH₃-4-OCBrF₂ 194-196 328 i-C₃H₇ H H 6-Br 2-CH₃-4-OCF₂CHFCF₃ 212-213329 i-C₃H₇ H H 6-Br 2-CH₃-4-OCF₂CHClF 211-213 330 i-C₃H₇ H H 6-Br2-CH₃-4-OCF₂CHF₂ 214-215 331 i-C₃H₇ H H 6-Br 2,3-(CH₃)₂-4-OCHF₂ 228-229332 i-C₃H₇ H H 6-Br 2-CH₃-3-Cl-4-OCHF₂ 224-225 333 i-C₃H₇ H H 6-Br2-CH₃-4-SCH₃ 215-217 334 i-C₃H₇ H H 6-Br 2-CH₃-4-(3-CF₃—PhO) 194-195 335i-C₃H₇ H H 6-Br 2-CH₃-4-(5-CF₃-2-Pyi-O) 201-203 336 i-C₃H₇ H H 6-Br2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 234-236 337 i-C₃H₇ H H 6-Br -3-OCH₂O-4-205-207 338 i-C₃H₇ H H 3,4-Br₂ 2-CH₃-4-OCHF₂ 196-197 339 i-C₃H₇ H H3,4-Br₂ 2-CH₃-4-Cl 199-201 340 i-C₃H₇ H H 3,6-Br 2-CH₃-4-OCHF₂ 233-234341 i-C₃H₇ H H 3,6-Br₂ 2-CH₃-4-Cl 245-247 242 i-C₃H₇ H H 5,6-Br₂2-CH₃-4-OCHF₂ 208-210 343 i-C₃H₇ H H 5,6-Br₂ 2-CH₃-4-Cl 259-261 344i-C₃H₇ H H 3,4,5,6-Br₄ 2-CH₃-4-Cl 270-272 345 i-C₃H₇ H H 3-I 4-Cl230-232 346 i-C₃H₇ H H 3-I 4-Br 251-253 347 i-C₃H₇ H H 3-I 4-I 231-233348 i-C₃H₇ H H 3-I 3-CF₃ 194-197 349 i-C₃H₇ H H 3-I 4-CF₃ 223-224 350i-C₃H₇ H H 3-I 4-CF₂CF₂CF₃ 217-219 351 i-C₃H₇ H H 3-I 4-CF(CF₃)₂ 209-211352 i-C₃H₇ H H 3-I 4-OCF₃ 222-223 353 i-C₃H₇ H H 3-I 4-OCF₂CHFOCF₃192-194 354 i-C₃H₇ H H 3-I 4-SCHF₂ 204-206 355 i-C₃H₇ H H 3-I 4-SCH₂CF₃195-197 356 i-C₃H₇ H H 3-I 4-SCF₂CHF₂ 196-198 357 i-C₃H₇ H H 3-I4-SCF₂CBrF₂ 203-205 358 i-C₃H₇ H H 3-I 4-SCF(CF₃)₂ 170-172 359 i-C₃H₇ HH 3-I 4-S(CF₂)₃CF₃ 185-187 360 i-C₃H₇ H H 3-I 3,4-F₂ 227-229 361 i-C₃H₇H H 3-I 2-CH₃-3-Cl 222-224 362 i-C₃H₇ H H 3-I 2-CH₃-4-Cl 215-217 363i-C₃H₇ H H 3-I 2-CH₃-5-Cl 210-212 364 i-C₃H₇ H H 3-I 2,4-(CH₃)₂-3-Cl226-228 365 i-C₃H₇ H H 3-I 2,3-(CH₃)₂-4-Cl 235-237 366 i-C₃H₇ H H 3-I2-CH₃-4-Br 227-229 367 i-C₃H₇ H H 3-I 2-CH₃-4-I 201-203 368 i-C₃H₇ H H3-I 2-CH₃-4-F 227-228 369 i-C₃H₇ H H 3-I 2-Cl-4-CF₃ 170-171 370 i-C₃H₇ HH 3-I 2-CH₃-3-CF₃ 179-181 371 i-C₃H₇ H H 3-I 2-CH₃-4-CF₃ 202-203 372i-C₃H₇ H H 3-I 2-CH₃-4-CF₂CF₃ 195-196 373 i-C₃H₇ H H 3-I2-CH₃-4-CF₂CF₂CF₃ 193-195 374 i-C₃H₇ H H 3-I 2-CH₃-4-CF(CF₃)₂ 211-213375 i-C₃H₇ H H 3-I 2-CH₃-4-(CF₂)₃CF₃ 203-204 376 i-C₃H₇ H H 3-I2-CH₃-4-OCH₃ 204-206 377 i-C₃H₇ H H 3-I 2-CH₃-4-O—C₃H₇-i 209-211 378i-C₃H₇ H H 3-I 2,3-(CH₃)₂-4-OCH₃ 220-222 379 i-C₃H₇ H H 3-I2-CH₃-4-OCH₂CF₃ 223-224 380 i-C₃H₇ H H 3-I 2-CH₃-4-OCF₂CBrF₂ 228-230 381i-C₃H₇ H H 3-I 2-CH₃-4-OCF₂CCl₂F 230-231 382 i-C₃H₇ H H 3-I 3-F-4-OCHF₂208-210 383 i-C₃H₇ H H 3-I 3,5-Cl₂-4-OCHF₂ 234-236 384 i-C₃H₇ H H 3-I3-OCH₃-4-OCHF₂ 196-198 385 i-C₃H₇ H H 3-I 3,4-(OCHF₂)₂ 171-172 386i-C₃H₇ H H 3-I 2-CH₃-4-OCF₃ 214-216 387 i-C₃H₇ H H 3-I 2-CH₃-4-OCHF₂207-209 388 i-C₃H₇ H H 3-I 2-CH₃-4-OCH₂CF₂CHF₂ 229-231 389 i-C₃H₇ H H3-I 2-CH₃-4-OCBrF₂ 181-182 390 i-C₃H₇ H H 3-I 2-CH₃-4-OCF₂CHF₂ 197-199391 i-C₃H₇ H H 3-I 2-CH₃-4-OCF₂CHF₂-5-Cl 198-200 392 i-C₃H₇ H H 3-I2-CH₃-4-OCF₂CHClF 200-201 393 i-C₃H₇ H H 3-I 2-CH₃-4-OCF₂CHFCF₃ 213-214394 i-C₃H₇ H H 3-I 2-CH₃-4-OCF₂CBrFCF₃ 233-234 395 i-C₃H₇ H H 3-I2-CH₃-4-OCF₂CHFOCF₃ 213-215 396 i-C₃H₇ H H 3-I 2-CH₃-4-OCHF₂-5-Cl230-232 397 i-C₃H₇ H H 3-I 2-CH₃-4-(F₅—PhO) 245-247 398 i-C₃H₇ H H 3-I2-CH₃-4-(3-CF₃—PhO) 168-170 399 i-C₃H₇ H H 3-I 2-CH₃-4-(5-CF₃-2-Pyi-O)186-188 400 i-C₃H₇ H H 3-I 2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 212-214 401i-C₃H₇ H H 3-I 2-CH₃-4-SO₂CH₃ 172-175 402 i-C₃H₇ H H 3-I 2-CH₃-4-SC₃H₇-i190-192 403 i-C₃H₇ H H 3-I 2-CH₃-4-SCF₂CF₂CF₃ 227-228 404 i-C₃H₇ H H 3-I2-CH₃-4-(4-Cl—PhS) 191-192 405 i-C₃H₇ H H 3-I 4-(3-Cl-5-CF₃-2-Pyi-S)198-200 406 i-C₃H₇ H H 3-I 2-Br-4-OCF₃ 196-198 407 i-C₃H₇ H H 3-I2-Cl-4-CF₂CF₂CF₃ 162-164 408 i-C₃H₇ H H 3-I 2-Cl-4-OCF₃ 173-175 409i-C₃H₇ H H 3-I 2-CF₃-4-OCHF₂ 219-220 410 i-C₃H₇ H H 3-I 3-CF₃-4-OCHF₂128-130 411 i-C₃H₇ H H 6-I 4-Cl 251-253 412 i-C₃H₇ H H 6-I 4-Br 270-272413 i-C₃H₇ H H 6-I 4-I 242-244 414 i-C₃H₇ H H 6-I 3-CF₃ 210-212 415i-C₃H₇ H H 6-I 4-CF₃ 201-202 416 i-C₃H₇ H H 6-I 4-CF(CF₃)₂ 238-240 417i-C₃H₇ H H 6-I 4-CF₂CF₂CF₃ 238-240 418 i-C₃H₇ H H 6-I 4-OCF₃ 193-194 419i-C₃H₇ H H 6-I 4-OCF₂CHFOC₃H₇-n 213-214 420 i-C₃H₇ H H 6-I 4-SCH₂CF₃217-219 421 i-C₃H₇ H H 6-I 4-SCHF₂ 224-226 422 i-C₃H₇ H H 6-I 4-SCF₂CHF₂213-215 423 i-C₃H₇ H H 6-I 4-SCF₂CBrF₂ 220-222 424 i-C₃H₇ H H 6-I4-SCF₂CF₂CF₃ 196-197 425 i-C₃H₇ H H 6-I 4-SCF(CF₃)₂ 216-218 426 i-C₃H₇ HH 6-I 4-S(CF₂)₃CF₃ 201-203 427 i-C₃H₇ H H 6-I 2-CH₃-3-Cl 252-254 428i-C₃H₇ H H 6-I 2-CH₃-4-Cl 244-246 429 i-C₃H₇ H H 6-I 2,4-(CH₃)₂-3-Cl260-262 430 i-C₃H₇ H H 6-I 2-CH₃-4-Br 241-243 431 i-C₃H₇ H H 6-I2-CH₃-4-I 213-215 432 i-C₃H₇ H H 6-I 2-CH₃-4-F 251-252 433 i-C₃H₇ H H6-I 2-Cl-4-CF₃ 195-196 434 i-C₃H₇ H H 6-I 2,3-(CH₃)₂-4-Cl 253-255 435i-C₃H₇ H H 6-I 2-CH₃-3-CF₃ 245-251 436 i-C₃H₇ H H 6-I 2-CH₃-4-CF₃220-221 437 i-C₃H₇ H H 6-I 2-CH₃-4-CF₂CF₃ 203-205 438 i-C₃H₇ H H 6-I2-CH₃-4-CF₂CF₂CF₃ 154-156 439 i-C₃H₇ H H 6-I 2-CH₃-4-CF(CF₃)₂ 237-239440 i-C₃H₇ H H 6-I 2-CH₃-4-(CF₂)₃CF₃ 168-170 441 i-C₃H₇ H H 6-I2-CH₃-4-OCH₃ 215-217 442 i-C₃H₇ H H 6-I 2-CH₃-4-O—C₃H₇-i 212-214 443i-C₃H₇ H H 6-I 2-CH₃-4-OCH₂CF₃ 233-234 444 i-C₃H₇ H H 6-I2-CH₃-4-OCF₂CBrF₂ 242-244 445 i-C₃H₇ H H 6-I 2-CH₃-4-OCF₂CCl₂F 251-253446 i-C₃H₇ H H 6-I 2-CH₃-4-OCF₂CBrFCF₃ 251-253 447 i-C₃H₇ H H 6-I2-CH₃-4-OCH₂CF₂CHF₂ 235-237 448 i-C₃H₇ H H 6-I 3-F-4-OCHF₂ 214-216 449i-C₃H₇ H H 6-I 3,5-Cl₂-4-OCHF₂ 211-213 450 i-C₃H₇ H H 6-I 3-OCH₃-4-OCHF₂215-217 451 i-C₃H₇ H H 6-I 2,3-(CH₃)₂-4-OCH₃ 253-254 452 i-C₃H₇ H H 6-I2-CH₃-4-OCBrF₂ 192-194 453 i-C₃H₇ H H 6-I 2-CH₃-4-OCF₂CHF₂ 216-218 454i-C₃H₇ H H 6-I 2-CH₃-4-OCF₂CHF₂-5-Cl 230-232 455 i-C₃H₇ H H 6-I2-CH₃-4-OCF₂CHClF 205-207 456 i-C₃H₇ H H 6-I 2-CH₃-4-OCF₂CHFCF₃ 222-223457 i-C₃H₇ H H 6-I 2-CH₃-4-OCF₂CHFOCF₃ 258-260 458 i-C₃H₇ H H 6-I2-CH₃-4-(3-CF₃—PhO) 198-199 459 i-C₃H₇ H H 6-I 2-CH₃-4-(F₅—PhO) 262-264460 i-C₃H₇ H H 6-I 2-CH₃-4-(5-CF₃-2-Pyi-O) 245-246 461 i-C₃H₇ H H 6-I2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 231-232 462 i-C₃H₇ H H 6-I 2-CH₃-4-SC₃H₇-i197-199 463 i-C₃H₇ H H 6-I 2-CH₃-4-(4-Cl—PhS) 211-213 464 i-C₃H₇ H H 6-I2-CH₃-4-OCF₃ 230-232 465 i-C₃H₇ H H 6-I 2-CF₃-4-OCHF₂ 238-239 466 i-C₃H₇H H 6-I 2-Br-4-OCF₃ 215-217 467 i-C₃H₇ H H 6-I 2-Cl-4-OCF₃ 186-188 468i-C₃H₇ H H 6-I 2-Cl-4-CF₂CF₂CF₃ 199-200 469 i-C₃H₇ H H 6-I 2-CH₃-4-OCHF₂226-228 470 i-C₃H₇ H H 6-I 2-CH₃-4-OCHF₂-5-Cl 239-240 471 i-C₃H₇ H H 6-I3-CF₃-4-OCHF₂ 238-239 472 i-C₃H₇ H H 3-F 4-(CF₂)₃CF₃ 187-188 473 i-C₃H₇H H 3-F 4-CF₂CF₂CF₃ 182-183 474 i-C₃H₇ H H 3-F 4-CF(CF₃)₂ 206-208 475i-C₃H₇ H H 3-F 4-OCF₃ 197-199 476 i-C₃H₇ H H 3-F 4-OCF₂CHFOC₃F₇-n142-144 477 i-C₃H₇ H H 3-F 4-SCHF₂ 190-192 478 i-C₃H₇ H H 3-F 4-SCH₂CF₃157-158 479 i-C₃H₇ H H 3-F 4-SCF₂CHF₂ 177-178 480 i-C₃H₇ H H 3-F4-SCF₂CBrF₂ 197-199 481 i-C₃H₇ H H 3-F 4-SCF(CF₃)₂ 206-208 482 i-C₃H₇ HH 3-F 4-S(CF₂)₃CF₃ 173-174 483 i-C₃H₇ H H 3-F 4-SOCH₂CF₃ 115-119 484i-C₃H₇ H H 3-F 4-SOCF₂CBrF₂ 181-182 485 i-C₃H₇ H H 3-F 4-SOCF(CF₃)₂195-197 486 i-C₃H₇ H H 3-F 4-SO(CF₂)₃CF₃ 175-176 487 i-C₃H₇ H H 3-F4-SO₂CH₂CF₃ 199-202 488 i-C₃H₇ H H 3-F 2,3-Cl₂ 175-177 489 i-C₃H₇ H H3-F 2-CH₃-3-Cl 193-194 490 i-C₃H₇ H H 3-F 2-CH₃-4-Cl 192-194 491 i-C₃H₇H H 3-F 2-CH₃-5-Cl 191-193 492 i-C₃H₇ H H 3-F 2-CH₃-4-I 192-194 493i-C₃H₇ H H 3-F 2-CH₃-5-F 175-177 494 i-C₃H₇ H H 3-F 2-CH₃-3-F 187-189495 i-C₃H₇ H H 3-F 2-CH₃-4-CF₂CF₃ 213-214 496 i-C₃H₇ H H 3-F2-CH₃-4-CF₂CF₂CF₃ 191-192 497 i-C₃H₇ H H 3-F 2-CH₃-4-CF(CF₃)₂ 241-243498 i-C₃H₇ H H 3-F 2-CH₃-4-(CF₂)₃CF₃ 138-139 499 i-C₃H₇ H H 3-F2-CH₃-3-OCHF₂ 172-174 500 i-C₃H₇ H H 3-F 2-CH₃-4-OCHF₂ 160-162 501i-C₃H₇ H H 3-F 2-CH₃-4-OCF₂CCl₃ 162-163 502 i-C₃H₇ H H 3-F2-CH₃-4-OCF₂CCl₂F 207-208 503 i-C₃H₇ H H 3-F 2-CH₃-4-OCF₂CBrF₂ 196-197504 i-C₃H₇ H H 3-F 2-Cl-4-CF₃ 169-170 505 i-C₃H₇ H H 3-F2-Cl-4-CF₂CF₂CF₃ 169-170 506 i-C₃H₇ H H 3-F 3,5-Cl₂-4-OCHF₂ 201-202 507i-C₃H₇ H H 3-F 2-Cl-4-CF(CF₃)₂ 223-225 508 i-C₃H₇ H H 3-F 2-Cl-4-OCF₃169-170 509 i-C₃H₇ H H 3-F 2-Br-4-OCF₃ 164-165 510 i-C₃H₇ H H 3-F2-CH₃-4-OCF₃ 183-184 511 i-C₃H₇ H H 3-F 2-CH₃-4-OCBrF₂ 177-178 512i-C₃H₇ H H 3-F 2-CH₃-4-OCF₂CHF₂ 172-173 513 i-C₃H₇ H H 3-F2-CH₃-4-OCF₂CHClF 168-169 514 i-C₃H₇ H H 3-F 2-CH₃-4-OCF₂CHFCF₃ 160-162515 i-C₃H₇ H H 3-F 2-CH₃-4-OCF₂CHFOCF₃ 148-150 516 i-C₃H₇ H H 3-F2-CH₃-4-OCF₂CBrFCF₃ 148-150 517 i-C₃H₇ H H 3-F 2-CH₃-4-OCHF₂-5-Cl187-188 518 i-C₃H₇ H H 3-F 2-CH₃-4-SC₃H₇-i 165-167 519 i-C₃H₇ H H 3-F2-CH₃-4-(3-CF₃—PhO) 135-136 520 i-C₃H₇ H H 3-F 2-CH₃-4-(F₅—PhO) 206-207521 i-C₃H₇ H H 3-F 2-CH₃-4-(2-Cl-4-CF₃—PhO) 215-217 522 i-C₃H₇ H H 3-F2-CH₃-4-(4-Cl—PhS) 176-178 523 i-C₃H₇ H H 3-F 2-CH₃-4-(5-CF₃-2-Pyi-O)175-176 524 i-C₃H₇ H H 3-F 2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 188-190 525i-C₃H₇ H H 3-F 4-(3-Cl-5-CF₃-2-Pyi-S) 213-215 526 i-C₃H₇ H H 3-F2-CH₃-4-OP═S(OCH₃)₂ 175-177 527 i-C₃H₇ H H 3-F 2-CF₃-4-OCHF₂ 180-182 528i-C₃H₇ H H 3-F -3-OCH₂O-4- 197-199 529 i-C₃H₇ H H 4-F 2-CH₃-4-Cl 217-218530 i-C₃H₇ H H 4-F 2-CH₃-5-Cl 202-203 531 i-C₃H₇ H H 4-F 2-CH₃-4-OCHF₂191-193 532 i-C₃H₇ H H 5-F 2-CH₃-4-Cl 197-198 533 i-C₃H₇ H H 5-F2-CH₃-4-CF₂CF₂CF₃ 213-215 534 i-C₃H₇ H H 5-F 2-CH₃-4-OCHF₂ 181-182 535i-C₃H₇ H H 6-F 4-CF₂CF₂CF₃ 201-202 536 i-C₃H₇ H H 6-F 4-(CF₂)₃CF₃156-158 537 i-C₃H₇ H H 6-F 4-OCF₃ 212-214 538 i-C₃H₇ H H 6-F4-OCF₂CHFOC₃F₇-n 178-180 539 i-C₃H₇ H H 6-F 4-SCH₂CF₃ 176-178 540 i-C₃H₇H H 6-F 4-SCF₂CHF₂ 230-232 541 i-C₃H₇ H H 6-F 4-SCF(CF₃)₂ 218-220 542i-C₃H₇ H H 6-F 4-S(CF₂)₃CF₃ 178-181 543 i-C₃H₇ H H 6-F 2,3-Cl₂ 158-160544 i-C₃H₇ H H 6-F 2-CH₃-3-Cl 182-184 545 i-C₃H₇ H H 6-F 2-CH₃-4-Cl204-206 546 i-C₃H₇ H H 6-F 2-CH₃-5-Cl 196-199 547 i-C₃H₇ H H 6-F2-CH₃-4-I 213-215 548 i-C₃H₇ H H 6-F 2-CH₃-3-F 165-167 549 i-C₃H₇ H H6-F 2-CH₃-5-F 181-183 550 i-C₃H₇ H H 6-F 2-Cl-4-CF₃ 190-191 551 i-C₃H₇ HH 6-F 2-CH₃-4-CF₂CF₃ 222-223 552 i-C₃H₇ H H 6-F 2-CH₃-4-OCF₂CCl₃ 184-185553 i-C₃H₇ H H 6-F 2-CH₃-4-OCF₂CCl₂F 214-215 554 i-C₃H₇ H H 6-F2-CH₃-4-OCF₂CBrF₂ 208-210 555 i-C₃H₇ H H 6-F 2-CH₃-4-CF₂CF₂CF₃ 168-170556 i-C₃H₇ H H 6-F 2-CH₃-4-CF(CF₃)₂ 255-257 557 i-C₃H₇ H H 6-F2-CH₃-4-(CF₂)₃CF₃ 157-159 558 i-C₃H₇ H H 6-F 2-CH₃-3-OCHF₂ 177-179 559i-C₃H₇ H H 6-F 2-CH₃-4-OCHF₂ 176-178 560 i-C₃H₇ H H 6-F 3,5-Cl₂-4-OCHF₂198-200 561 i-C₃H₇ H H 6-F 2-Cl-4-CF(CF₃)₂ 241-243 562 i-C₃H₇ H H 6-F2-Cl-4-OCF₃ 171-172 563 i-C₃H₇ H H 6-F 2-Br-4-OCF₃ 181-182 564 i-C₃H₇ HH 6-F 2-CH₃-4-OCF₃ 193-195 565 i-C₃H₇ H H 6-F 2-CH₃-4-OCBrF₂ 181-183 566i-C₃H₇ H H 6-F 2-CH₃-4-OCF₂CHF₂ 185-187 567 i-C₃H₇ H H 6-F2-CH₃-4-OCF₂CHClF 175-176 568 i-C₃H₇ H H 6-F 2-CH₃-4-OCF₂CHFCF₃ 176-178569 i-C₃H₇ H H 6-F 2-CH₃-4-OCF₂CBrFCF₃ 217-219 570 i-C₃H₇ H H 6-F2-CH₃-4-OCF₂CHFOCF₃ 183-185 571 i-C₃H₇ H H 6-F 2-CH₃-4-OCHF₂-5-Cl209-211 572 i-C₃H₇ H H 6-F 2-CH₃-4-(3-CF₃—PhO) 184-185 573 i-C₃H₇ H H6-F 2-CH₃-4-(F₅—PhO) 227-228 574 i-C₃H₇ H H 6-F 2-CH₃-4-(2-Cl-4-CF₃—PhO)220-222 575 i-C₃H₇ H H 6-F 2-CH₃-4-(4-Cl—PhS) 190-193 576 i-C₃H₇ H H 6-F2-CH₃-4-(5-CF₃-2-Pyi-O) 206-207 577 i-C₃H₇ H H 6-F2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 177-179 578 i-C₃H₇ H H 6-F2-CH₃-4-OP═S(OCH₃)₂ 188-190 579 i-C₃H₇ H H 6-F 2-CF₃-4-OCHF₂ 223-225 580i-C₃H₇ H H 6-F -3-OCH₂O-4- 201-203 581 i-C₃H₇ H H 3,6-F₂ 2-CH₃-4-OCHF₂203-204 582 i-C₃H₇ H H 3,6-F₂ 2-CH₃-4-Cl 221-222 583 i-C₃H₇ H H3,4,5,6-F₄ 2-CH₃-5-Cl 189-191 584 i-C₃H₇ H H 3-NO₂ 2,3-Cl₂ 201-203 585i-C₃H₇ H H 3-NO₂ H 236-238 586 i-C₃H₇ H H 3-NO₂ 2-Cl 190-192 587 i-C₃H₇H H 3-NO₂ 3-Cl 227-229 588 i-C₃H₇ H H 3-NO₂ 4-Cl 238-240 589 i-C₃H₇ H H3-NO₂ 2-Br 170-172 590 i-C₃H₇ H H 3-NO₂ 3-Br 196-198 591 i-C₃H₇ H H3-NO₂ 4-Br 205-207 592 i-C₃H₇ H H 3-NO₂ 2-F 199-201 593 i-C₃H₇ H H 3-NO₂228-230 594 i-C₃H₇ H H 3-NO₂ 4-F 250-252 595 i-C₃H₇ H H 3-NO₂ 4-I187-189 596 i-C₃H₇ H H 3-NO₂ 4-NO₂ 201-203 597 i-C₃H₇ H H 3-NO₂ 3-CN220-222 598 i-C₃H₇ H H 3-NO₂ 4-CN 226-228 599 i-C₃H₇ H H 3-NO₂ 2-CH₃227-228 600 i-C₃H₇ H H 3-NO₂ 3-CH₃ 195-197 601 i-C₃H₇ H H 3-NO₂ 4-CH₃196-198 602 i-C₃H₇ H H 3-NO₂ 2-C₂H₅ 189-191 603 i-C₃H₇ H H 3-NO₂2-C₃H₇-i 190-192 604 i-C₃H₇ H H 3-NO₂ 4-C₃H₇-i 221-223 605 i-C₃H₇ H H3-NO₂ 4-C₄H₉-n 193-195 606 i-C₃H₇ H H 3-NO₂ 4-CF₃ 192-194 607 i-C₃H₇ H H3-NO₂ 3-CF₃ 220-222 608 i-C₃H₇ H H 3-NO₂ 2-CF₃ 215-217 609 i-C₃H₇ H H3-NO₂ 4-CF₂CF₂CF₃ 184-185 610 i-C₃H₇ H H 3-NO₂ 4-CF(CF₃)₂ 243-244 611i-C₃H₇ H H 3-NO₂ 4-(CF₂)₃CF₃ 220-221 612 i-C₃H₇ H H 3-NO₂ 2-OCH₃ 172-174613 i-C₃H₇ H H 3-NO₂ 3-OCH₃ 201-203 614 i-C₃H₇ H H 3-NO₂ 4-OCH₃ 221-223615 i-C₃H₇ H H 3-NO₂ 3-O—C₃H₇-i 198-200 616 i-C₃H₇ H H 3-NO₂ 3-OCHF₂188-190 617 i-C₃H₇ H H 3-NO₂ 4-OCHF₂ 222-224 618 i-C₃H₇ H H 3-NO₂ 4-OCF₃234-236 619 i-C₃H₇ H H 3-NO₂ 4-OCF₂CHFOC₃F₇-n 138-140 620 i-C₃H₇ H H3-NO₂ 4-COOCH₃ 192-194 621 i-C₃H₇ H H 3-NO₂ 3-SCH₃ 205-207 622 i-C₃H₇ HH 3-NO₂ 2-SCH₃ 201-203 623 i-C₃H₇ H H 3-NO₂ 3-SCF₃ 203-205 624 i-C₃H₇ HH 3-NO₂ 4-SCH₂CF₃ 155-156 625 i-C₃H₇ H H 3-NO₂ 4-SCHF₂ 183-185 626i-C₃H₇ H H 3-NO₂ 4-SCF₂CHF₂ 235-237 627 i-C₃H₇ H H 3-NO₂ 4-SCF₂CF₃190-192 628 i-C₃H₇ H H 3-NO₂ 4-SCF₂CBrF₂ 228-230 629 i-C₃H₇ H H 3-NO₂4-SCF(CF₃)₂ 242-243 630 i-C₃H₇ H H 3-NO₂ 4-S(CF₂)₃CF₃ 229-230 631 i-C₃H₇H H 3-NO₂ 4-SO(CF₂)₃CF₃ 190-193 632 i-C₃H₇ H H 3-NO₂ 4-O—Ph 228-230 633i-C₃H₇ H H 3-NO₂ 2,4-Cl₂ 202-204 634 i-C₃H₇ H H 3-NO₂ 2,5-Cl₂ 230-232635 i-C₃H₇ H H 3-NO₂ 2,6-Cl₂ 210-212 636 i-C₃H₇ H H 3-NO₂ 3,4-Cl₂227-229 637 i-C₃H₇ H H 3-NO₂ 3,5-Cl₂ 194-196 638 i-C₃H₇ H H 3-NO₂ 2,3-F₂184-186 639 i-C₃H₇ H H 3-NO₂ 2,4-F₂ 210-212 640 i-C₃H₇ H H 3-NO₂ 2,5-F₂191-193 641 i-C₃H₇ H H 3-NO₂ 2,6-F₂ 173-175 642 i-C₃H₇ H H 3-NO₂ 3,4-F₂241-243 643 i-C₃H₇ H H 3-NO₂ 3-Cl-4-F 203-205 644 i-C₃H₇ H H 3-NO₂2,3,4-Cl₃ 203-205 645 i-C₃H₇ H H 3-NO₂ 2,3,4-F₃ 202-204 646 i-C₃H₇ H H3-NO₂ 2,3,4,5,6-F₅ 192-194 647 i-C₃H₇ H H 3-NO₂ 2,3-(CH₃)₂ 200-202 648i-C₃H₇ H H 3-NO₂ 2,4-(CH₃)₂ 201-203 649 i-C₃H₇ H H 3-NO₂ 2,5-(CH₃)₂221-223 650 i-C₃H₇ H H 3-NO₂ 2,6-(CH₃)₂ 234-236 651 i-C₃H₇ H H 3-NO₂3,4-(CH₃)₂ 195-197 652 i-C₃H₇ H H 3-NO₂ 2,4,6-(CH₃)₃ 229-231 653 i-C₃H₇H H 3-NO₂ 2,6-(C₂H₅)₂ 258-260 654 i-C₃H₇ H H 3-NO₂ 3,5-(CF₃)₂ 225-227655 i-C₃H₇ H H 3-NO₂ 3-Cl-4-CH₃ 208-210 656 i-C₃H₇ H H 3-NO₂ 2-Cl-4-CH₃195-197 657 i-C₃H₇ H H 3-NO₂ 2-F-4-Cl-5-CH₃ 193-195 658 i-C₃H₇ H H 3-NO₂3-Cl-4-OCHF₂ 222-224 659 i-C₃H₇ H H 3-NO₂ 3,5-Cl₂-4-OCHF₂ 218-220 660i-C₃H₇ H H 3-NO₂ 2-Cl-4-CF₃ 217-219 661 i-C₃H₇ H H 3-NO₂ 2-Cl-5-CF₃193-195 662 i-C₃H₇ H H 3-NO₂ 2,6-Cl₂-4-CF₃ 226-228 663 i-C₃H₇ H H 3-NO₂2-CH₃-3-Cl 198-200 664 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-Cl 235-237 665 i-C₃H₇ HH 3-NO₂ 2-CH₃-5-Cl 218-219 666 i-C₃H₇ H H 3-NO₂ 2-CH₃-6-Cl 248-250 667i-C₃H₇ H H 3-NO₂ 2-C₂H₅-4-Cl 235-237 668 i-C₃H₇ H H 3-NO₂ 2-CH₃-4,5-Cl₂196-198 669 i-C₃H₇ H H 3-NO₂ 2,3-(CH₃)₂-4-Cl 226-228 670 i-C₃H₇ H H3-NO₂ 2,4-(CH₃)₂-3-Cl 203-205 671 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-Br 214-216672 i-C₃H₇ H H 3-NO₂ 2-CH₃-5-Br 191-193 673 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-I227-227 674 i-C₃H₇ H H 3-NO₂ 2-CH₃-3-F 199-201 675 i-C₃H₇ H H 3-NO₂2-CH₃-4-F 226-228 676 i-C₃H₇ H H 3-NO₂ 2-CH₃-5-F 213-215 677 i-C₃H₇ H H3-NO₂ 2-C₂H₅-5-F 191-193 678 i-C₃H₇ H H 3-NO₂ 3-CF₃-4-Cl 215-217 679i-C₃H₇ H H 3-NO₂ 2-CF₃-4-Cl 208-210 680 i-C₃H₇ H H 3-NO₂ 3-CH₃-4-Br199-201 681 i-C₃H₇ H H 3-NO₂ 2-CH₃-3-CF₃ 221-222 682 i-C₃H₇ H H 3-NO₂2-CH₃-4-CF₃ 236-237 683 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-CF₂CF₃ 218-219 684i-C₃H₇ H H 3-NO₂ 2-CH₃-4-CF₂CF₂CF₃ 188-189 685 i-C₃H₇ H H 3-NO₂2-CH₃-4-CF(CF₃)₂ 248-250 686 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-(CF₂)₃CF₃ 225-226687 i-C₃H₇ H H 3-NO₂ 2-CH₃-3-OCH₃ 198-200 688 i-C₃H₇ H H 3-NO₂2-CH₃-4-OCH₃ 208-210 689 i-C₃H₇ H H 3-NO₂ 2,3-(CH₃)₂-4-OCH₃ 253-255 690i-C₃H₇ H H 3-NO₂ 2-CH₃-4-O—C₃H₇-i 233-234 691 i-C₃H₇ H H 3-NO₂3-CF₃-5-OCH₃ 214-216 692 i-C₃H₇ H H 3-NO₂ 2-CF₃-4-OCHF₂ 201-203 693i-C₃H₇ H H 3-NO₂ 3-CF₃-4-OCHF₂ 231-232 694 i-C₃H₇ H H 3-NO₂ 3-NO₂2,4-(CH₃)₂-3-OCH₃ 201-203 695 i-C₃H₇ H H 3-NO₂ 2-CH₃-3-OCHF₂ 200-202 696i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCHF₂ 186-188 697 i-C₃H₇ H H 3-NO₂2-CH₃-4-OCH₂CF₃ 241-243 698 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCF₂CBrF₂ 229-230699 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCH₂CF₂CHF₂ 199-200 700 i-C₃H₇ H H 3-NO₂2-CH₃-4-OCF₂CBrFCF₃ 224-226 701 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCH₂CHFOCF₃208-210 702 i-C₃H₇ H H 3-NO₂ 3-OCH₃-4-OCHF₂ 242-243 703 i-C₃H₇ H H 3-NO₂2-Cl-4-CF(CF₃)₂ 198-200 704 i-C₃H₇ H H 3-NO₂ 2-Cl-4-OCF₃ 188-190 705i-C₃H₇ H H 3-NO₂ 2-Br-4-OCF₃ 202-203 706 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-NO₂201-203 707 i-C₃H₇ H H 3-NO₂ 2-Cl-5-NO₂ 193-195 708 i-C₃H₇ H H 3-NO₂2-CH₃-5-NO₂ 197-199 709 i-C₃H₇ H H 3-NO₂ 2,3-(CH₃)₂-4-NO₂ 207-209 710i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCF₃ 184-186 711 i-C₃H₇ H H 3-NO₂2-CH₃-4-OCBrF₂ 217-218 712 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCF₂CHF₂ 205-207 713i-C₃H₇ H H 3-NO₂ 2-CH₃-3-OCF₂CHClF 164-166 714 i-C₃H₇ H H 3-NO₂2-CH₃-4-OCF₂CHClF 192-193 715 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCF₂CCl₂F 212-213716 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCF₂CHFCF₃ 198-199 717 i-C₃H₇ H H 3-NO₂2-CH₃-3-Cl-4-OCHF₂ 236-238 718 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCF₂CHF₂-5-Cl233-234 719 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-SCH₃ 214-216 720 i-C₃H₇ H H 3-NO₂2,3-(CH₃)₂-4-SCH₃ 254-256 721 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-SC₃H₇-i 209-211722 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-SCHF₂ 225-227 723 i-C₃H₇ H H 3-NO₂2-CH₃-4-N(CH₃)₂ 215-217 724 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-(3-CF₃—PhO) 174-175725 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-(F₅—PhO) 242-244 726 i-C₃H₇ H H 3-NO₂2-CH₃-4-(2-Cl-4-CF₃—PhO) 191-192 727 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-(4-Cl—PhS)165-167 728 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-(5-CF₃-2-Pyi-O) 216-218 729 i-C₃H₇H H 3-NO₂ 2-CH₃-4-(3-Cl-5-CF₃-2-Pyi-O) 236-238 730 i-C₃H₇ H H 3-NO₂4-(3-Cl-5-CF₃-2-Pyi-S) 190-192 731 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-P═O(OC₂H₅)₂128-130 732 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-P═S(OCH₃)₂ 128-130 733 i-C₃H₇ H H3-NO₂ -3-OCH₂O-4- 229-231 734 i-C₃H₇ H H 3-NO₂ 3-CH₂CH₂CH₂-4 209-211 735i-C₃H₇ H H 3-NO₂ 2-CH₂CH₂CH₂-3 226-228 736 i-C₃H₇ H H 3-NO₂3-N═C(CF₃)—NH-4 162-164 737 i-C₃H₇ H H 3-NO₂ 3-N═C(CF₃)—N(CH₃)-4 186-188738 i-C₃H₇ H H 5-NO₂ 2-CH₃-5-Cl 226-228 739 i-C₃H₇ H H 6-NO₂ 2-CH₃-5-Cl247-249 740 i-C₃H₇ H H 6-NO₂ 2-Cl-4-CF₃ Crystals 741 i-C₃H₇ H H 6-NO₂2-Cl-4-CF₂CF₂CF₃ 192-193 742 i-C₃H₇ H H 6-NO₂ 2-CH₃-4-CF₃ 239-240 743i-C₃H₇ H H 6-NO₂ 2-CH₃-4-OCF₂CHFCF₃ 252-253 744 i-C₃H₇ H H 3-CN2-CH₃-4-Cl 162-164 745 i-C₃H₇ H H 6-CN 2-CH₃-4-Cl Crystals 749 i-C₃H₇ HH 3-CH₃ 4-OCF₃ 180-182 750 i-C₃H₇ H H 3-CH₃ 2-CH₃-4-Cl 169-171 751i-C₃H₇ H H 3-CH₃ 2-CH₃-4-OCHF₂ 192-193 752 i-C₃H₇ H H 5-CH₃ 2-CH₃-5-Cl193-195 753 i-C₃H₇ H H 6-C₂H₅ 2-CH₃-4-Cl 180-182 754 i-C₃H₇ H H 3-CF₃ H202-204 755 i-C₃H₇ H H 3-CF₃ 2-CH₃-5-Cl 196-198 756 i-C₃H₇ H H 3-CF₃2-CH₃-3-Cl 216-218 757 i-C₃H₇ H H 3-CF₃ 2,6-(C₂H₅)₂ 238-239 758 i-C₃H₇ HH 3-CF₃ 2-CH₃-4-Cl 207-209 759 i-C₃H₇ H H 3-CF₃ 2-CH₃-4-OCHF₂ 212-213760 i-C₃H₇ H H 5-CF₃ 2,6-(C₂H₅)₂ 240-241 761 i-C₃H₇ H H 5-CF₃ 2-CH₃-4-Cl203-205 762 i-C₃H₇ H H 5-CF₃ 3-CF₃-5-OCH₃ 209-210 763 i-C₃H₇ H H 5-CF₃2-CH₃-4-OCHF₂ 196-197 764 i-C₃H₇ H H 6-CF₃ H 152-154 765 i-C₃H₇ H H6-CF₃ 2-CH₃-3-Cl 158-160 766 i-C₃H₇ H H 6-CF₃ 2-CH₃-5-Cl 273-275 767i-C₃H₇ H H 3-OCH₃ 4-OCF₃ 178-180 768 i-C₃H₇ H H 3-OCH₃ 2-CH₃-4-Br214-215 769 i-C₃H₇ H H 6-OCH₃ 4-OCF₃ 189-190 770 i-C₃H₇ H H 6-OCH₃2-CH₃-5-Cl 155-157 771 i-C₃H₇ H H 6-OCH₃ 2-CH₃-4-Br 195-197 772 i-C₃H₇ HH 3-OCHF₂ 2-CH₃-4-Cl 212-213 773 i-C₃H₇ H H 3-OCHF₂ 2-CH₃-5-Cl 198-200774 i-C₃H₇ H H 3-OCHF₂ 2-CH₃-4-OCHF₂ 174-175 775 i-C₃H₇ H H 4-OCHF₂2-CH₃-5-Cl 215-217 776 i-C₃H₇ H H 5-OCHF₂ 2-CH₃-5-Cl 173-175 777 i-C₃H₇H H 6-OCHF₂ 2-CH₃-4-Cl 224-226 778 i-C₃H₇ H H 6-OCHF₂ 2-CH₃-5-Cl 191-193779 i-C₃H₇ H H 6-OCHF₂ 2-CH₃-4-OCHF₂ 199-200 780 i-C₃H₇ H H 3-SCH₃2-CH₃-3-Cl 191-193 781 i-C₃H₇ H H 3-SCH₃ 2-CH₃-4-Cl 188-190 782 i-C₃H₇ HH 3-SCH₃ 2-CH₃-4-Br 185-187 783 i-C₃H₇ H H 3-SCH₃ 2-CH₃-4-OCHF₂ 159-161784 i-C₃H₇ H H 6-SCH₃ 2-CH₃-4-Br 201-202 785 i-C₃H₇ H H 6-SCH₃2-CH₃-3-Cl 207-209 786 i-C₃H₇ H H 6-SCH₃ 2-CH₃-4-Cl 204-206 787 i-C₃H₇ HH 6-SCH₃ 2-CH₃-4-OCHF₂ 212-214 788 i-C₃H₇ H H 3-SC₃H₇-i 2-CH₃-4-Cl183-184 789 i-C₃H₇ H H 6-SC₃H₇-i 2-CH₃-4-Cl 228-229 790 i-C₃H₇ H H3-SOCH₃ 2-CH₃-4-Br 125-130 791 i-C₃H₇ H H 3-SOCH₃ 2-CH₃-4-OCHF₂ 215-217792 i-C₃H₇ H H 6-SOCH₃ 2-CH₃-4-Br 203-208 793 i-C₃H₇ H H 3-SOC₃H₇-i2-CH₃-4-Cl 157-160 794 i-C₃H₇ H H 6-SOC₃H₇-i 2-CH₃-4-Cl 170-173 795i-C₃H₇ H H 3-SO₂CH₃ 2-CH₃-4-OCHF₂ 211-213 796 i-C₃H₇ H H 3-SO₂C₃H₇-i2-CH₃-4-Cl 240-242 797 i-C₃H₇ H H 3-SCH₂CF₃ 2-CH₃-4-OCHF₂ 184-186 798i-C₃H₇ H H 6-SCH₂CF₃ 2-CH₃-4-OCHF₂ 239-241 799 i-C₃H₇ H H 3-SOCH₂CF₃2-CH₃-4-OCHF₂ 198-200 800 i-C₃H₇ H H 6-SOCH₂CF₃ 2-CH₃-4-OCHF₂ 238-240801 i-C₃H₇ H H 6-C≡CH 2-CH₃-4-Cl 253-255 802 i-C₃H₇ H H 6-COOCH₃2-CH₃-4-Cl 149-151 803 i-C₃H₇ H H 3-CONHC₃H₇-i 2-CH₃-4-Cl 187-189 804i-C₃H₇ H H 6-CONHC₃H₇-i 2-CH₃-4-Cl 191-193 807 i-C₃H₇ H H 3-Ph2-CH₃-4-Cl 228-229 808 i-C₃H₇ H H 6-Ph 4-OCF₃ 213-214 809 i-C₃H₇ H H6-Ph 2-CH₃-4-Cl 254-256 810 i-C₃H₇ H H 3-O—Ph 2-CH₃-4-OCHF₂ 175-177 811i-C₃H₇ H H 6-O—Ph 2-CH₃-4-OCHF₂ 194-196 812 i-C₃H₇ H H 3-(4-Cl—PhO)2-CH₃-4-Br 204-206 813 i-C₃H₇ H H 3-S—Ph 2-CH₃-4-Cl 204-206 814 i-C₃H₇ HH 3-S—Ph 2-CH₃-4-Br 193-194 815 i-C₃H₇ H H 6-S—Ph 2-CH₃-4-Cl 211-213 816i-C₃H₇ H H 6-S—Ph 2-CH₃-4-Br 193-194 817 i-C₃H₇ H H 3-SO—Ph 2-CH₃-4-Cl201-203 818 i-C₃H₇ H H 3-SO₂—Ph 2-CH₃-4-Cl 189-191 819 i-C₃H₇ H H3-CH═CH—CH═CH-4 2-CH₃-4-OCHF₂ 158-160 820 i-C₃H₇ H H 5-CH═CH—CH═CH-62-CH₃-4-OCHF₂ 154-155 821 i-C₃H₇ H H 3-CH═CH—CH═CH-4 2-CH₃-5-Cl 156-158822 i-C₃H₇ H H 4-CH═CH—CH═CH-5 2-CH₃-5-Cl 229-231 823 i-C₃H₇ H H5-CH═CH—CH═CH-6 2-CH₃-5-Cl 232-234 824 i-C₃H₇ CH₃ H H 4-CF₃ 178-180 825i-C₃H₇ CH₃ H 3-NO₂ 2-CH₃-4-OCHF₂ 148-149 826 i-C₃H₇ CH₃ H H 2-CH₃-4-Cl82-83 827 i-C₃H₇ H CH₃ H 2-CH₃-4-Cl 165-166 828 i-C₃H₇ CH₂OCH₃ H H2-CH₃-4-Cl Oil 829 n-C₄H₉ H H H 4-CF₃ 171-173 830 n-C₄H₉ H H 3-NO₂2-CH₃-5-Cl 172-174 831 i-C₄H₉ H H 3-NO₂ 2-CH₃-5-Cl 186-188 832 i-C₄H₉ HH 3-NO₂ 2-CH₃-4-OCHF₂ 192-193 833 i-C₄H₉ H H H 4-CF₃ 149-151 834 i-C₄H₉CH₃ H 6-NO₂ 2-CH₃-4-OCHF₂ 135-137 835 s-C₄H₉ H H H 4-CF₃ 194-195 836s-C₄H₉ H H 3-Cl 2-CH₃-4-OCHF₂ 203-205 837 s-C₄H₉ H H 6-Cl 2-CH₃-4-OCHF₂213-215 838 s-C₄H₉ H H 3-NO₂ 2-CH₃-5-Cl 205-207 839 s-C₄H₉ H H 3-NO₂2-CH₃-4-OCHF₂ 228-229 840 t-C₄H₉ H H H H 237-239 841 t-C₄H₉ H H H2-CH₃-5-Cl 200-202 842 t-C₄H₉ H H 3-NO₂ 2-CH₃-5-Cl 256-258 843 t-C₄H₉ HH 3-NO₂ 2-CH₃-4-OCHF₂ 172-173 844 CH₂C(CH₃)₃ H H 3-NO₂ 2-CH₃-4-OCHF₂226-227 845 CH(C₂H₅)₂ H H 3-NO₂ 2-CH₃-4-OCHF₂ 245-246 846CH(CH₃)CH(CH₃)₂ H H 3-NO₂ 2-CH₃-4-OCHF₂ 245-247 847 n-C₈H₁₇ H H 3-NO₂2-CH₃-5-Cl 164-166 848 c-C₃H₅ H H H 4-CF₃ 195-197 849 c-C₃H₅ H H 3-Cl2-CH₃-4-OCHF₂ 156-158 850 c-C₃H₅ H H 6-Cl 2-CH₃-4-OCHF₂ 179-181 851c-C₃H₅ H H 3-NO₂ 2-CH₃-5-Cl 194-196 852 c-C₃H₅ H H 3-NO₂ 2-CH₃-4-OCHF₂191-192 853 c-C₄H₇ H H H 2-CH₃-5-Cl 205-207 854 c-C₄H₇ H H 3-NO₂2-CH₃-5-Cl 206-208 855 c-C₄H₇ H H 3-NO₂ 2-CH₃-5-F 199-201 856 c-C₅H₉ H H3-NO₂ 2-CH₃-4-OCHF₂ 219-220 857 c-C₅H₉ H H H 4-CF₃ 208-210 858 c-C₅H₉ HH 3-NO₂ 2-CH₃-5-Cl 200-202 859 c-C₅H₁₁ H H 3-NO₂ 2-CH₃-5-Cl 225-227 860CH₂—C₃H₅-c H H 3-NO₂ 2-CH₃-5-F 190-192 861 CH₂CH₂Cl H H 3-NO₂ 2-CH₃-5-F179-181 862 CH₂CH₂F H H 3-NO₂ 2-CH₃-5-F 179-181 863 CH₂CH₂F H H 3-NO₂2-CH₃-4-OCHF₂ 190-191 864 CH₂CF₃ H H H 2-CH₃-5-Cl 187-189 865 CH₂CH═CH₂H H H 4-CF₃ 161-163 866 CH₂CH═CH₂ H H 3-NO₂ 2-CH₃-5-Cl 175-177 867CH₂CH═CH₂ H H 3-NO₂ 2-CH₃-4-OCHF₂ 194-195 868 CH₂C≡CH H H H 4-CF₃185-188 869 CH₂C≡CH H H 3-NO₂ 2-CH₃-5-Cl 191-193 870 CH₂C≡CH H H 3-NO₂2-CH₃-4-OCHF₂ 190-191 871 CH₂CH₂OCH₃ H H 3-NO₂ 2-CH₃-5-Cl 165-167 872CH₂CH₂OCH₃ H H 3-NO₂ 2-CH₃-4-OCHF₂ 165-167 873 CH(CH₃)CH₂OCH₃ H H H4-CF₃ 252-253 874 CH(CH₃)CH₂OCH₃ H H 3-NO₂ 2-CH₃-4-OCHF₂ 153-155 875CH₂CH(OC₂H₅)₂ H H 3-NO₂ 2-CH₃-4-OCHF₂ 149-151 876 CH₂—Ph H H H 4-CF₃148-150 877 CH₂—Ph H H 3-NO₂ 2-CH₃-5-Cl 196-198 878 CH(CH₃)—Ph H H 3-NO₂2-CH₃-5-Cl 168-170 879 CH(CH₃)—Ph H H 3-NO₂ 2-CH₃-4-OCHF₂ 187-189 880CH₂CH₂O-(2,4- H H 3-NO₂ 2-CH₃-5-Cl 126-128 (CH₃)₂—Ph) 881 —CH₂CH₂CH₂CH₂—H H 4-CF₃ 170-171 882 —CH₂CH₂CH₂CH₂— H 6-NO₂ 2-CH₃-5-Cl 157-159 883—CH₂CH₂CH₂CH₂— H 6-NO₂ 2-CH₃-4-OCHF₂ 163-165 884 —CH₂CH₂OCH₂CH₂— H H4-CF₃ 167-168 885 —CH₂CH₂OCH₂CH₂— H 6-NO₂ 2-CH₃-5-Cl 192-194 886—CH₂CH₂OCH₂CH₂— H 6-NO₂ 2-CH₃-4-OCHF₂ 186-188 887 —CH₂CH(CH₃) H 6-NO₂3-CF₃-5-OCH₃ 164-165 OCH(CH₃)CH₂— 888 CH₂-3-Pyi H H 3-NO₂ 2-CH₃-4-Br180-182 889 i-C₃H₇ H H H 4-CF₂CF₃ 155-157 890 i-C₃H₇ H H 3-NO₂ 4-CF₂CF₃223-225 891 i-C₃H₇ H H 3-F 4-CF₂CF₃ 199-201 892 i-C₃H₇ H H 6-F 4-CF₂CF₃213-215 893 i-C₃H₇ H H 3-Cl 4-CF₂CF₃ 214-216 894 i-C₃H₇ H H 6-Cl4-CF₂CF₃ 225-227 895 i-C₃H₇ H H 3-I 4-CF₂CF₃ 208-210 896 i-C₃H₇ H H 6-I4-CF₂CF₃ 224-226 897 i-C₃H₇ H H H 2-CH₃-4-OSO₂-(4-CH₃—Ph) 135-137 898i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OSO₂-(4-CH₃—Ph) 208-210 899 i-C₃H₇ H H 3-Cl2-CH₃-4-OSO₂-(4-CH₃—Ph) 187-189 900 i-C₃H₇ H H 6-Cl2-CH₃-4-OSO₂-(4-CH₃—Ph) 218-220 901 i-C₃H₇ H H 3-F2-F-4-O-(4-CF₃-2-Cl—Ph) 137-139 902 i-C₃H₇ H H 6-F2-F-4-O-(4-CF₃-2-Cl—Ph) 155-157 903 i-C₃H₇ H H 3-Cl2-F-4-O-(4-CF₃-2-Cl—Ph) 119-121 904 i-C₃H₇ H H 6-Cl2-F-4-O-(4-CF₃-2-Cl—Ph) 154-156 905 i-C₃H₇ H H 3-F 2-CH₃-4-SCF₂CF₃140-142 906 i-C₃H₇ H H 6-F 2-CH₃-4-SCF₂CF₃ 162-164 907 i-C₃H₇ H H 3-Cl2-CH₃-4-SCF₂CF₃ 172-173 908 i-C₃H₇ H H 6-Cl 2-CH₃-4-SCF₂CF₃ 193-195 909i-C₃H₇ H H 3-I 2-CH₃-4-SCF₂CF₃ 207-209 910 i-C₃H₇ H H 6-I2-CH₃-4-SCF₂CF₃ 196-198 911 i-C₃H₇ H H 3-Cl 4-CH═C(Cl)CF₃ 196.3-208.2912 i-C₃H₇ H H 6-Cl 4-CH═C(Cl)CF₃ 202.8-209.4 913 i-C₃H₇ H H 3-Cl4-CH═CBr₂ 209.8-214.8 914 i-C₃H₇ H H 6-Cl 4-CH═CBr₂ 207.7-213.9 915i-C₃H₇ H H 3-Cl 4-CH═CCl₂ 120.1 916 i-C₃H₇ H H 6-Cl 4-CH═CCl₂ 199.7 917i-C₃H₇ H H 3-I 4-CH═C(Cl)CF₃ 196.6 918 i-C₃H₇ H H 6-I 4-CH═C(Cl)CF₃203.3 919 i-C₃H₇ H H 3-I 2-C₂H₅-4-I 195.5 920 i-C₃H₇ H H 6-I 2-C₂H₅-4-I242.3 921 C₂H₅ H H H 2-C₂H₅-3-Cl-6-C₂H₅ 171-173 922 i-C₃H₇ H H H2-C₂H₅-3-Cl-6-C₂H₅ 185-186 923 t-C₄H₉ H H H 2-C₂H₅-3-Cl-6-C₂H₅ 166-167924 t-C₃H₇ H H 3-Cl 2-C₂H₅-3-Cl-6-C₂H₅ 260-261 925 t-C₃H₇ H H 3-I2-C₂H₅-3-Cl-6-C₂H₅ 269-271 926 t-C₄H₉ H H 3-Cl 2-C₂H₅-3-Cl-6-C₂H₅221-222 927 t-C₄H₉ H H H 2-CH₃-4-Cl 216-218 928 t-C₄H₉ H H H 4-CF₃220-221 929 t-C₄H₉ H H H 4-OCF₃ 178-179 930 t-C₄H₉ H H H 2-CH₃-4-OCF₃184-185 931 t-C₄H₉ H H H 2-CH₃-4-CF₂CF₃ 223-224 932 t-C₄H₉ H H 3-Cl2-CH₃-4-CF₂CF₃ 219-220 933 t-C₄H₉ H CH₃ H 4-OCF₃ 155-158 934 t-C₄H₉ H H3-Cl 4-CF₃ 228-229 935 t-C₄H₉ H H 6-Cl 4-CF₃ 253-255 936 t-C₄H₉ H H 3-Cl4-OCF₃ 268-270 937 t-C₄H₉ H H 3-Cl 2-CH₃-4-Cl 242-244 938 t-C₄H₉ H H6-Cl 2-CH₃-4-Cl 262-264 939 t-C₄H₉ H H 3-I 4-CF₃ 268-269 940 t-C₄H₉ H H3-I 4-OCF₃ 263-265 941 t-C₄H₉ H H 3-I 2-CH₃-4-Cl 218-220 942 t-C₄H₉ H H3-I 2-CH₃-4-CF₂CF₃ 205-207 943 t-C₄H₉ H H 6-I 2-CH₃-4-CF₂CF₃ 216-217 944t-C₄H₉ H H 3-Cl 2-CH₃-4-OCF₃ 260-262 945 n-C₄H₉ H H 3-I 2-CH₃-4-CF₂CF₃173.1-178.5 946 n-C₄H₉ H H 6-I 2-CH₃-4-CF₂CF₃ 181.8-187.7 947 n-C₅H₁₁ HH 3-I 2-CH₃-4-CF₂CF₃ 140.2-151.4 948 n-C₅H₁₁ H H 6-I 2-CH₃-4-CF₂CF₃168.7-171.3 949 n-C₆H₁₃ H H 3-I 2-CH₃-4-CF₂CF₃ 135.5-143.9 950 n-C₆H₁₃ HH 6-I 2-CH₃-4-CF₂CF₃ 167.1-169.9 951 i-C₃H₇ H H 3-I 2-C₂H₅-4-I254.8-273.8 952 i-C₃H₇ H H 3-I 2-n-C₃H₇-4-I 179.7 953 i-C₃H₇ H H 3-CH₃2-CH₃-4-CF₂CF₃ 184-186 954 i-C₃H₇ H H 6-CH₃ 2-CH₃-4-CF₂CF₃ 177-179 955t-C₄H₉ H H 3-CH₃ 2-CH₃-4-CF₂CF₃ 198-200 956 t-C₄H₉ H H 6-CH₃2-CH₃-4-CF₂CF₃ 236-237 957 t-C₄H₉ H H 3-I 2-CH₃-4-OCF₃ 208-210 958t-C₄H₉ H H 6-I 2-CH₃-4-OCF₃ 253-255 959 n-C₃H₇ H H 3-I 2-CH₃-3-Cl190-192 960 n-C₃H₇ H H 6-I 2-CH₃-3-Cl 159-161 961 n-C₃H₇ H H 6-I2-C₂H₅-3-Cl-6-C₂H₅ 225-228 962 i-C₃H₇ H H 3-NO₂ 4-OCOCF₃ 185-187 963i-C₃H₇ H H 3-Cl 4-OCOCF₃ Paste 964 i-C₃H₇ H H 3-I 4-OCOCF₃ Paste 965i-C₃H₇ H H 3-I 2-i-C₃H₇-4-I 132.5 966 i-C₃H₇ H H 3-I 2-n-C₄H₉-4-I194.2-198.3 967 i-C₃H₇ H H 3-I 2-CH₃-4-Br-6-CH₃ 119.1 968 i-C₃H₇ H H3-Cl 4-CO₂CH(CF₃)₂ 168-170 969 i-C₃H₇ H H 3-I 4-CO₂CH(CF₃)₂ 193-195 970i-C₃H₇ H H 3-NO₂ 4-CO₂CH(CF₃)₂ 215-217 971 i-C₃H₇ H H 3-Cl2-CH₃-4-C≡C-(2,4-Cl₂—Ph) 123-125 972 i-C₃H₇ H H 3-I2-CH₃-4-C≡C-(2,4-Cl₂—Ph) 138-140 973 i-C₃H₇ H H 3-Cl 3-OCF₂CF₂-4 125-128974 i-C₃H₇ H H 3-I 3-OCF₂CF₂-4 123-126 975 i-C₃H₇ H H H 3-OCF₂CF₂O-4152-154 976 i-C₃H₇ H H 3-NO₂ 3-OCF₂CF₂O-4 247-248 977 i-C₃H₇ H H 3-Cl3-OCF₂CF₂O-4 224-226 978 i-C₃H₇ H H H 4-C(CF₃)₂OH 87-89 979 i-C₃H₇ H H3-NO₂ 4-C(CF₃)₂OH 205-207 980 i-C₃H₇ H H 3-Cl 4-C(CF₃)₂OH 187-189 981CH₂CH₂OCH₃ H H 3-I 2-CH₃-4-CF₂CF₃ 145.3-151.7 982 CH₂CH₂OCH₃ H H 6-I2-CH₃-4-CF₂CF₃ 166.7-169.4 983 CH₂CH₂OC₂H₅ H H 3-I 2-CH₃-4-CF₂CF₃146.5-150.3 984 CH₂CH₂OC₂H₅ H H 6-I 2-CH₃-4-CF₂CF₃ 157.3-160.4 985(CH₂)₃OCH₃ H H 3-I 2-CH₃-4-CF₂CF₃ 151.9-155.8 986 (CH₂)₃OCH₃ H H 6-I2-CH₃-4-CF₂CF₃ 156.5-158.8 987 CH₂CH═CH₂ H H 3-I 2-CH₃-4-CF₂CF₃ 157.5988 CH₂CH═CH₂ H H 6-I 2-CH₃-4-CF₂CF₃ 164.6-171.3 989 CH₂C≡CH H H 3-I2-CH₃-4-CF₂CF₃ 153.6-158.4 990 CH₂C≡CH H H 6-I 2-CH₃-4-CF₂CF₃171.5-178.1 991 c-C₅H₉ H H 3-I 2-CH₃-4-CF₂CF₃ 212.9 992 c-C₅H₉ H H 6-I2-CH₃-4-CF₂CF₃ 205.2 993 c-C₆H₁₁ H H 3-I 2-CH₃-4-CF₂CF₃ 219.7-224.3 994c-C₆H₁₁ H H 6-I 2-CH₃-4-CF₂CF₃ 239.0-244.4 995 i-C₃H₇ H H H 4-SCF₃182-184 996 i-C₃H₇ H H 3-NO₂ 4-SCF₃ 228-229 997 i-C₃H₇ H H 3-Cl 4-SCF₃229-231 998 i-C₃H₇ H H 3-I 4-SCF₃ 226-227 999 i-C₃H₇ H H H 4-SOCF₃175-178 1000 i-C₃H₇ H H 3-NO₂ 4-SOCF₃ 202-205 1001 i-C₃H₇ H H 3-Cl4-SOCF₃ 242-244 1002 i-C₃H₇ H H 3-I 4-SOCF₃ 229-231 1003 i-C₃H₇ H H 3-I3-OCF₂CF₂O-4 163-165 1004 i-C₃H₇ H H 3-I 4-C(CF₃)₂OH 227-229 1005 i-C₄H₉H H 3-I 2-CH₃-4-CF₂CF₃ 200.4-206.8 1006 i-C₄H₉ H H 6-I 2-CH₃-4-CF₂CF₃179.2-181.8 1007 s-C₄H₉ H H 3-I 2-CH₃-4-CF₂CF₃ 226.0-230.9 1008 s-C₄H₉ HH 6-I 2-CH₃-4-CF₂CF₃ 216.1-218.0 1009 s-C₅H₁₁ H H 3-I 2-CH₃-4-CF₂CF₃215.3-218.2 1010 s-C₅H₁₁ H H 6-I 2-CH₃-4-CF₂CF₃ 191.4-210.5 1011CH(C₂H₅)₂ H H 3-I 2-CH₃-4-CF₂CF₃ 234.8-236.9 1012 CH(C₂H₅)₂ H H 6-I2-CH₃-4-CF₂CF₃ 253.7-255.7 1013 CH(C₂H₅)CH₂O—CH₃ H H 3-I 2-CH₃-4-CF₂CF₃177   1014 CH(C₂H₅)CH₂O—CH₃ H H 6-I 2-CH₃-4-CF₂CF₃ 198.3-201.0 1015i-C₅H₁₁ H H 3-I 2-CH₃-4-CF₂CF₃ 190.0-192.5 1016 i-C₅H₁₁ H H 6-I2-CH₃-4-CF₂CF₃ 187.8 1017 i-C₃H₇ H H 3-I 2-C₂H₅-4-CF₂CF₃ 232.5-235.81018 t-C₄H₉ H H H 2-CH₃-4-OCHF₂ 138-140 1019 t-C₄H₉ H H 3-Cl2-CH₃-4-OCHF₂ 206-208 1020 t-C₄H₉ H H 3-I 2-CH₃-4-OCHF₂ 204-206 1021t-C₄H₉ H H H 2-Cl-4-OCF₃ 162-164 1022 t-C₄H₉ H H 3-Cl 2-Cl-4-OCF₃189-191 1023 t-C₄H₉ H H 3-I 2-Cl-4-OCF₃ 188-190 1024 c-C₃H₅ H H 3-I2-CH₃-4-CF₂CF₃ 156.0-165.0 1025 c-C₃H₅ H H 6-I 2-CH₃-4-CF₂CF₃173.2-176.4 1026 CH₂CH(CH₃)—C₂H₅ H H 3-I 2-CH₃-4-CF₂CF₃ 148.6 1027CH₂CH(CH₃)—C₂H₅ H H 6-I 2-CH₃-4-CF₂CF₃ 157.8 1028 CH₂-c-C₆H₁₁ H H 3-I2-CH₃-4-CF₂CF₃ 186.8-188.7 1029 CH₂(4-t-C₄H₉-c-C₆H₁₁) H H 3-I2-CH₃-4-CF₂CF₃ 226.0-231.2 1030 CH₂(4-t-C₄H₉-c-C₆H₁₁) H H 6-I2-CH₃-4-CF₂CF₃ 215.4 1031 CH(CH₃)CH₂O—CH₃ H H 3-I 2-CH₃-4-CF₂CF₃187.2-189.9 1032 CH(CH₃)CH₂O—CH₃ H H 6-I 2-CH₃-4-CF₂CF₃ 169.7-176.1 1033CH(CH₃)CH—(CH₃)₂ H H 3-I 2-CH₃-4-CF₂CF₃ 208.3-212.7 1034CH(CH₃)CH—(CH₃)₂ H H 6-I 2-CH₃-4-CF₂CF₃ 219.3-223.0 1035 C₂H₅ C₂H₅ H 3-I2-CH₃-4-CF₂CF₃ 131.3 1036 C₂H₅ C₂H₅ H 6-I 2-CH₃-4-CF₂CF₃ 137   1037t-C₄H₉ H H H 2-CH₃-4-CF(CF₃)₂ 172-175 1038 t-C₄H₉ H H 3-Cl2-CH₃-4-CF(CF₃)₂ 241-243 1039 t-C₄H₉ H H 3-I 2-CH₃-4-CF(CF₃)₂ 238-2401040 CH₂CF₃ H H 3-I 2-CH₃-4-CF₂CF₃ 166.1-175.5 1041 CH₂CF₃ H H 6-I2-CH₃-4-CF₂CF₃ 184.7-202.5 1042 i-C₃H₇ CH₃ H 3-I 2-CH₃-4-CF₂CF₃ 201.41043 i-C₄H₉ CH₃ H 3-I 2-CH₃-4-CF₂CF₃ 183.5-189.0 1044 n-C₃H₇ n-C₃H₇ H3-I 2-CH₃-4-CF₂CF₃ 142.6-145.4 1045 CH₂CH═CH₂ CH₂CH═ H 3-I2-CH₃-4-CF₂CF₃ 100.2-105.6 CH₂ 1046 CH₂CH₂O—C₂H₅ CH₂CH₂O— H 3-I2-CH₃-4-CF₂CF₃ 84.0-87.3 C₂H₅ 1047 CH₂CH₂CH₂CH₂ H 3-I 2-CH₃-4-CF₂CF₃172.7-177.3 1048 C₂H₅ C₂H₅ H 3-I 2-CH₃-4-CF₂CF₃ 119.1 1049 t-C₄H₉ H H H2-CH₃-4-OCBrF₂ 195-197 1050 t-C₄H₉ H H 3-Cl 2-CH₃-4-OCBrF₂ 198-200 1051t-C₄H₉ H H 3-I 2-CH₃-4-OCBrF₂ 196-198 1052 t-C₄H₉ H H H 4-C(CF₃)₂OH123-125 1053 t-C₄H₉ H H 3-Cl 4-C(CF₃)₂OH 185-187 1054 t-C₄H₉ H H 3-I4-C(CF₃)₂OH 203-205 1055 i-C₃H₇ H H 3-I 2,4-F₂ 236-237 1056 C₂H₅ H H 3-I2-CH₃-4-OCF₂—CHF₂ 176-178 1057 C₂H₅ H H 6-I 2-CH₃-4-OCF₂—CHF₂ 207-2091058 n-C₃H₇ H H 3-I 2-CH₃-4-OCF₂—CHF₂ 185-187 1059 n-C₃H₇ H H 6-I2-CH₃-4-OCF₂—CHF₂ 215-217 1060 t-C₄H₉ H H H 2-CH₃-4-OCF₂—CHF₂ 197-1981061 t-C₄H₉ H H 3-Cl 2-CH₃-4-OCF₂—CHF₂ 192-194 1062 t-C₄H₉ H H 3-I2-CH₃-4-OCF₂—CHF₂ 217-218 1063 i-C₃H₇ H H 3-Cl2-CH₃-4-O-(3,5-(CH₃O)₂-2-Pym) 186-188 1064 i-C₃H₇ H H 3-I2-CH₃-4-O-(3,5-(CH₃O)₂-2-Pym) 201-202 1065 t-C₄H₉ H H H 3-OCF₂CF₂O-4156-158 1066 t-C₄H₉ H H 3-Cl 3-OCF₂CF₂O-4 240-241 1067 t-C₄H₉ H H 3-I3-OCF₂CF₂O-4 252-253 1068 CH₃ CH₃ H 3-I 2-CH₃-4-CF₂CF₃ 148.7 1069 n-C₃H₇CH₃ H 3-I 2-CH₃-4-CF₂CF₃ 129.3 1070 CH₂CH₂OCH₂CH₂ H 3-I 2-CH₃-4-CF₂CF₃164.7 1071 i-C₃H₇ i-C₃H₇ H H 2-CH₃-4-CF₂CF₃ 169.1 1072 i-C₃H₇ i-C₃H₇ H6-I 2-CH₃-4-CF₂CF₃ 201.2 1073 C₂H₅ H H 3-I 2-CH₃-4-CF(CF₃)₂ 194-195 1074C₂H₅ H H 6-I 2-CH₃-4-CF(CF₃)₂ 218-220 1075 n-C₃H₇ H H 3-I2-CH₃-4-CF(CF₃)₂ 188-190 1076 n-C₃H₇ H H 6-I 2-CH₃-4-CF(CF₃)₂ 201-2031077 i-C₃H₇ H H H 4-SO₂CF₃ 184-186 1078 i-C₃H₇ H H 3-Cl 4-SO₂CF₃ 239-2411079 i-C₃H₇ H H 3-I 4-SO₂CF₃ 225-227 1080 t-C₄H₉ H H 3-I 4-SO₂CF₃230-232 1081 i-C₃H₇ i-C₃H₇ H 3-I 2-CH₃-4-CF₂CF₃ Paste 1082CH₂CH₂CH₂CH₂CH₂ H 3-I 2-CH₃-4-CF₂CF₃ 140.0-146.8 1083CH₂CH₂CH(CH₃)CH₂—CH₂— H 3-I 2-CH₃-4-CF₂CF₃ 171.4 1086 i-C₃H₇ H H H2-CH₃-4-OCF₂CH₂—Ph 138-140 1087 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₂CF₂—Ph160-162 1088 i-C₃H₇ H H 3-I 2-CH₃-4-OCF₂CF₂—Ph 209-211 1089 i-C₃H₇ H H3-NO₂ 2-CH₃-4-OCF₂CF₂—Ph 190-192 1090 i-C₃H₇ H H H2-CH₃-4-SCH₂CH₂—CF═CF₂ 190-192 1091 i-C₃H₇ H H H 2-CH₃-4-SOCH₂CH₂—CF═CF₂149-153 1092 i-C₃H₇ H H H 2-CH₃-4-SO₂CH₂—CH₂CF═CH₂ 183-185 1093 i-C₃H₇ HH 3-Cl 2-CH₃-4-SCH₂CH₂—CF═CF₂ 168-170 1094 i-C₃H₇ H H 3-Cl2-CH₃-4-SOCH₂CH₂—CF═CF₂ 164-167 1095 i-C₃H₇ H H 3-Cl2-CH₃-4-SO₂CH₂—CH₂CF═CF₂ 181-183 1096 i-C₃H₇ H H 3-I2-CH₃-4-SCH₂CH₂—CF═CF₂ 193-195 1097 i-C₃H₇ H H 3-I2-CH₃-4-SOCH₂CH₂—CF═CF₂ 182-186 1098 i-C₃H₇ H H 3-I2-CH₃-4-SO₂CH₂—CH₂CF═CF₂ 208-210 1099 i-C₃H₇ H H H 3-OCF₂O-4 216-2181100 i-C₃H₇ H H 3-NO₂ 3-OCF₂O-4 227-229 1101 i-C₃H₇ H H 3-Cl 3-OCF₂O-4243-245 1102 i-C₃H₇ H H 3-I 3-OCF₂O-4 229-231 1103 t-C₄H₉ H H H3-OCF₂O-4 209-211 1104 t-C₄H₉ H H 3-Cl 3-OCF₂O-4 206-208 1105 t-C₄H₉ H H3-I 3-OCF₂O-4 228-230 1106 i-C₃H₇ H H H 4-SCBrF₂ 175-177 1107 i-C₃H₇ H HH 4-SOCBrF₂ 158-161 1108 i-C₃H₇ H H 3-NO₂ 4-SCBrF₂ 180-182 1109 i-C₃H₇ HH 3-NO₂ 4-SOCBrF₂ 195-198 1110 i-C₃H₇ H H 3-Cl 4-SCBrF₂ 156-158 1111i-C₃H₇ H H 3-Cl 4-SOCBrF₂ 218-220 1112 i-C₃H₇ H H 3-I 4-SCBrF₂ 206-2081113 i-C₃H₇ H H 3-I 4-SOCBrF₂ 158-160 1114 t-C₄H₉ H H 3-Cl 4-SCBrF₂210-212 1115 t-C₄H₉ H H 3-I 4-SCBrF₂ 219-220 1116 C₂H₅ C₂H₅ H 3-I2-CH₃-4-CF₂CF₃ 179.8-183.7 1117 CH₂CH₂CH₂—CH₂CH₂CH₂ H 3-I 2-CH₃-4-CF₂CF₃170.7 1118 C₂H₅ C₂H₅ H 3-NO₂ 2-CH₃-4-OCF₃ 161.9 1119 C₂H₅ C₂H₅ H 3-NO₂2-CH₃-4-CF(CF₃)₂ 169.1 1120 CH₃ CH₃ CH₃ 3-I 2-CH₃-4-CF₂CF₃ 141.9-146.61121 i-C₃H₇ CH₃ CH₃ 3-I 2-CH₃-4-CF₂CF₃ Paste 1122 C₂H₅ C₂H₅ CH₃ 3-I2-CH₃-4-CF₂CF₃ Paste 1123 t-C₃H₇ H H H 4-SCF₃ 135-137 1124 t-C₃H₇ H H3-NO₂ 4-SCF₃ 187-189 1125 t-C₃H₇ H H 3-Cl 4-SCF₃ 192-194 1126 t-C₃H₇ H H3-I 4-SCF₃ 194-196 1127 t-C₄H₉ H H 3-I 4-SCF₃ 195-197 1128 C₂H₅ C₂H₅ H3-I 4-SCF₃ 173-175 1129 C₂H₅ C₂H₅ H 3-I 3-OCF₂O-4 128-130 1130 C₂H₅ C₂H₅H 3-I 4-C(CF₃)₂OH 152-154 1131 C₂H₅ C₂H₅ H 3-NO₂ 2-CH₃-4-OCF₃178.7-182.6 1132 C₂H₅ C₂H₅ H 3-NO₂ 2-CH₃-4-OCF₂CHF₂ 160.8-165.0 1133C₂H₅ C₂H₅ H 3-NO₂ 2-Cl-4-CF₂CF₃ 91.9-95.2 1134 C₂H₅ C₂H₅ H 3-NO₂2-F-4-CF₂CF₃ 162.6-166.8 1135 C₂H₅ C₂H₅ H 3-NO₂ 2-CH₃-4-Cl 188.8-190.81136 C₂H₅ C₂H₅ H 3-NO₂ 4-OCF₃ 185.7-187.9 1137 C₂H₅ C₂H₅ H 6-NO₂2-CH₃-4-OCF₂CHF₂ 111.2 1138 C₂H₅ C₂H₅ H 6-NO₂ 2-CH₃-4-Cl 149.7 1139 C₂H₅C₂H₅ H 6-NO₂ 4-OCF₃ 173.4 1140 CH₂CH(CH₃)CH₂— H 6-I 2-CH₃-4-CF₂CF₃ 166.4CH(CH₃)CH₂ 1141 t-C₄H₉ H H 3-I 2-CH₃-4-CF₃ 197-198 1142 i-C₃H₇ H H 3-I3-N═C(CF₂CF₃)O-4 214-216 1143 t-C₄H₉ H H 3-I 3-N═C(CF₂CF₃)O-4 253-2541144 C₂H₅ C₂H₅ H 3-I 2-CH₃-4-CF₃ 160-161 1145 i-C₃H₇ H H H 3-OCHFCF₂O-4102-104 1146 i-C₃H₇ H H 3-NO₂ 3-OCHFCF₂O-4 190-192 1147 i-C₃H₇ H H 3-Cl3-OCHFCF₂O-4 123-125 1148 i-C₃H₇ H H 3-I 3-OCHFCF₂O-4 218-220 1149t-C₄H₉ H H H 3-OCHFCF₂O-4 165-167 1150 t-C₄H₉ H H 3-I 3-OCHFCF₂O-4240-241 1151 C₂H₅ C₂H₅ H 3-I 3-OCHFCF₂O-4 193-195 1152 t-C₅H₁₁ H H 3-F2-CH₃-4-CF₂CF₃ 223.3 1153 t-C₅H₁₁ H H 3-F 2-CH₃-4-CF(CF₃)₂ 222   1154t-C₅H₁₁ H H 3-F 2-CH₃-4-OCF₃ 193.6-195.8 1155 t-C₅H₁₁ H H 3-F2-CH₃-4-OCHF₂ 165.5-174.0 1156 n-C₃H₇ n-C₃H₇ H 3-I 2-CH₃-4-OCF₃132.2-135.0 1157 n-C₃H₇ n-C₃H₇ H 3-I 2-CH₃-4-OCHF₂ 81.4-87.8 1158 n-C₃H₇n-C₃H₇ H 3-I 2-CH₃-4-OCF₂CHF₂ 116.3 1159 i-C₃H₇ C₂H₅ H 3-I2-CH₃-4-CF₂CF₃ 124.4 1160 i-C₃H₇ C₂H₅ H 3-I 4-OCF₃ 137.3-144.1 1161i-C₃H₇ H H 3-I 3-OCF₂CHFO-4 161-13 1162 i-C₃H₇ H H 3-NO₂ 3-OCF₂CHFO-4238-240 1163 i-C₃H₇ H H 3-Cl 3-OCF₂CHFO-4 243-245 1164 i-C₃H₇ H H 3-I3-OCF₂CHFO-4 192-194 1165 t-C₄H₉ H H H 3-OCF₂CHFO-4 205-207 1166 t-C₄H₉H H 3-I 3-OCF₂CHFO-4 238-240 1167 C₂H₅ C₂H₅ H 3-I 3-OCF₂CHFO-4 195-1971168 i-C₃H₇ H H 3-I 2-CH₃-4-SOCF₃ 148-152 1169 t-C₄H₉ H H 3-I2-CH₃-4-SOCF₃ 165-168 1173 i-C₃H₇ H H 3-I 3-N═C(4-CF₃—Ph)—O-4 253-2551174 t-C₄H₉ H H 3-I 3-N═C(4-CF₃—Ph)—O-4 251-253 1175 C₂H₅ C₂H₅ H 3-I3-N═C(4-CF₃—Ph)—O-4 231-233 1176 i-C₃H₇ H H 3-I 3-O—C(2-CF₃—Ph)═N-4242-244 1177 t-C₄H₉ H H 3-I 3-O—C(2-CF₃—Ph)═N-4 229-231 1178 C₂H₅ C₂H₅ H3-I 3-O—C(2-CF₃—Ph)═N-4 203-205 1179 C₂H₅ C₂H₅ C₂H₅ 3-I 2-CH₃-4-CF₂CF₃Paste 1180 i-C₃H₇ H H 3-I 3-O—C(CF₂CF₃)═N-4 130-132 1181 t-C₄H₉ H H 3-I3-O—C(CF₂CF₃)═N-4 205-207 1182 C₂H₅ C₂H₅ H 3-I 3-O—C(CF₂CF₃)═N-4 188-1901183 i-C₃H₇ H H 3-CF₃ 2-CH₃-4-OCF₃ 222-224 1184 i-C₃H₇ H H 3-CF₃2-CH₃-4-CF₂CF₃ 219-221 1185 C₂H₅ C₂H₅ H 3-CF₃ 2-CH₃-4-OCF₃ 192-194 1186C₂H₅ C₂H₅ H 3-CF₃ 2-CH₃-4-CF₂CF₃ 218-220 1187 i-C₃H₇ H H 3-Cl 2-F-4-OCF₃126-128 1188 i-C₃H₇ H H 3-I 2-F-4-OCF₃ 220-222 1189 t-C₄H₉ H H 3-I2-F-4-OCF₃ 198-200 1190 C₂H₅ C₂H₅ H 3-I 2-F-4-OCF₃ 129-131 1191 i-C₃H₇ HH 3-OCF₃ 2-CH₃-4-CF₂CF₃ 190-192 1192 t-C₄H₉ H H 3-OCF₃ 2-CH₃-4-CF₂CF₃205-207 1193 C₂H₅ C₂H₅ H 3-OCF₃ 2-CH₃-4-CF₂CF₃ 146-148 1202 i-C₃H₇ H H4-I 2-CH₃-4-CF₂CF₃ 197-199 1203 i-C₃H₇ H H 5-I 2-CH₃-4-CF₂CF₃ 201-2031204 i-C₃H₇ H H 4-I 2-CH₃-4-OCHF₂ 241-243 1205 i-C₃H₇ H H 5-I2-CH₃-4-OCHF₂ 214-216 1206 i-C₃H₇ H H 3-CF₃ 2-CH₃-4-OCF₂CHF₂ 195-1971207 i-C₃H₇ H H 3-CF₃ 2-CH₃-4-CF(CF₃)₂ 227-229 1208 i-C₃H₇ H H H2-C₂H₅-4-OCF₃ 160-162 1209 i-C₃H₇ H H 3-Cl 2-C₂H₅-4-OCF₃ 205-207 1210i-C₃H₇ H H 3-I 2-C₂H₅-4-OCF₃ 241-243 1211 t-C₄H₉ H H 3-I 2-C₂H₅-4-OCF₃224-225 1212 C₂H₅ C₂H₅ H 3-I 2-C₂H₅-4-OCF₃ 141-143 1221 i-C₃H₇ H H3,4-Cl₂ 2-CH₃-4-OCF₃ 199-200 1222 i-C₃H₇ H H 3,4-Cl₂ 2-CH₃-4-CF₂CF₃208-209 1223 i-C₃H₇ H H 3,4-Cl₂ 2-CH₃-4-CF(CF₃)₂ 228-229 1224 i-C₃H₇ H H3,5-Cl₂ 2-CH₃-4-OCF₃ 228-230 1225 i-C₃H₇ H H 3,5-Cl₂ 2-CH₃-4-CF₂CF₃219-220 1226 i-C₃H₇ H H 3,5-Cl₂ 2-CH₃-4-CF(CF₃)₂ 211-212 1227 i-C₃H₇ H H3-Cl-4-F 2-CH₃-4-OCF₃ 184-186 1228 i-C₃H₇ H H 3-Cl-4-F 2-CH₃-4-CF₂CF₃178-180 1229 i-C₃H₇ H H 3-Cl-4-F 2-CH₃-4-CF(CF₃)₂ 200-201 1230 t-C₄H₉ HH 3-CF₃ 2-CH₃-4-OCF₃ 209-210 1231 t-C₄H₉ H H 3-CF₃ 2-CH₃-4-CF₂CF₃210-211 1232 t-C₄H₉ H H 3-CF₃ 2-CH₃-4-CF(CF₃)₂ 242-243 1233 i-C₃H₇ H H3-OCF₃ 2-CH₃-4-OCF₃ 219-220 1234 t-C₄H₉ H H 3-OCF₃ 2-CH₃-4-OCF₃ 222-2231235 C₂H₅ C₂H₅ H 3-OCF₃ 2-CH₃-4-OCF₃ 125-126 1236 i-C₃H₇ H H 3-OCF₃2-CH₃-4-CF(CF₃)₂ 235-236 1237 t-C₄H₉ H H 3-OCF₃ 2-CH₃-4-CF(CF₃)₂ 220-2221238 C₂H₅ C₂H₅ H 3-OCF₃ 2-CH₃-4-CF(CF₃)₂ 156-157 1245 i-C₃H₇ H H 3-CN2-CH₃-4-CF₂CF₃ 168-170 1246 i-C₃H₇ H H 4-I 2-CH₃-4-OCF₃ 238-240 1247i-C₃H₇ H H 5-I 2-CH₃-4-OCF₃ 205-206 1248 i-C₃H₇ H H 4-I 2-CH₃-4-OCF₂CHF₂222-223 1249 i-C₃H₇ H H 5-I 2-CH₃-4-OCF₂CHF₂ 203-204 1250 i-C₃H₇ H H 4-I2-CH₃-4-CF(CF₃)₂ 215-216 1251 i-C₃H₇ H H 5-I 2-CH₃-4-CF(CF₃)₂ 216-2171256 i-C₃H₇ H H 3-Cl-4-F 2-CH₃-4-CF₂CF₃ 235-236 1257 t-C₄H₉ H H 3-Cl-4-F2-CH₃-4-CF₂CF₃ 225-226 1258 C₂H₅ C₂H₅ H 3-Cl-4-F 2-CH₃-4-CF₂CF₃ 155-1561259 i-C₃H₇ H H 3-Cl-4-F 2-CH₃-4-OCF₃ 229-231 1260 t-C₄H₉ H H 3-Cl-4-F2-CH₃-4-OCF₃ 237-238 1261 C₂H₅ C₂H₅ H 3-Cl-4-F 2-CH₃-4-OCF₃ 140-141 1262i-C₃H₇ H H 3-Cl-4-F 2-CH₃-4-CF(CF₃)₂ 264-265 1263 t-C₄H₉ H H 3-Cl-4-F2-CH₃-4-CF(CF₃)₂ 253-154 1264 C₂H₅ C₂H₅ H 3-Cl-4-F 2-CH₃-4-CF(CF₃)₂158-159 1266 i-C₃H₇ H H 3,4-Br₂ 2-CH₃-4-CF₂CF₃ 162-164 1277 i-C₃H₇ H H4-Cl 2-CH₃-4-CF₂CF₃ 185-186 1278 t-C₄H₉ H H 4-Cl 2-CH₃-4-CF₂CF₃ 206-2071280 C₂H₅ C₂H₅ H 4-Cl 2-CH₃-4-CF₂CF₃ 163-164 1281 C₂H₅ C₂H₅ H 4-Cl-6-I2-CH₃-4-CF₂CF₃ 193-194 1283 i-C₃H₇ H H 3,4-F₂ 2-CH₃-4-OCF₃ 194-195 1284t-C₄H₉ H H 3,4-F₂ 2-CH₃-4-OCF₃ 216-217 1285 C₂H₅ C₂H₅ H 3,4-F₂2-CH₃-4-OCF₃ 156-157 1287 i-C₃H₇ H H 4,5-F₂ 2-CH₃-4-OCF₃ 195-196 1288t-C₄H₉ H H 4,5-F₂ 2-CH₃-4-OCF₃ 223-224 1290 i-C₃H₇ H H 3-I 2-CH₃-4-OC—226-227 (CF₂CF₃)═C—(CF₃)₂ 1291 i-C₃H₇ H H 3-Cl 2-CH₃-4-OC— 204-205(CF₂CF₃)═C—(CF₃)₂ 1292 i-C₃H₇ H H 3-I 2-CH₃-4-OC— 198-199(OCH₃)═C—(CF₃)₂ 1293 i-C₃H₇ H H 3-Cl 2-CH₃-4-OC— 179-180 (OCH₃)═C—(CF₃)₂1294 CH(CH₃)CH₂OH H H H 2-CH₃-4-C₂F₅ 73-74 1295 i-C₃H₇ H H 6-Cl2-OCH₃-5-Ph 120   1296 i-C₃H₇ H H 3-Cl 2-OCH₃-5-Ph 195   1297 n-C₃H₇ H H6-Cl 2-OCH₃-5-Ph 200   1298 CH(CH₃)CH₂OH H H 3-Cl 2-CH₃-4-C₂F₅ 195  1299 CH(C₂H₅)CH₂OH H H H 2-CH₃-4-C₂F₅ 78  1300 CH(CH₃)CH₂OH H H 3-I2-CH₃-4-C₂F₅ 98-99 1301 i-C₃H₇ H H 3-Cl 2-CH₃-4-C≡C—C₄H₉-t 210   1302i-C₃H₇ H H 6-Cl 2-CH₃-4-C≡C—C₄H₉-t 205   1303 n-C₃H₇ H H 3-I2-CH₃-4-C₂F₅ 200   1304 n-C₃H₇ H H 6-I 2-CH₃-4-C₂F₅ 195   1305 i-C₃H₇ HH 3-I 2-CH₃-4-C≡C—C₄H₉-t 205   1306 i-C₃H₇ H H 6-I 2-CH₃-4-C≡C—C₄H₉-t170   1307 CH₂—Ph H H 3-Cl 2-CH₃-4-C₂F₅ 175   1308 CH₂—Ph H H 6-Cl2-CH₃-4-C₂F₅ 175   1309 CH₂-(2-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 170   1310CH₂-(2-Cl—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 210   1311 CH₃ H H 3-I 2-CH₃-4-C₂F₅190   1312 CH₃ H H 6-I 2-CH₃-4-C₂F₅ 200   1313 C₂H₅ H H 3-I 2-CH₃-4-C₂F₅182   1314 C₂H₅ H H 6-I 2-CH₃-4-C₂F₅ 205   1315 CH₂CH(OH)CH₃ H H 3-Cl2-CH₃-4-C₂F₅ 187   1316 CH(C₂H₅)CH₂OH H H 3-Cl 2-CH₃-4-C₂F₅ 208   1317C(CH₃)₂CH₂OH H H 3-Cl 2-CH₃-4-C₂F₅ 181-182 1318 CH₂CH(OH)C₂H₅ H H 3-Cl2-CH₃-4-C₂F₅ 171-172 1319 CH₂CH₂—Ph H H 3-Cl 2-CH₃-4-C₂F₅ 150   1320CH₂CH₂—Ph H H 6-Cl 2-CH₃-4-C₂F₅ 190   1321 CH(CH₃)—Ph H H 3-Cl2-CH₃-4-C₂F₅ 160   1322 CH(CH₃)—Ph H H 6-Cl 2-CH₃-4-C₂F₅ 190   1323i-C₃H₇ H H 3-Cl 2-CH₃-4-CH₂CH₂C(CH₃)₃ 220   1324 i-C₃H₇ H H 6-Cl2-CH₃-4-CH₂CH₂C(CH₃)₃ 205   1325 i-C₃H₇ H H 3-Cl 2-CH₃-4-C≡C—Ph 215  1326 i-C₃H₇ H H 6-Cl 2-CH₃-4-C≡C—Ph 230   1327 O-n-C₃H₇ H H 3-Cl2-CH₃-4-C₂F₅ 165   1328 O-n-C₃H₇ H H 6-Cl 2-CH₃-4-C₂F₅ 150   1329O—CH₂CH═CHCl H H 3-Cl 2-CH₃-4-C₂F₅ 150   (E) 1330 i-C₃H₇ H H 3-Cl2-CH₃-4-CN 230   1331 (CH₂)₃—Ph H H 3-Cl 2-CH₃-4-C₂F₅ 112   1332(CH₂)₃—Ph H H 6-Cl 2-CH₃-4-C₂F₅ 105   1333 CH₂(4-Cl—Ph) H H 3-Cl2-CH₃-4-C₂F₅ 198   1334 CH₂(4-Cl—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 156   1335CH₂(3-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 168   1336 CH₂(3-Cl—Ph) H H 6-Cl2-CH₃-4-C₂F₅ 177   1337 CH₂(2-CH₃—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 152   1338CH₂(2-CH₃—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 147   1339 CH₂(3-CH₃—Ph) H H 3-Cl2-CH₃-4-C₂F₅ Crystals 1340 CH₂(3-CH₃—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 173  1341 CH₂(4-CH₃—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 175   1342 CH₂(4-CH₃—Ph) H H6-Cl 2-CH₃-4-C₂F₅ Crystals 1343 CH₂(2-CH₃O—Ph) H H 3-Cl 2-CH₃-4-C₂F₅Crystals 1344 CH₂(2-CH₃O—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 176   1345CH₂(3-CH₃O—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 73  1346 CH₂(3-CH₃O—Ph) H H 6-Cl2-CH₃-4-C₂F₅ 86  1347 CH₂(4-CH₃O—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 169   1348CH₂(4-CH₃O—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 168   1349 CH₂(2,4-Cl₂—Ph) H H 3-Cl2-CH₃-4-C₂F₅ 169   1350 CH₂(2,4-Cl₂—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 205   1351CH₂(3,4-Cl₂—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 179   1352 CH₂(3,4-Cl₂—Ph) H H6-Cl 2-CH₃-4-C₂F₅ 192   1353 CH₂(2,3-Cl₂—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 179  1354 CH₂(2,3-Cl₂—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 208   1355 CH₂-2-Pyi H H 3-Cl2-CH₃-4-C₂F₅ 143   1356 (CH₂)₂(2-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 141   1357(CH₂)₂(2-Cl—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ Paste 1358 (CH₂)₂(3-Cl—Ph) H H3-Cl 2-CH₃-4-C₂F₅ 117   1359 (CH₂)₂(3-Cl—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ Paste1360 (CH₂)₂(4-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 118   1361 (CH₂)₂(4-Cl—Ph) HH 6-Cl 2-CH₃-4-C₂F₅ 138   1362 CH(CH₃)(2-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅Paste 1363 CH(CH₃)(2-Cl—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 197   1364CH(CH₃)(3-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 100   1365 CH(CH₃)(3-Cl—Ph) H H6-Cl 2-CH₃-4-C₂F₅ Crystals 1366 CH(CH₃)(4-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅195   1367 CH(CH₃)(4-Cl—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ Paste 1368(CH₂)₂O(2-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 162   1369 (CH₂)₂O(2-Cl—Ph) H H6-Cl 2-CH₃-4-C₂F₅ 160   1370 (CH₂)₂O(3-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅115   1371 (CH₂)₂O(3-Cl—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 172   1372(CH₂)₂O(4-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 185   1373 (CH₂)₂O(4-Cl—Ph) H H6-Cl 2-CH₃-4-C₂F₅ 148   1374 (CH₂)₂O—Ph H H 3-Cl 2-CH₃-4-C₂F₅ 154   1375(CH₂)₂O—Ph H H 6-Cl 2-CH₃-4-C₂F₅ 183   1376 (CH₂)₂NH—Ph H H 3-Cl2-CH₃-4-C₂F₅ 104   1377 (CH₂)₂NH—Ph H H 6-Cl 2-CH₃-4-C₂F₅ Paste 1378CH(CH₃)CH₂OH H H 6-Cl 2-CH₃-4-C₂F₅ 192   1379 CH(Ph)CH₂OH H H H2-CH₃-4-C₂F₅ 100-101 1380 CH(4-t-C₄H₉—Ph)— H H H 2-CH₃-4-C₂F₅ 107-108CH₂OH 1381 C(CH₃)₂CH₂OH H H H 2-CH₃-4-C₂F₅ 227   1382 i-C₃H₇ H H 3-Cl2-F-4-C₂F₅ 190   1383 i-C₃H₇ H H 3-Cl 2-Cl-4-C₂F₅ 180   1384 i-C₃H₇ H H3-Cl 2-CF₃-4-C₂F₅ 235   1385 i-C₃H₇ H H 3-I 2-F-4-C₂F₅ 190   1386 i-C₃H₇H H 3-I 2-Cl-4-C₂F₅ 200   1387 i-C₃H₇ H H 3-I 2-CF₃-4-C₂F₅ 255   1388i-C₃H₇ H H 3-I 2-OCH₃-4-C₂F₅ 152   1389 i-C₃H₇ H H 3-I 2-CH₃-4-CN 215  1390 2-Fur H H 3-Cl 2-CH₃-4-C₂F₅ 178   1391 2-Fur H H 6-Cl 2-CH₃-4-C₂F₅149   1392 2-TetFur H H 3-Cl 2-CH₃-4-C₂F₅ 153   1393 2-TetFur H H 6-Cl2-CH₃-4-C₂F₅ 130   1394 CH₂-4-Pyi H H 3-Cl 2-CH₃-4-C₂F₅ 88  1395CH₂-4-Pyi H H 6-Cl 2-CH₃-4-C₂F₅ Paste 1396 (CH₂)₃OH H H H 2-CH₃-4-C₂F₅83-84 1397 (CH₂)₂OH H H H 2-CH₃-4-C₂F₅ 136   1398 CH₂CH(OH)CH₂Ph H H H2-CH₃-4-C₂F₅ 77-78 1399 (CH₂)₃OH H H 3-Cl 2-CH₃-4-C₂F₅ 188   1400 CH₂—PhH H 3-I 2-CH₃-4-C₂F₅ 172   1401 CH₂—Ph H H 6-I 2-CH₃-4-C₂F₅ 212   1402CH₂(2-Cl—Ph) H H 3-I 2-CH₃-4-C₂F₅ 136   1403 CH₂(2-Cl—Ph) H H 6-I2-CH₃-4-C₂F₅ 214   1404 CH₂(2-CH₃—Ph) H H 3-I 2-CH₃-4-C₂F₅ 100   1405CH₂(2-CH₃—Ph) H H 6-I 2-CH₃-4-C₂F₅ 185   1406 CH₂—Ph CH₃ H 3-Cl2-CH₃-4-C₂F₅ Paste 1407 CH₂—Ph CH₂—Ph H 3-Cl 2-CH₃-4-C₂F₅ 136   1408CH₂—Ph CH₂—Ph H 6-Cl 2-CH₃-4-C₂F₅ Paste 1409 i-C₃H₇ H H 3-I 2-C₂F₅-4-Br250   1410 i-C₃H₇ H H 3-I 2-C₂F₅-4-C₂F₅ 245   1411 CH₂C≡CH H H H2-CH₃-4-C₂F₅ 133-135 1412 CH(4-Ph—Ph)CH₂—OH H H 3-Cl 2-CH₃-4-C₂F₅ 112  1414 C(CH₃)₂C≡CH H H H 2-CH₃-4-C₂F₅ 207   1415 C(CH₃)₂CH₂OH H H 6-Cl2-CH₃-4-C₂F₅ 231   1416 CH(4-Cl—Ph)CH₂—OH H H 6-Cl 2-CH₃-4-C₂F₅ 225  1417 C(CH₃)₂—Ph H H 3-Cl 2-CH₃-4-C₂F₅ 190   1418 C(CH₃)₂CH₂—Ph H H 3-Cl2-CH₃-4-C₂F₅ 192   1419 CH₂-3-Pyi H H 3-Cl 2-CH₃-4-C₂F₅ Paste 1420CH₂-3-Pyi H H 6-Cl 2-CH₃-4-C₂F₅ Paste 1421 CH₂—Ph H H 3-Cl 2-CH₃-4-OCHF₂187   1422 CH₂—Ph H H 6-Cl 2-CH₃-4-OCHF₂ 198   1423 CH₂-(2-Cl—Ph) H H3-Cl 2-CH₃-4-OCHF₂ 178   1424 CH₂-(2-Cl—Ph) H H 6-Cl 2-CH₃-4-OCHF₂ 192  1425 CH₂-(2-CH₃—Ph) H H 3-Cl 2-CH₃-4-OCHF₂ 183   1426 CH₂-(2-CH₃—Ph) H H6-Cl 2-CH₃-4-OCHF₂ 192   1427 t-C₄H₉ H H 3-I 2-F-4-C₂F₅ 220   1428t-C₄H₉ H H 3-I 2-Cl-4-C₂F₅ 187   1429 t-C₄H₉ H H 3-I 2-CF₃-4-C₂F₅ 240  1430 CH₂—Ph H H 3-I 2-CH₃-4-OCHF₂ 176   1431 CH₂—Ph H H 6-I2-CH₃-4-OCHF₂ 196   1432 CH₂-(2-Cl—Ph) H H 3-I 2-CH₃-4-OCHF₂ 189   1433CH₂-(2-Cl—Ph) H H 6-I 2-CH₃-4-OCHF₂ 227   1434 CH₂-(2-CH₃—Ph) H H 3-I2-CH₃-4-OCHF₂ 215   1435 CH₂-(2-CH₃—Ph) H H 6-I 2-CH₃-4-OCHF₂ 209   1436CH₂—Ph CH₃ H 6-Cl 2-CH₃-4-C₂F₅ Paste 1437 CH₂—Ph CH₃ H 3-Cl2-CH₃-4-OCHF₂ Paste 1438 CH₂—Ph CH₃ H 3-I 2-CH₃-4-C₂F₅ 175   1439 CH₂—PhCH₃ H 6-I 2-CH₃-4-C₂F₅ Paste 1440 CH₂—Ph CH₃ H 3-I 2-CH₃-4-OCHF₂ Paste1441 CH(C₂H₅)CH₂OH H H 6-Cl 2-CH₃-4-C₂F₅ 213   1442 (R)—C*H(Ph)—CH₂OH HH 3-Cl 2-CH₃-4-C₂F₅ 105-107 1443 (R)—C*H(Ph)—CH₂OH H H 6-Cl 2-CH₃-4-C₂F₅145-146 1445 (S)—C*H(CH₃)—CH₂OH H H 3-Cl 2-CH₃-4-C₂F₅ 93-95 1446(S)—C*H(CH₃)—CH₂OH H H 6-Cl 2-CH₃-4-C₂F₅ 93-95 1447 t-C₄H₉ H H 3-Cl4-C₂F₅ 275   1448 t-C₄H₉ H H 3-Cl 2-F-4-C₂F₅ 225   1449 t-C₄H₉ H H 3-Cl2-Cl-4-C₂F₅ 200   1450 n-C₃H₇ H H 3-I 2-CH₃-4-OCHF₂ 181   1451 n-C₃H₇ HH 6-I 2-CH₃-4-OCHF₂ 233   1452 c-C₃H₅ H H 3-I 2-CH₃-4-OCHF₂ 182   1453c-C₃H₅ H H 6-I 2-CH₃-4-OCHF₂ 231   1454 s-C₄H₉ H H 3-I 2-CH₃-4-OCHF₂225   1455 s-C₄H₉ H H 6-I 2-CH₃-4-OCHF₂ 244   1456 CH₂C≡CH H H 3-I2-CH₃-4-OCHF₂ 196   1457 CH₂—Ph C₂H₅ H 3-Cl 2-CH₃-4-C₂F₅ Paste 1458(R)—C*H(CH₃)—Ph H H 3-Cl 2-CH₃-4-OCHF₂ 136   1459 (S)—C*H(CH₃)—Ph H H3-Cl 2-CH₃-4-OCHF₂ 136   1460 (R)—C*H(CH₃)—CH₂OH H H 3-Cl 2-CH₃-4-C₂F₅94-95 1461 (R)—C*H(CH₃)—CH₂OH H H 6-Cl 2-CH₃-4-C₂F₅ 94-95 1464C(CH₃)₂CH₂OH H H 3-I 2-CH₃-4-C₂F₅ 118   1465 CH(CH₃)CH₂OH H H 6-I2-CH₃-4-C₂F₅ 130-131 1466 C(CH₃)₂C≡CH H H 3-Cl 2-CH₃-4-C₂F₅ 210-211 1467C(CH₃)₂C≡CH H H 6-Cl 2-CH₃-4-C₂F₅ 230   1468 CH₂(2-F—Ph) H H 3-Cl2-CH₃-4-C₂F₅ 187   1469 CH₂(2-F—Ph) H H 6-Cl 2-CH₃-4-C₂F₅ 165   1470CH₂—Ph H H 3-F 2-CH₃-4-C₂F₅ 158   1471 CH₂—Ph H H 6-F 2-CH₃-4-C₂F₅ 134  1472 s-C₄H₉ H H 3-I 2-F-4-C₂F₅ 200   1473 s-C₄H₉ H H 3-I 2-Cl-4-C₂F₅205   1474 i-C₃H₇ H H 3-I 2-F-4-n-C₃F₇ 165   1475 t-C₄H₉ H H 3-I2-C₂H₅-4-C₂F₅ 235   1476 CH₂CH(OH)Ph H H 3-Cl 2-CH₃-4-C₂F₅ 108   1477CH₂CH(OH)Ph H H 6-Cl 2-CH₃-4-C₂F₅ 105   1478 C(CH₃)₂C≡CH H H 3-Cl2-CH₃-4-C₂F₅ 105   1479 C(CH₃)₂C≡C-2-Thi H H 3-Cl 2-CH₃-4-C₂F₅ 110  1480 C(CH₃)₂C≡C—Ph H H 6-Cl 2-CH₃-4-C₂F₅ 194   1481 (R)—C*H(CH₃)—CH₂OH HH 3-I 2-CH₃-4-C₂F₅ 103-105 1482 (S)—C*H(CH₃)—CH₂OH H H 3-I 2-CH₃-4-C₂F₅103-105 1483 (R)—C*H(CH₃)—CH₂OH H H 6-I 2-CH₃-4-C₂F₅ 173-174 1484C(CH₃)₂(4-Cl—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 218   1485 C(CH₃)₂(3-Cl—Ph) H H3-Cl 2-CH₃-4-C₂F₅ 128   1486 CH₂—Ph H H 3-Cl 2-F-4-C₂F₅ 162   1487CH₂—Ph H H 3-Cl 2-Cl-4-C₂F₅ 153   1488 C₂H₅ H H 3-Cl 2-F-4-C₂F₅ 135  1489 C₂H₅ H H 3-Cl 2-Cl-4-C₂F₅ 125   1490 C₂H₅ H H 3-Cl 2-F-4-n-C₃F₇128   1491 n-C₃H₇ H H 3-Cl 2-F-4-C₂F₅ 153   1492 n-C₃H₇ H H 3-Cl2-Cl-4-C₂F₅ 147   1493 n-C₃H₇ H H 3-Cl 2-F-4-n-C₃F₇ 142   1494 i-C₃H₇ HH 3-Cl 2-F-4-n-C₃F₇ 142   1495 i-C₃H₇ H H 3-Cl 2-C₂H₅-4-C₂F₅ 213   1496t-C₄H₉ H H 3-Cl 2-F-4-n-C₃F₇ 172   1497 t-C₄H₉ H H 3-Cl 2-C₂H₅-4-C₂F₅194   1498 s-C₄H₉ H H 3-Cl 2-F-4-C₂F₅ 209   1499 s-C₄H₉ H H 3-Cl2-Cl-4-C₂F₅ 194   1500 s-C₄H₉ H H 3-Cl 2-F-4-n-C₃F₇ 182   1501 s-C₄H₉ HH 3-Cl 2-C₂H₅-4-C₂F₅ 212   1502 C₂H₅ H H 3-I 2-F-4-C₂F₅ 135   1503 C₂H₅H H 3-I 2-Cl-4-C₂F₅ 155   1504 t-C₄H₉ H H 3-I 2-F-4-n-C₃F₇ 180   1505t-C₄H₉ H H 3-F 2-CH₃-4-C₂F₅ 220   1506 t-C₄H₉ H H 3-F 2-CH₃-4-OCHF₂186   1507 t-C₄H₉ H H 3-F 2-F-4-C₂F₅ 214   1508 t-C₄H₉ H H 3-F2-Cl-4-C₂F₅ 222   1509 t-C₄H₉ H H 3-F 2-F-4-n-C₃F₇ 179   1510 C₂H₅ H H3-F 2-F-4-C₂F₅ 125   1511 C₂H₅ H H 6-F 2-F-4-C₂F₅ 155   1512 n-C₃H₇ H H3-F 2-F-4-C₂F₅ 130   1513 n-C₃H₇ H H 6-F 2-F-4-C₂F₅ 170   1514 i-C₃H₇ HH 3-F 2-F-4-C₂F₅ 190   1515 i-C₃H₇ H H 6-F 2-F-4-C₂F₅ 180   1516 i-C₃H₇H H 3-F 2-Cl-4-C₂F₅ 210   1517 i-C₃H₇ H H 6-F 2-Cl-4-C₂F₅ 160   1518(S)—C*H(CH₃)—CH₂OH H H 6-I 2-CH₃-4-C₂F₅ 173-174 1519 C(CH₃)₂CH₂OH H H3-I 2-CH₃-4-OCF₃ 205   1520 C(CH₃)₂CH₂OH H H 6-I 2-CH₃-4-OCF₃ 248   1521i-C₃H₇ H H 3-I 2-CH₃-4-(4-CF₃O—Ph) 247-250 1522 i-C₃H₇ H H 3-I2-CH₃-4-(4-CF₃—Ph) 243-246 1523 CH₂(2-CF₃—Ph) H H 3-Cl 2-CH₃-4-C₂F₅183   1524 n-C₃H₇ H H 3-I 2-F-4-n-C₃F₇ 145   1525 C₂H₅ C₂H₅ H 3-F2-CH₃-4-C₂F₅ 135   1526 C₂H₅ C₂H₅ H 3-F 2-CH₃-4-i-C₃F₇ 150   1527 C₂H₅C₂H₅ H 3-F 2-CH₃-4-OCF₃ 125   1528 C₂H₅ C₂H₅ H 3-F 2-CH₃-4-OCHF₂ 110  1529 C₂H₅ C₂H₅ H 3-F 2-CH₃-4-OCF₂CHF₂ 155   1530 C₂H₅ C₂H₅ H 3-F2-F-4-C₂F₅ 130   1531 C₂H₅ C₂H₅ H 3-F 2-Cl-4-C₂F₅ 110   1532 C₂H₅ C₂H₅ H3-I 2-CH₃-4-i-C₃F₇ 142   1533 C₂H₅ C₂H₅ H 3-I 2-CH₃-4-OCF₃ 142   1534C₂H₅ C₂H₅ H 3-I 4-OCF₃ 142   1535 C₂H₅ C₂H₅ H 3-Cl 2-CH₃-4-C₂F₅ 150  1536 C₂H₅ C₂H₅ H 3-Cl 2-CH₃-4-OCF₃ 123   1537 C₂H₅ C₂H₅ H 3-Cl2-CH₃-4-i-C₃F₇ 147   1538 C₂H₅ C₂H₅ H 3-Cl 2-CH₃-4-OCHF₂ 92  1539 C₂H₅C₂H₅ H 3-Cl 2-CH₃-4-OCF₂CHF₂ 135   1540 C₂H₅ C₂H₅ H 3-Cl 2-Cl-4-C₂F₅110   1541 C₂H₅ C₂H₅ H 3-Cl 2-F-4-C₂F₅ 113   1542 C₂H₅ C₂H₅ H 3-Cl2-CH₃—Cl 142   1543 C₂H₅ C₂H₅ H 3-Cl 2-C₂H₅-4-C₂F₅ 101   1544 C₂H₅ C₂H₅H 3-Cl 4-OCF₃ 138   1545 C₂H₅ C₂H₅ H 3-Cl 4-CF₃ 188   1546 C₂H₅ C₂H₅ H3-F 2-CH₃-4-Cl 135   1547 C₂H₅ C₂H₅ H 3-F 4-CF₃ 175   1548 C₂H₅ C₂H₅ H3-F 4-OCF₃ 155   1549 C₂H₅ C₂H₅ H 3-F 2-C₂H₅-4-C₂F₅ 80  1550 C₂H₅ C₂H₅ H3-NO₂ 2-CH₃-4-C₂F₅ 185   1551 C₂H₅ C₂H₅ H 6-NO₂ 2-CH₃-4-C₂F₅ 145   1552t-C₄H₉ H H 3-I 3-CH₃-4-C₂F₅ 215   1553 CH₂—Ph CH₃ CH₃ 3-Cl 2-CH₃-4-C₂F₅Paste 1554 CH(CH₃)—Ph H CH₃ 3-Cl 2-CH₃-4-C₂F₅ Paste 1555 C₂H₅ C₂H₅ H 3-I2-CH₃-4-OCHF₂ 138-139 1556 C₂H₅ C₂H₅ H 3-I 2-CH₃-4-OCF₂CHF₂ 136   1557C₂H₅ C₂H₅ H 3-I 2-CH₃-4-Cl 179   1558 C₂H₅ C₂H₅ H 3-I 4-CF₃ 187   1559C₂H₅ C₂H₅ H 3-I 2-C₂H₅-4-C₂F₅ 106   1560 C₂H₅ C₂H₅ H 3-I 2-Cl-4-C₂F₅103-105 1561 C₂H₅ C₂H₅ H 3-I 2-CH₃-4-C₂F₅ 115   1562 t-C₄H₉ H H 3-I2-Br-4-C₂F₅ 185   1563 i-C₃H₇ H H 3-I 3-CH₃-4-C₂F₅ 240   1564 i-C₃H₇ H HH 4-O-(2-Pym) 246   1565 C(CH₃)₂—CH₂CH₃ H H 3-I 2-CH₃-4-C₂F₅ 193   1566C(CH₃)₂—CH₂CH₃ H H 3-I 2-CH₃-4-OCF₃ 180   1567 C(CH₃)₂CH₂CH₃ H H 3-I178-179 1568 C(CH₃)₂CH₂CH₃ H H 3-I 2-CH₃-4-OCHF₂ 176-177 1569C(CH₃)₂CH═CH₂ H H 3-Cl 2-CH₃-4-C₂F₅ 223-224 1570 C(CH₃)₂CH═C- H H 3-Cl2-CH₃-4-C₂F₅ 92-93 (4-CH₃—Ph 1571 C(CH₃)₂CH═C- H H 3-Cl 2-CH₃-4-C₂F₅96-97 (2,4-Cl₂—Ph) 1572 C(CH₃)₂CH≡C- H H 3-Cl 2-CH₃-4-C₂F₅ 88-89(4-CH₃O—Ph) 1573 n-C₃H₇ C₂H₅ H 3-I 2-CH₃-4-C₂F₅ 93  1574 n-C₃H₇ C₂H₅ H3-I 2-CH₃-4-OCF₃ 109   1575 n-C₃H₇ C₂H₅ H 3-I 2-CH₃-4-OCHF₂ 102   1576CH₂(4-CF₃O—Ph) H H 3-Cl 2-CH₃-4-C₂F₅ 172   1577 CH₂(4-CF₃O—Ph) H H 6-Cl2-CH₃-4-C₂F₅ 193   1578 CH₂(3-Cl—Ph) CH₃ H 3-Cl 2-CH₃-4-C₂F₅ Paste 1579CH₂(2-F—Ph) CH₃ H 3-Cl 2-CH₃-4-C₂F₅ 115   1580 i-C₃H₇ H H 3-I2-Br-4-C₂F₅ 190   1581 n-C₃H₇ C₂H₅ H 3-F 2-CH₃-4-C₂F₅ 120   1582 n-C₃H₇C₂H₅ H 3-F 4-OCF₃ 115   1583 n-C₃H₇ C₂H₅ H 3-F 4-OCHF₂ 85  1584 n-C₃H₇C₂H₅ H 3-F 2-Cl-4-C₂F₅ 75  1585 C(CH₃)₂CH≡C- H H 3-Cl 2-CH₃-4-C₂F₅102-103 (4-CF₃—Ph) 1586 C(CH₃)₂CH≡C- H H 3-Cl 2-CH₃-4-C₂F₅ 115-117(2,6-Cl₂—Ph) 1587 C(CH₃)₂CH≡C- H H 3-Cl 2-CH₃-4-C₂F₅ 169   2-Pyi 1588C(CH₃)₂CH≡CH H H 3-Cl 2-CH₃-4-OCHF₂ 191-192 1589 C(CH₃)₂CH═CH₂ H H 6-Cl2-CH₃-4-C₂F₅ 242   1590 C(CH₃)₂CH≡C- H H 3-Cl 2-CH₃-4-C₂F₅ 134-135 3-Pyi1591 i-C₃H₇ H H H 2-CH₃-4-(2,6- 165   (CH₃O)₂—Ph 1592 i-C₃H₇ H H H2-CH₃-4-(3,5- 150   (CH₃O)₂—Ph 1593 C₂H₅ C₂H₅ H H 2-CH₃-4-(3,5- Paste(CH₃O)₂—Ph) 1594 i-C₃H₇ H H 3-Cl 2-F-4-(OCF₂O)-5 195   1595 i-C₃H₇ H H3-I 2-F-4-(OCF₂O)-5 208   1596 t-C₄H₉ H H 3-I 2-F-4-(OCF₂O)-5 202   1597i-C₃H₇ H H 3-Cl 2-CH₃-4-(OCHFCF₂—O)-5 211   1598 i-C₃H₇ H H 3-I2-CH₃-4-(OCHFCF₂—O)-5 212   1599 t-C₄H₉ H H 3-I 2-CH₃-4-(OCHFCF₂—O)-5217   1600 i-C₃H₇ H H 3-I 2-Cl-4-(OCHFCF₂—O)-5 210   1601 i-C₃H₇ H H 3-I2-Cl-4-(OCF₂CHF—O)-5 214   1602 C(CH₃)₂C≡CH H H 3-Cl 2-CH₃-4-OCF₃178-180 1603 C(CH₃)₂CHBr—CH₂Br H H 3-Cl 2-CH₃-4-C₂F₅ 130-131 1604C(CH₃)₂CH═CH—Ph(E) H H 3-Cl 2-CH₃-4-C₂F₅ 90-93 1605 C(CH₃)₂CH₂Br H H 3-I2-CH₃-4-OCF₃ 139-141 1606 (S)—C*H—(CH₃)—CH₂Br H H 3-I 2-CH₃-4-C₂F₅105-107 1607 (R)—C*H—(CH₃)—CH₂Br H H 3-I 2-CH₃-4-C₂H₅ 105-107 1608i-C₃H₇ H H 3-I 3-Cl-4-C₂F₅ 145   1609 t-C₄H₉ H H 3-I 3-Cl-4-C₂F₅ 260  1610 i-C₃H₇ H H 3-I 2-CH₃-4-C₂F₅-5-CH₃ 210   1611 t-C₄H₉ H H 3-I2-CH₃-4-C₂F₅-5-CH₃ 215   1612 i-C₃H₇ H H 3-I 2,3-(CH₃)₂-4-C₂F₅ 210  1613 t-C₄H₉ H H 3-I 2,3-(CH₃)₂-4-C₂F₅ 220   1614 C₂H₅ C₂H₅ H 3-I2-CH₃-4-(4-F—Ph) 130-133 1615 C₂H₅ C₂H₅ H 3-I 2-CH₃-4-(4-Cl—Ph) 173-1751616 i-C₃H₇ H H H 2-CH₃-4-O-(2-Thz) 149   1617 i-C₃H₇ H H 3-I Mixture of2-CH₃-4- 235   (4-(2-CH₃Thz)) and 2-CH₃-5-(4-(2-CH₃- Thz)) (1:1) 1618i-C₃H₇ H H 3-I 2-CH₃-4-O-(2-Pym) 239   1619 C₂H₅ C₂H₅ H 3-I2-CH₃-4-(4-CF₃—Ph) 112-115 1620 i-C₃H₇ H H 3-I 4-CF₂CF₂O-5 239   1621i-C₃H₇ H H 3-Cl 4-CF₂CF₂O-5 243   1622 i-C₃H₇ H H 3-I 2-Cl-4-OCF₂O-5226   1623 i-C₃H₇ H H 3-Cl 2-Cl-4-OCF₂O-5 223   1624 t-C₄H₉ H H 3-I2-Cl-4-OCF₂O-5 221   1625 i-C₃H₇ H H 3-I 2-Cl-4-OCF₂CF₂O 241   1626i-C₃H₇ H H 3-I 2-Cl-3-OCF₂CF₂O-4 219   1627 C(CH₃)₂CH₂Cl H H 3-I2-CH₃-4-OCF₃ 160   1628 C(CH₃)₂C≡C-3-Thi H H 3-Cl 2-CH₃-4-C₂F₅ 78-801629 C(CH₃)₂C≡CH H H 3-I 2-CH₃-4-C₂F₅ 187-188 1630 i-C₃H₇ H H 3-I2-CH₃-4-(3,5-(CH₃O)₂—Ph) 199   1631 i-C₃H₇ H H H 3-OCH₂O-4 195   1632i-C₃H₇ H H H 2-F-4-Cl 177   1633 C(CH₃)₂C≡C- H H 3-Cl 2-CH₃-4-C₂F₅ 92-93(4-CF₃O—Ph) 1634 C(CH₃)₂C≡CH H H 3-I 2-CH₃-4-OCF₃ 188-189 1635C(CH₃)₂C≡CH H H 3-I 2-CH₃-4-OCHF₂ 175-176 1636 i-C₃H₇ H H 3-I4-N═(n-C₃F₇)C—O-5 182   1637 i-C₃H₇ H H 3-I 4-O—C(n-C₃F₇)═N-5 250   1638i-C₃H₇ H H 3-Cl 4-O—C(N-C₃F₇)═N-5 168   1639 t-C₄H₉ H H 3-I4-O—C(n-C₃F₇)═N-5 248   1640 i-C₃H₇ H H 3-I 2,3-(CH₃)₂-4-C₂F₅ 195   1641i-C₃H₇ H H 3-I 2-CH₃-4-OC(CF₃)═N-5 229   1642 i-C₃H₇ H H 3-Cl2-Cl-3-OCF₂CF₂O-4 188   1643 i-C₃H₇ H H 3-Cl 2-Cl-4-OCF₂CF₂O-5 203  1644 t-C₄H₉ H H 3-I 2-Cl-3-OCF₂CF₂O-4 189   1645 t-C₄H₉ H H 3-I2-Cl-4-OCF₂CF₂O-5 234   1646 C(CH₃)₂CH₂Cl H H 3-I 2-CH₃-4-C₂F₅ 168-1691647 C(CH₃)₂CH₂Br H H 3-I 2-CH₃-4-C₂F₅ 167-168 1648 C(CH₃)₂C≡C-Naph H H3-I 2-CH₃-4-C₂F₅ 90  1649 C(CH₃)₂C≡C- H H 3-Cl 2-CH₃-4-C₂F₅ 105-106(5-Br-2-Pyi) 1650 C(CH₃)₂C≡C- H H 3-Cl 2-CH₃-4-C₂F₅ 103-105 (2,4-F₂—Ph)1651 (S)—C*H(CH₃)—CH₂F H H 3-Cl 2-CH₃-4-C₂F₅ 135   1652(S)—C*H—(CH₃)—CH₂Br H H 3-Cl 2-CH₃-4-C₂F₅ 193-198 1653 i-C₃H₇ H H 3-I2-CH₃-4-C₂F₅-5-Cl 210   1654 t-C₄H₉ H H 3-I 2-CH₃-4-C₂F₅-5-Cl 200   1655i-C₃H₇ H H 3-I 2-CH₃-4-C₂F₅-5-CH₃ 190   1656 t-C₄H₉ H H 3-I2-CH₃-4-C₂F₅-5-CH₃ 195   1657 i-C₃H₇ H H H 3-(2-CH₃-4-Thz) 211   1658i-C₃H₇ H H 3-I 3-(2-CF₃-4-Thz) 122   1659 i-C₃H₇ H H 3-I 3-(2-CH₃-4-Oxa)102   1660 i-C₃H₇ H H 3-I 2-I-4-OCF₂O-5 252   1661 i-C₃H₇ H H 3-Cl2-CH₃-4-OCF₂O-5 218   1662 t-C₄H₉ H H 3-I 2-CH₃O-4-C₂F₅ 135   1663i-C₃H₇ H H 3-I 2-CH₃-4-i-C₃F₇-5-F 235   1664 t-C₄H₉ H H 3-I2-CH₃-4-i-C₃F₇-5-F 230   1665 i-C₃H₇ H H 3-I 2-CH₃-4-i-C₃F₇-5-Cl 210  1666 i-C₃H₇ H H 3-I 2-CH₃-4-CF₂CF₂O-5 198   1667 i-C₃H₇ H H 3-I2-CH₃-4-i-C₃F₇ 270   1668 t-C₄H₉ H H 3-I 2-CH₃-4-i-C₃F₇ 290   1669i-C₃H₇ H H 3-I 2-F-4-i-C₃F₇ 205   1670 t-C₄H₉ H H 3-I 2-F-4-i-C₃F₇ 210  1671 i-C₃H₇ H H 3-I 2-SCH₃-4-i-C₃F₇ 205   1672 t-C₄H₉ H H 3-I2-SCH₃-4-i-C₃F₇ 205   1673 i-C₃H₇ H H 3-I 2,4-(CH₃)₂-4-i-C₃F₇ 240   1674t-C₄H₉ H H 3-I 2,4-(CH₃)₂-4-i-C₃F₇ 245   1675 i-C₃H₇ H H 3-I4-(2-CH₃-4-Thz) 217   1676 i-C₃H₇ H H 3-I 4-(2-CH₃-4-Oxa) 212   1677i-C₃H₇ H H 3-I 4-(2-i-C₃H₇-4-Thz) 199   1678 i-C₃H₇ H H 3-NO₂4-(2-CH₃-4-Thz) 230   1679 i-C₃H₇ H H 3-I 2-Cl-3-OCF₂CHFO-4 188   1680i-C₃H₇ H H 3-I 2-Cl-3-OCHFCF₂O-4 191   1681 i-C₃H₇ H H 3-I Mixture of2-Cl-3- 199   OCHFCF₂O-4-5-Cl and 2-Cl-3-OCHFCF₂O-4-6-Cl (1:1) 1682i-C₃H₇ H H 3-I 2-Cl-3-N═C(CF₃)—O-4 265   1683 t-C₄H₉ H H 3-I2-Cl-3-N═C(CF₃)—O-4 259   1684 i-C₃H₇ H H 3-I 2-Br-4-OCF₂CHFO-5 185  1685 i-C₃H₇ H H 3-I Mixture of 2,3-Br₂-4- 250   OCF₂CHFO-5; 2,5-Br₂-3-OCHFCF₂O-4; and 2,6- Br₂-3-OCF₂CHFO-4(1:1:1) 1686 i-C₃H₇ H H 3-I Mixtureof 2,3-Br₂-4- 228   OCHFCF₂O-5; 2,5-Br₂-3- OCF₂CHFO-4; and 2,6-Br₂-3-OCF₂CHFO-4(1:1:1) 1689 i-C₃H₇ H H 3-I 2,3-(CH₃)₂-4-i-C₃F₇ 270  1690 t-C₄H₉ H H 3-I 2,3-(CH₃)₂-4-i-C₃F₇ 280   1691 i-C₃H₇ H H 3-I2-i-C₃H₇-4-i-C₃F₇ 240   1692 t-C₄H₉ H H 3-I 2-i-C₃H₇-4-i-C₃F₇ 245   1693i-C₃H₇ H H 3-I 2-OC₂H₅-4-i-C₃F₇ 195   1694 t-C₄H₉ H H 3-I2-OC₂H₅-4-i-C₃F₇ 210   1695 i-C₃H₇ H H 3-I 3-F-4-i-C₃F₇ 265   1696t-C₄H₉ H H 3-I 3-F-4-i-C₃F₇ 285   1697 i-C₃H₇ H H 3-I 3-Cl-4-i-C₃F₇295   1698 i-C₃H₇ H H 3-I 2-Br-4-i-C₃F₇-5-CH₃ 240   1699 i-C₃H₇ H H 3-I2-Br-4-i-C₃F₇ 240   1700 i-C₃H₇ H H 3-I 2-SCH₃-4-C₂F₅ 200   1703 i-C₃H₇H H 3-I 4-(2-c-C₃H₅-4-Thz) 198   1714 i-C₃H₇ H H 3-I 2-C₂H₅-4-i-C₃F₇220   1715 i-C₃H₇ H H 3-I 2-OCH₃-4-i-C₃F₇ 190   1716 i-C₃H₇ H H 3-I2,6(CH₃)₂-4-i-C₃F₇ 275   1717 i-C₃H₇ H H 3-I 2,6-(CH₃)₂-4-C₂F₅ 250  1722 i-C₃H₇ H H 3-I 2-Cl-4-i-C₃F₇ 220   1723 t-C₄H₉ H H 3-I2-Cl-4-i-C₃F₇ 210   1726 i-C₃H₇ H H 3-I 2-(CH₂)₄-3-4-i-C₃F₇ 260   1727t-C₄H₉ H H 3-I 2-(CH₂)₄-3-4-i-C₃F₇ 272   1732 i-C₃H₇ H H 3-I2-Cl-3-OCF₂CF₂O-4 245   1733 i-C₃H₇ H H 3-I 2-Cl-3-OCHFCF₂O-4 190   1737i-C₃H₇ H H 3-I 4-C(CH₃)═NOCH₃ 190   1742 i-C₃H₇ H H 3-I 2-OCF₂O-3 190  1743 i-C₃H₇ H H 3-I 2-OCF₂O-3-6-Cl 213   1744 i-C₃H₇ H H 3-I2-OCF₂O-3-4-Cl 202   1745 i-C₃H₇ H H 3-I 2-OCF₂O-3-4,6-Cl₂ 228   1746i-C₃H₇ H H 3-I 2-OCF₂O-3-4-i-C₃F₇ 175   1747 t-C₄H₉ H H 3-I2-OCF₂O-3-4-Cl 235   1748 t-C₄H₉ H H 3-I 2-OCF₂O-3-4,6-Cl₂ 243   1749i-C₃H₇ H H 3-I 4-C(CH₃)═NOCH₂—Ph 205   1750 i-C₃H₇ H H 3-I4-C(CH₃)═NOCH₂—CH═CH₂ Decomp. 1751 CH₃ CH₃ H H 2-CH₃-4-Cl 149   1752C₂H₅ C₂H₅ H H 2-CH₃-4-Cl 172   1753 n-C₃H₇ n-C₃H₇ H H 2-CH₃-4-Cl 126  1762 i-C₃H₇ H H 3-I 3-C(i-C₃F₇)═NN- Paste (i-C₃F₇)-4 1763 i-C₃H₇ H H 3-I4-i-C₃H₇-2-N═CH—S-3 200   1764 i-C₃H₇ H H 3-I 3-S—C(i-C₃H₇)═N-4 218  1765 i-C₃H₇ H H 3-I 4-(2-CF₃-4-Thz) 105   1766 i-C₃H₇ H H 3-I3-SCH₃-4-i-C₃F₇ 160   1767 i-C₃H₇ H H 3-I 2-Ph-4-i-C₃F₇ 240   1768i-C₃H₇ H H 3-I 2-OPh-4-i-C₃F₇ 180   1769 i-C₃H₇ H H 3-I 2-OCH₃-4-i-C₃F₇265   1770 (CH₂)₂-3-Pyi H H 3-I 2-CH₃-4-i-C₃F₇ Amorphous 1771(CH₂)₂-3-Pyi H H 6-I 2-CH₃-4-i-C₃F₇ Amorphous 1772 (CH₂)₂-3-Pyi H H 3-I2-CH₃-4-OCF₃ 169-173 1773 CH(CH₃)-2-Pyi H H 3-I 2-CH₃-4-i-C₃F₇ Amorphous1774 CH(CH₃)-2-Pyi H H 6-I 2-CH₃-4-i-C₃F₇ Amorphous 1775 CH(CH₃)-2-Pyi HH 3-I 2-CH₃-4-OCF₃ 158-161 1776 CH(CH₃)-2-Pyi H H 6-I 2-CH₃-4-OCF₃213-216 1777 CH(CH₃)-2-Pyi H H 3-I 2-CH₃-4-C₂F₅ 149-152 1778CH(CH₃)-2-Pyi H H 6-I 2-CH₃-4-C₂F₅ 194-196 1780 N(Ph)COCF₃ H H 3-I2-CH₃-4-C₂F₅ 239-241 1799 CH(CH₃)-2-Fur H H 3-I 2-CH₃-4-i-C₃F₇ 191  1800 CH(CH₃)-2-Thi H H 3-I 2-CH₃-4-i-C₃F₇ 159   1801 i-C₃H₇ H H 3-CF₃2-CH₃-4-C₂F₅ 210-212 1802 i-C₃H₇ H H 3-Cl-6-CF₃S 2-CH₃-4-C₂F₅ 236-2371803 i-C₃H₇ H H 3-CF₃SO 2-CH₃-4-C₂F₅ 186-187 1804 i-C₃H₇ H H 6-CF₃SO2-CH₃-4-C₂F₅ 206-208 1805 i-C₃H₇ H H 3-CF₃SO 2-CH₃-4-i-C₃F₇ 211-213 1815i-C₃H₇ H H 3-I 2-CH₃-4-s-C₄F₉ 190   1816 i-C₃H₇ H H 3-I 2-OH-4-i-C₃F₇155   1824 i-C₃H₇ H H 3-I 2-N═C(CF₃)O-3- 132   4-i-C₃F₇ 1825 i-C₃H₇ H H3-I 2-N═C(CF₃)O-3 145   1826 t-C₄H₉ H H 3-I 2-N═C(CF₃)O-3- 110  4-i-C₃F₇ 1827 t-C₄H₉ H H 3-I 2-N═C(CF₃)O-3 120   1829 (CH₂)₂NH—CO₂C₂H₅ HH 3-I 2-CH₃-4-i-C₃F₇ 155   1830 (CH₂)₂NHCO₂CH₂Ph H H 3-I 2-CH₃-4-C₂F₅155   1831 (CH₂)₂CH═CF₂ H H 3-I 2-CH₃-4-C₂F₅ 180   1838 i-C₃H₇ H H 3-I2-CH₃-4-OCF₂CF₃ 1839 i-C₃H₇ H H 3-NO₂ 2-CH₃-4-OCF₂CF₃ 1840 i-C₃H₇ H H3-F 2-CH₃-4-OCF₂CF₃ 1841 i-C₃H₇ H H 3-Cl 2-CH₃-4-OCF₂CF₃ 1842 i-C₃H₇ H H3-Br 2-CH₃-4-OCF₂CF₃ 1843 i-C₃H₇ H H 3-Cl-4-F 2-CH₃-4-OCF₂CF₃ 1844i-C₃H₇ H H 3,4-Cl₂ 2-CH₃-4-OCF₂CF₃ 1845 i-C₃H₇ H H 3-I 4-OCF₂CF₃ 1846i-C₃H₇ H H 3-I 2-Cl-4-OCF₂CF₃ 1847 i-C₃H₇ H H 3-I 2-CH₃-4-OCF₂CF₃ 1848t-C₄H₉ H H 3-I 2-CH₃-4-OCF₂CF₃ 1849 C₂H₅ C₂H₅ H 3-I 2-CH₃-4-OCF₂CF₃ 1850i-C₃H₇ H H 3-I 2-C₂H₅-4-OCF₂CF₃ 1851 i-C₃H₇ H H H 2-CH₃-4-O-n-C₃F₇ 1852i-C₃H₇ H H 3-NO₂ 2-CH₃-4-O-n-C₃F₇ 1853 i-C₃H₇ H H 3-F 2-CH₃-4-O-n-C₃F₇1854 i-C₃H₇ H H 3-Cl 2-CH₃-4-O-n-C₃F₇ 1855 i-C₃H₇ H H 3-Br2-CH₃-4-O-n-C₃F₇ 1856 t-C₄H₉ H H 3-Cl-4-F 2-CH₃-4-O-n-C₃F₇ 1857 C₂H₅C₂H₅ 3,4-Cl₂ 2-CH₃-4-O-n-C₃F₇ 1858 i-C₃H₇ H H 3-I 4-O-n-C₃F₇ 1859 i-C₃H₇H H 3-I 2-Cl-4-O-n-C₃F₇ 1860 i-C₃H₇ H H 3-I 2-CH₃-4-O-n-C₃F₇ 1861 t-C₄H₉H H 3-I 2-CH₃-4-O-n-C₃F₇ 1862 C₂H₅ C₂H₅ H 3-I 2-CH₃-4-O-n-C₃F₇ 1863i-C₃H₇ H H 3-I 2-C₂H₅-4-OCF₂CF₃ 1864 i-C₃H₇ H H 3-I 2-CH₃-4-C≡C-t-C₄F₉1865 i-C₃H₇ H H 3-I 2-CH₃-4-C≡C—CF₃ 1866 i-C₃H₇ H H 3-I2-CH₃-4-C≡C-i-C₃F₇ 1867 i-C₃H₇ H H 3-I 2-CH₃-4-CF═CF₂ 1868 i-C₃H₇ H H3-I 2-CH₃-4-CF═CFCF₃ 1869 i-C₃H₇ H H 3-I 2-CH₃-4-C(CF₃)═CF₂ 1870 i-C₃H₇H H 3-I 2-CH₃-4-COCH₃ 1871 i-C₃H₇ H H 3-I 2-CH₃-4-COCF₃ 195   1872i-C₃H₇ H H 3-I 2-CH₃-4-COC₂F₅ 1873 i-C₃H₇ H H 3-I 2-CH₃-4-COCF(CH₃)₂1874 i-C₃H₇ H H 3-I 2-CH₃-4-COOCH₃ 217   1875 i-C₃H₇ H H 3-I2-CH₃-4-COOC₂H₅ 1876 i-C₃H₇ H H 3-I 2-CH₃-4-C(CH₃)═NOCH₃ 218   1877i-C₃H₇ H H 3-I 2-CH₃-4-C(CH₃)═NOC₂H₅ 1878 i-C₃H₇ H H 3-I2-CH₃-4-C(CH₃)═NO— CH₂CH═CH₂ 1879 i-C₃H₇ H H 3-I 2-CH₃-4-C(CH₃)═NO—CH₂C≡CH 1880 i-C₃H₇ H H 3-I 2-CH₃-4-C(CH₃)═NOCH₂—Ph 1881 i-C₃H₇ H H 3-I2-CH₃-4-CH₂OH 1882 i-C₃H₇ H H 3-I 4-CH(OH)CH₃ 1883 i-C₃H₇ H H 3-I2-CH₃-4-CH(OH)CH₃ 1884 i-C₃H₇ H H 3-I 2-CH₃-4-CH₂ON═C(CH₃)₂ 1885 i-C₃H₇H H 3-I 2-CH₃-4-CH₂ON═C(Ph)-i-C₃H₇ 1886 i-C₃H₇ H H 3-I2-OCH₂O-3-4-i-C₃F₇ 1887 i-C₃H₇ H H 3-I 2-OCH₂CH₂O-3-4-i-C₃F₇ 1888 i-C₃H₇H H 3-I 2-OCF₂CF₂O-3-4-i-C₃F₇ 1889 i-C₃H₇ H H 3-I 2-OCF₂CHFO-3-4-i-C₃F₇1890 i-C₃H₇ H H 3-I 2-OCHFCF₂O-3-4-i-C₃F₇ 1891 i-C₃H₇ H H 3-I2-SCH₂S-3-4-i-C₃F₇ 1892 i-C₃H₇ H H 3-I 2-SCF₂S-3-4-i-C₃F₇ 1893 i-C₃H₇ HH 3-I 2-SCH₂CH₂S-3-4-i-C₃F₇ 1894 i-C₃H₇ H H 3-I 2-SCF₂CF₂S-3-4-i-C₃F₇1895 i-C₃H₇ H H 3-I 2-CH₂OCH₂-3-4-i-C₃F₇ 1896 i-C₃H₇ H H 3-I2-CH₂SCH₂-3-4-i-C₃F₇ 1897 i-C₃H₇ H H 3-I 2-CF₂OCF₂-3-4-i-C₃F₇ 1898i-C₃H₇ H H 3-I 2-CF₂SCF₂-3-4-i-C₃F₇ 1899 i-C₃H₇ H H 3-Br 2-CH₃-4-i-C₃F₇1900 i-C₃H₇ H H 3-Br-4-Cl 2-CH₃-4-i-C₃F₇ 1901 i-C₃H₇ H H 3-I-4-F2-CH₃-4-i-C₃F₇ 1902 i-C₃H₇ H H 3-I-4-Cl 2-CH₃-4-i-C₃F₇ 1903 i-C₃H₇ H H3-I-4-CF₃ 2-CH₃-4-i-C₃F₇ 1904 i-C₃H₇ H H 3-I-4-OCH₃ 2-CH₃-4-i-C₃F₇ 1905i-C₃H₇ H H 3-I-4-Br 2-CH₃-4-i-C₃F₇ 1906 i-C₃H₇ H H 3-Cl-4-CF₃2-CH₃-4-i-C₃F₇ 1907 i-C₃H₇ H H 3-CF₃-4-Cl 2-CH₃-4-i-C₃F₇ 1908 i-C₃H₇ H H3-CF₃-4-F 2-CH₃-4-i-C₃F₇ 1919 i-C₃H₇ H H 3-CF₃-4-OCH₃ 2-CH₃-4-i-C₃F₇1910 i-C₃H₇ H H 3-N═CH—CH═CH-4 2-CH₃-4-i-C₃F₇ 1911 i-C₃H₇ H H 3-OCH₂O-42-CH₃-4-i-C₃F₇ 1912 i-C₃H₇ H H 3-OCH₂O-4 2-CH₃-4-C₂F₅ 1913 i-C₃H₇ H H3-OCH₂O-4 2-CH₃-4-OCF₃ 1914 i-C₃H₇ H H 3-OCF₂O-4 2-CH₃-4-i-C₃F₇ 1915i-C₃H₇ H H 3-OCF₂O-4 2-CH₃-4-C₂F₅ 1916 i-C₃H₇ H H 3-OCF₂O-4 2-CH₃-4-OCF₃1917 i-C₃H₇ H H 3-OCH₂CH₂O-4 2-CH₃-4-i-C₃F₇ 1918 i-C₃H₇ H H 3-OCF₂CF₂O-42-CH₃-4-i-C₃F₇ 1919 i-C₃H₇ H H 3-OCHFCF₂O-4 2-CH₃-4-i-C₃F₇ 1920 i-C₃H₇ HH 3-OCF₂CHFO-4 2-CH₃-4-i-C₃F₇ 1921 i-C₃H₇ H H 3-OCH₂CH₂-4 2-CH₃-4-i-C₃F₇1922 i-C₃H₇ H H 3-CH₂CH₂O-4 2-CH₃-4-i-C₃F₇ 1923 i-C₃H₇ H H 3-OCF₂CF₂-42-CH₃-4-i-C₃F₇ 1924 i-C₃H₇ H H 3-CF₂CF₂O-4 2-CH₃-4-i-C₃F₇ 1925 i-C₃H₇ HH 3-SOCH₃ 2-CH₃-4-i-C₃F₇ 1926 i-C₃H₇ H H 3-SO₂CH₃ 2-CH₃-4-i-C₃F₇ 1927i-C₃H₇ H H 3-CF₃S 2-CH₃-4-i-C₃F₇ 222-223 1928 i-C₃H₇ H H 6-CF₃S2-CH₃-4-i-C₃F₇ 219-221 1929 t-C₄H₉ H H 3-CF₃S 2-CH₃-4-i-C₃F₇ 231   1930t-C₄H₉ H H 6-CF₃S 2-CH₃-4-i-C₃F₇ 245-247 1931 t-C₄H₉ H H 3-CF₃SO₂2-CH₃-4-i-C₃F₇ 1932 t-C₄H₉ H H 3-CF₃SO₂ 2-CH₃-4-C₂F₅ 1933 t-C₄H₉ H H3-CF₃SO₂ 2-CH₃-4-OCF₃ 1934 C₂H₅ C₂H₅ H 3-CF₃SO₂ 2-CH₃-4-i-C₃F₇ 1935 C₂H₅C₂H₅ H 3-CONHCH₃ 2-CH₃-4-i-C₃F₇ 1936 C₂H₅ C₂H₅ H 3-CON(CH₃)₂2-CH₃-4-i-C₃F₇ 1937 C₂H₅ C₂H₅ H 3-COCH₃ 2-CH₃-4-i-C₃F₇ 1938 C₂H₅ C₂H₅ H3-COC₂H₅ 2-CH₃-4-i-C₃F₇ 1939 C₂H₅ C₂H₅ H 3-C(CH₃)═NOCH₃ 2-CH₃-4-i-C₃F₇1940 C₂H₅ C₂H₅ H 3-C(CH₃)═NO—C₂H₅ 2-CH₃-4-i-C₃F₇ 1941 i-C₃H₇ H H 3-C≡CH2-CH₃-4-C₂F₅ 1942 i-C₃H₇ H H 3-C≡CH 2-CH₃-4-i-C₃F₇ 1943 i-C₃H₇ H H3-C≡C-t-C₄H₉ 2-CH₃-4-C₂F₅ 195-202 1944 i-C₃H₇ H H 3-C≡C-t-C₄H₉2-CH₃-4-i-C₃F₇ 1945 i-C₃H₇ H H 3-C≡C—Ph 2-CH₃-4-C₂F₅ 179-183 1946 i-C₃H₇H H 3-C≡C—Ph 2-CH₃-4-i-C₃F₇ 1947 i-C₃H₇ H H 3-C≡C—CF₃ 2-CH₃-4-C₂F₅ 1948i-C₃H₇ H H 3-C≡C—CF₃ 2-CH₃-4-i-C₃F₇ 1949 i-C₃H₇ H H 3-C₂F₅ 2-CH₃-4-C₂F₅1950 t-C₄H₉ H H 3-C₂F₅ 2-CH₃-4-C₂F₅ 1951 C₂H₅ C₂H₅ H 3-C₂F₅ 2-CH₃-4-C₂F₅1952 i-C₃H₇ H H 3-C₂F₅ 2-CH₃-4-i-C₃F₇ 1953 t-C₄H₉ H H 3-C₂F₅2-CH₃-4-i-C₃F₇ 1954 C₂H₅ C₂H₅ H 3-C₂F₅ 2-CH₃-4-i-C₃F₇ 1955 i-C₃H₇SN-(n-C₄H₉)₂ H 3-I 2-CH₃-4-i-C₃F₇ 1956 i-C₃H₇ SO₂CH₃ H 3-I2-CH₃-4-i-C₃F₇ 1957 i-C₃H₇ CN H 3-I 2-CH₃-4-i-C₃F₇ 1958 i-C₃H₇ COOCH₃ H3-I 2-CH₃-4-i-C₃F₇ 1959 i-C₃H₇ COOC₂H₅ H 3-I 2-CH₃-4-i-C₃F₇ 1960 i-C₃H₇COCH₃ H 3-I 2-CH₃-4-i-C₃F₇ 1961 i-C₃H₇ COC₂H₅ H 3-I 2-CH₃-4-i-C₃F₇ 1962i-C₃H₇ CO—Ph H 3-I 2-CH₃-4-i-C₃F₇ 1963 i-C₃H₇ NHCOCH₃ H 3-I2-CH₃-4-i-C₃F₇ 1964 C₂H₅ C₂H₅ SN(n-C₄H₉)₂ 3-I 2-CH₃-4-i-C₃F₇ 1965 C₂H₅C₂H₅ SO₂CH₃ 3-I 2-CH₃-4-i-C₃F₇ 1966 C₂H₅ C₂H₅ CN 3-I 2-CH₃-4-i-C₃F₇ 1967C₂H₅ C₂H₅ COOCH₃ 3-I 2-CH₃-4-i-C₃F₇ 1968 C₂H₅ C₂H₅ COOC₂H₅ 3-I2-CH₃-4-i-C₃F₇ 1969 C₂H₅ C₂H₅ COCH₃ 3-I 2-CH₃-4-i-C₃F₇ 1970 C₂H₅ C₂H₅COC₂H₅ 3-I 2-CH₃-4-i-C₃F₇ Amorphous 1971 C₂H₅ C₂H₅ COPh 3-I2-CH₃-4-i-C₃F₇ 1972 C₂H₅ C₂H₅ NHCOCH₃ 3-I 2-CH₃-4-i-C₃F₇ 1973(CH₂)₂COO—CH₃ H H 3-I 2-CH₃-4-i-C₃F₇ 1974 (CH₂)₂COO—CH₃ H H 3-I2-CH₃-4-C₂F₅ 1975 (CH₂)₂COO—C₂H₅ H H 3-I 2-CH₃-4-i-C₃F₇ 133.2 1976(CH₂)₂COO—C₂H₅ H H 3-I 2-CH₃-4-C₂F₅ 1977 (CH₂)₂COO—C₂H₅ H H 6-I2-CH₃-4-C₂F₅ 163.5 1978 CH(CH₃)CH₂— H H 3-I 2-CH₃-4-i-C₃F₇ COOCH₃ 1979CH(CH₃)CH₂COOC₂H₅ H H 3-I 2-CH₃-4-i-C₃F₇ 1980 CH(CH₃)CH₂COO-i-C₃H₇ H H3-I 2-CH₃-4-i-C₃F₇ 1981 (CH₂)₂CONHCH₃ H H 3-I 2-CH₃-4-i-C₃F₇ 1982(CH₂)₂CONHC₂H₅ H H 3-I 2-CH₃-4-i-C₃F₇ 1983 CH(CH₃)CH₂CONHCH₃ H H 3-I2-CH₃-4-i-C₃F₇ 1984 CH(CH₃)CH₂CONHC₂H₅ H H 3-I 2-CH₃-4-i-C₃F₇ 1985CH(CH₃)CH₂CONH-i-C₃H₇ H H 3-I 2-CH₃-4-i-C₃F₇ 1986 CH(CH₃)CH₂CON—(CH₃)₂ HH 3-I 2-CH₃-4-i-C₃F₇ 1987 CH(CH₃)CH₂CON—(C₂H₅)₂ H H 3-I 2-CH₃-4-i-C₃F₇1988 (CH₂)₂NHCOOCH₃ H H 3-I 2-CH₃-4-C₂F₅ 1989 (CH₂)₂NHCOOCH₃ H H 3-I2-CH₃-4-i-C₃F₇ 1990 (CH₂)₂NHCOOC₂H₅ H H 3-I 2-CH₃-4-C₂F₅ 145   1991(CH₂)₂NHCOOC₂H₅ H H 3-I 2-CH₃-4-OCF₃ 210   1992 CH(CH₃)CH₂NHCOOCH₃ H H3-I 2-CH₃-4-i-C₃F₇ 1993 CH(CH₃)CH₂NHCOO—C₂H₅ H H 3-I 2-CH₃-4-i-C₃F₇ 1994(CH₂)₂P(CH₃)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 1995 CH(CH₃)P(C₂H₅)₂ H H 3-I2-CH₃-4-i-C₃F₇ 1996 (CH₂)₂P(Ph)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 1997CH(CH₃)CH₂P(CH₃)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 1998 CH(CH₃)CH₂P(C₂H₅)₂ H H 3-I2-CH₃-4-i-C₃F₇ 1999 CH(CH₃)CH₂P(Ph)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 2000CH(CH₃)(CH₂)₂P—(CH₃)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 2001 CH(CH₃)(CH₂)₃P—(CH₃)₂H H 3-I 2-CH₃-4-i-C₃F₇ 2002 (CH₂)₂PO(CH₃)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 2003(CH₂)₂PO(OC₂H₅)₂ H H 3-I 2-CH₃-4-i-C₃F₇ Amorphous 2004CH(CH₃)CH₂PO(OCH₃)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 2005 (CH₂)₂OPO(OCH₃)₂ H H 3-I2-CH₃-4-i-C₃F₇ 2006 CH(CH₃)CH₂PS(OCH₃)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 2007CH(CH₃)CH₂PS—(OC₂H₅)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 2008 (CH₂)₂OPO(OC₂H₅)₂ H H3-I 2-CH₃-4-i-C₃F₇ 2009 CH(CH₃)CH₂OPO—(OCH₃)₂ H H 3-I 2-CH₃-4-i-C₃F₇2010 CH(CH₃)CH₂OPO—(OC₂H₅)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 2011 (CH₂)₂OPS(OCH₃)₂H H 3-I 2-CH₃-4-i-C₃F₇ 2012 (CH₂)₂OPS(OC₂H₅)₂ H H 3-I 2-CH₃-4-i-C₃F₇2013 CH(CH₃)CH₂OPS—(OCH₃)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 2014CH(CH₃)CH₂OPS—(OC₂H₅)₂ H H 3-I 2-CH₃-4-i-C₃F₇ 2015 CH(CH₃)-2-Pyi-N-OxideH H 3-I 2-CH₃-4-C₂F₅ 198-205 2016 CH(CH₃)-2-Pyi-N-Oxide H H 3-I2-CH₃-4-i-C₃F₇ 208-210 2017 i-C₃H₇ H H 3-I 2-CH₃-4-C(CF₃)═NOCH₃ 2018i-C₃H₇ H H 3-I 2-CH₃-4-C(CF₃)═NOCH₂Ph 2019 i-C₃H₇ H H 3-I 2-NCHCHCHCH-3-180   4-i-C₃F₇ 2020 i-C₃H₇ H H 3-I 2-n-C₃H₇-4-i-C₃F₇ 225   2021 i-C₃H₇ HH 3-I 2-O-(2-Pyi)-4-i-C₃F₇ 158.3-159.8

[0123] The abbreviations in Table 1 stand for the followingsubstituents:

[0124] Ph: phenyl group,

[0125] c-: alicyclic hydrocarbon group,

[0126] Pyi: pyridyl group,

[0127] Pym: pyrimidinyl group,

[0128] Fur: furyl group,

[0129] TetFur: tetrahydrofuryl group,

[0130] Thi: thienyl group,

[0131] Thz: thiazolyl group,

[0132] Naph: naphthyl group,

[0133] Oxa: oxazolyl group,

[0134] C*: asymmetric carbon atom TABLE 2 Physical Properties (meltingNo R¹ R² R³ Xn Ym Z¹ Z² point: ° C. S-1 i-C₃H₇ H H 3-Cl 2-CH₃-4-CF₂CF₃ SO 162-164 S-2 t-C₄H₉ H H 3-Cl 2-CH₃-4-CF₂CF₃ S O 141-143 S-3 c-C₃H₅ H H3-Cl 2-CH₃-4-CF₂CF₃ S O 138-139 S-4 C₂H₅ C₂H₅ H 3-Cl 2-CH₃-4-CF₂CF₃ S O184-186 S-5 i-C₃H₇ H H H 2-CH₃-4-Cl S O 168-170 S-6 i-C₃H₇ H H H2-CH₃-4-Cl O S S-7 i-C₃H₇ H H 3-I 2-CH₃-4-i-C₃H₇ O S S-8 i-C₃H₇ H H H2-CH₃-4-i-C₃H₇ S S S-9 i-C₃H₇ H H 3-I 2-CH₃-4-i-C₃H₇ S S

[0135] The ¹H-NMR data of the compounds obtained as paste (physicalproperties) are given in Table 3 below. TABLE 3 No. ¹H-NMR[CDCl₃/TMS, δvalues (ppm)] 1122 1.2-1.4(m.6H), 2.4-2.5(m.3H), 3.1-3.9(m.7H),6.6-7.9(m.6H) 1218 1.3(d.3H), 2.3(s.3H), 2.9-3.2(m.2H), 4.4(m.1H),6.2(d.1H), 7.1-7.5(m.3H), 7.8(d.1H), 8.0(d.1H), 8.4(d.1H), 8.5(s.1H).

[0136] The fluorine-containing aniline compound of the general formula(ST-I) of the present invention is useful as an intermediate of amedicine, agrochemical, chemical product etc., particularly, is usefulas a starting material of the phthalic acid diamide derivative of thegeneral formula (I) of the present invention. That is, thefluorine-containing aniline compound of the general formula (ST-I) isuseful as an aniline of the general formula (IV) in the Productionprocesses 1, 3, 5 and 6 as illustrated above. The fluorine-containinganiline compound of the general formula (ST-I) of the present inventioncan be produced, for example, by any of the following productionprocesses.

Production Process 8.

[0137]

[0138] wherein each of X^(a), X^(b) and X^(c) is a hydrogen atom, aniodine atom or a bromine atom, provided that at least one of X^(a),X^(b) and X^(c) is not a hydrogen atom, and R^(a), R^(b), R^(c) andR^(d) are as defined above.

[0139] A fluorine-containing aniline compound of the general formula(ST-I) can be produced by reacting an aniline derivative of the generalformula (ST-II) with a perfluoroalkyl iodide of the general formula(ST-III), general formula (ST-IV) or general formula (ST-V) in thepresence of activated copper powder and an inert solvent.

[0140] Usually, the amount of each of the perfluoro-alkyl iodide of thegeneral formula (ST-III), (ST-IV) or (ST-V) and the activated copperpowder used may be properly chosen in the range of 1 to 5 times theamount of the aniline derivative of the general formula (ST-II).

[0141] As the inert solvent used in the reaction, any solvent may beused so long as it does not remarkably inhibit the progress of thereaction. There can be used, for example, aprotic polar solvents such asN,N-dimethyl-formamide (DMF), dimethyl sulfoxide (DMSO), etc. Thereaction temperature may be properly chosen in the range of roomtemperature to 200° C.

[0142] After completion of the reaction, the desired compound isisolated from the reaction mixture containing the desired compound by aconventional method and can, if necessary, be purified by silica gelchromatography, distillation, recrystallization, etc.

[0143] The reaction can be carried out by the method described in Bull.Chem. Soc. Jpn., 65, 2141-2144 (1992).

Production process 9.

[0144]

[0145] wherein R^(a), R^(b), R^(c), R^(d), X^(a), X^(b) and X^(c) are asdefined above, and R^(e) is a protecting group such as an acyl group.

[0146] A fluorine-containing aniline compound of the general formula(ST-I) can be produced by reacting an acylaniline derivative of thegeneral formula (ST-VI) with a perfluoroalkyl iodide of the generalformula (ST-III), general formula (ST-IV) or general formula (ST-V) inthe presence of activated copper powder and an inert solvent to obtainan acylaniline derivative of the general formula (ST-VII), anddeacylating the acylaniline derivative (ST-VII) after or withoutisolation.

General formula (ST-VI)→general formula (ST-VII)  {circle over (1)}

[0147] This reaction can be carried out according to production process8.

General formula (ST-VII)→general formula (ST-I)  {circle over (2)}

[0148] This reaction is usually carried out under acidic conditions. Inthe reaction, for example, an aqueous mineral acid solution such as a 5to 35% aqueous hydrochloric acid solution is used as an acid. Ifnecessary, there may be used together therewith alcohols such asmethanol, ethanol, etc., and inert solvents such as tetrahydrofuran(THF), acetonitrile, etc. The reaction temperature may be chosen in therange of room temperature to the boiling point of the solvent used. Thedesired compound can be produced by carrying out the similar workup asin production process 8.

Production Process 10.

[0149]

[0150] wherein R^(a), R^(b), R^(c), R^(d), X^(a), X^(b) and X^(c) are asdefined above.

[0151] A fluorine-containing aniline compound of the general formula(ST-I) can be produced by reacting a nitrobenzene derivative of thegeneral formula (ST-VIII) with a perfluoroalkyl iodide of the generalformula (ST-III), general formula (ST-IV) or general formula (ST-V) inthe presence of activated copper powder and an inert solvent to obtain anitrobenzene derivative of the general formula (ST-IX), and reducing thenitrobenzene derivative (ST-IX) after or without isolation.

General formula (ST-VIII)→general formula (ST-IX)  {circle over (1)}

[0152] This reaction can be carried out according to production process8.

General formula (ST-IX)→general formula (ST-I)  {circle over (2)}

[0153] Usually, the desired compound can be produced by subjecting thenitrobenzene derivative (ST-IX) to catalytic hydrogenation in an alcoholsolvent in the presence of a catalyst such as 5% palladium carbon(proportion: 1 to 5% by weight), or reducing the nitro-benzenederivative (ST-IX) with an aqueous hydrochloric acid solution containingstannous chloride, in a solvent such as ethanol.

[0154] The reaction {circle over (2)} can be carried out according tothe method described in Journal of Chemical Society of Japan, 1973,2351.

[0155] Typical examples of the fluorine-containing aniline compound ofthe general formula (ST-I) of the present invention are given in Table 4but they are not intended in any way to limit the scope of the presentinvention.

General Formula (ST-I):

[0156] TABLE 4 (ST-I)

Physical property or No. R^(a) R^(b) R^(c) R^(d) ¹H-NMR (δ, ppm) ST-1CH₃ H H C₂F₅ 2.21(s, 3H), 3.84(br, 2H), 6.86(s, 1H), 6.91(d, 1H),7.15(d, 1H). ST-2 CH₃ H H i-C₃F₇ ST-3 CH₃ H C₂F₅ H b.p. 95-105° C./10mmHg ST-4 CH₃ H i-C₃F₇ H b.p. 100-110° C./10 mmHg ST-5 CH₃ H n-C₃F₇ H2.20(s, 3H), 3.9(br, 2H), 6.70(d, 1H), 7.22-7.27(m, 2H). ST-6 CH₃ Hn-C₄F₉ H 2.19(s, 3H), 4.2(br, 2H), 6.70(d, 1H), 2.70-7.26(m, 2H). ST-7CH₃ H CF(CF₃)—C₂F₅ H ST-8 CH₃ C₂F₅ H H 2.22(s, 3H), 3.83(br, 2H),6.86(d, 1H), 6.99(d, 1H), 7.12(t, 1H). ST-9 CH₃ i-C₃F₇ H H ST-10 F Hi-C₃F₇ H ST-11 Cl H C₂F₅ H 4.4(br, 2H), 6.8(d, 1H), 7.27(dd, 1H),7.47(d, 1H). ST-12 Cl H i-C₃F₇ H 4.5(br, 2H), 7.41(s, 1H), 7.81(d, 1H),8.05(d, 1H). ST-13 Cl H n-C₃F₇ H 4.1(br, 2H), 6.83(d, 1H), 7.24(d, 1H),7.43(s, 1H). ST-14 Br H C₂F₅ H ST-15 OCH₃ H C₂F₅ H 3.85(br, 2H), 3.93(s,3H), 6.72(d, 1H), 6.92(s, 1H), 7.03(d, 1H). ST-16 OCH₃ H i-C₃F₇ H ST-17OC₂H₅ H i-C₃F₇ H ST-18 C₂H₅ H C₂F₅ H 1.29(t, 3H), 2.52(q, 2H), 3.95(br,2H), 6.8(d, 1H), 7.2-7.26 (m, 2H). ST-19 C₂H₅ H i-C₃F₇ H ST-20 i-C₃F₇ Hi-C₃F₇ H ST-21 n-C₄H₉ H C₂F₅ H 0.9(t, 3H), 1.4(q, 2H), 1.6(q, 2H),2.5(t, 2H), 3.95(br, 2H), 6.69(d, 2H), 7.19-7.21(m, 2H). ST-22 CF₃ HC₂F₅ H 4.52(br, 2H), 6.81(d, 1H), 7.48(d, 1H), 7.63(br, 1H). ST-23 CF₃ Hi-C₃F₇ H

[0157] Agricultural and horticultural insecticides containing thephthalic acid diamide derivative of the general formula (I) of thepresent invention as an active ingredient are suitable for controllingvarious insect pests such as agricultural insect pests, forest insectpests, horticultural insect pests, stored grain insect pests, sanitaryinsect pests, nematodes, etc., which are injurious to paddy rice, fruittrees, vegetables, other crops, flowers and ornamental plants, etc. Theyhave a marked insecticidal effect, for example, on LEPIDOPTERA includingsummer fruit tortrix (Adoxophyes orana fasciata), smaller tea tortrix(Adoxophyes sp.), Manchurian fruit moth (Grapholita inopinata), orientalfruit moth (Grapholita molestal ), soybean pod border (Leguminivoraglycinivorella), mulberry leafroller (Olethreutes mori), tea leafroller(Caloptilia thevivora), Caloptilia sp. (Calopilia zachrysa), appleleafminer (Phyllonorycter ringoniella), pear barkminer (Spulerrinaastaurota), common white (Piers rapae crucivora), tabacco budworm(Heliothis sp.), codling moth (Laspey resia pomonella), diamondback moth(Plutella xylostella), apple fruit moth (Argyresthia conjugella), peachfruit moth (Carposina niponensis), rice stem borer (Chilo suppressalis),rice leafroller (Cnaphalocrocis medinalis), tabacco moth (Ephestiaelutella), mulberry pyralid (Glyphodes pyloalis), yellow rice borer(Scirpophaga incertulas), rice skipper (Parnara guttata), rice armyworm(Pseudaletia separata), pink borer (Sesamia inferens), common cutworm(Spodoptera litura), beet armyworm (Spodoptera exigua), etc.; HEMIPTERAincluding aster leafhopper (Macrosteles fascifrons), green riceleafhopper (Nephotettix cincticeps), brown rice planthopper (Nilaparvatalugens), whitebacked rice planthopper (Sogatella furcifera), citruspsylla (Diaphorina citri), grape whitefly (Aleurolobus taonabae),sweetpotato whitefly (Bemisia tabaci), greenhouse whitefly (Trialeurodesvaporariorum), turnip aphid (Lipaphis erysimi), green peach aphid (Myzuspersicae), Indian wax scale (Ceroplastes ceriferus), cottony citrusscale (Pulvinaria aurantii), camphor scale (Pseudaonidia duplex), SanJose scale (Comstockaspis perniciosa), arrowhead scale (Unaspisyanonensis), etc.; COLEOPTERA including soybean beetle (Anomalarufocuprea), Japanese beetle (Popillia japonica), tabacco beetle(Lasioderma serricorne), powderpost beetle (Lyctus brunneus),twenty-eight-spotted ladybird (Epilachna vigintiotopunctata), adzukibean weevile (Callosobruchus chinensis), vegetable weevil (Listroderescostirostris), maize weevil (Sitophilus zeamais), boll weevil(Anthonomus gradis gradis), rice water weevil (Lissorhoptrusoryzophilus), cucurbit leaf beetle (Aulacophora femoralis), rice leafbeetle (Oulema oryzae), striped flea beetle (Phyllotreta striolata),pine shoot beetle (Tomicus piniperda), Colorado potato beetle(Leptinotarsa decemlineata), Mexican bean beetle (Epilachna varivestis),corn rootworm (Diabrotica sp.), etc.; DIPTERA including melon fly(Dacus(Zeugodacus) cucurbitae), oriental fruit fly (Dacus(Bactrocera)dorsalis), rice leafminer (Agnomyza oryzae), onion maggot (Deliaantiqua), seedcorn maggot (Delia platura), soybean pod gall midge(Asphondylia sp.), muscid fly (Musca domestica), house mosquito (Culexpipiens pipiens), etc.; and TYLENCHIDA including root-lesion nematode(Pratylenchus sp.), coffer root-lesion nematode (Pratylenchus coffeae),potato cyst nematode (Globodera rostochiensis), root-knot nematode(Meloidogyne sp.), citrus nematode (Tylenchulus semipenetrans),Aphelenchus sp. (Aphelenchus avenae), chrysanthemum foliar(Aphelenchoides ritzemabosi), etc.

[0158] The agricultural and horticultural insecticide containing thephthalic acid diamide derivative of the general formula (I) of thepresent invention as an active ingredient has a marked insecticidaleffect on the above-exemplified insect pests, sanitary insect pests,and/or nematodes, which are injurious to paddy field crops, uplandcrops, fruit trees, vegetables, other crops, flowers and ornamentplants, and the like. Therefore, the desired effect of the agriculturaland horticultural insecticide of the present invention can be obtainedby applying the insecticide to the paddy field water, stalks and leavesof fruit trees, vegetables, other crops, flowers and ornament plants,soil, etc. at a season at which the insect pests, sanitary pests ornematodes are expected to appear, before their appearance or at the timewhen their appearance is confirmed.

[0159] In general, the agricultural and horticultural insecticide of thepresent invention is used after being prepared into conveniently usableforms according to an ordinary manner for preparation of agrochemicals.

[0160] That is, the phthalic acid diamide derivative of the generalformula (I) and, optionally, an adjuvant are blended with a suitableinert carrier in a proper proportion and prepared into a suitablepreparation form such as a suspension, emulsifiable concentrate, solubleconcentrate, wettable powder, granules, dust or tablets throughdissolution, dispersion, suspension, mixing, impregnation, adsorption orsticking.

[0161] The inert carrier used in this invention may be either solid orliquid. As the solid carrier, there can be exemplified soybean flour,cereal flour, wood flour, bark flour, saw dust, powdered tobacco stalks,powdered walnut shells, bran, powdered cellulose, extraction residues ofvegetables, powdered synthetic polymers or resins, clays (e.g. kaolin,bentonite, and acid clay), talcs (e.g. talc and pyrophyllite), silicapowders or flakes (e.g. diatomaceous earth, silica sand, mica and whitecarbon, i.e. synthetic, high-dispersion silicic acid, also called finelydivided hydrated silica or hydrated silicic acid, some of commerciallyavailable products contain calcium silicate as the major component),activated carbon, powdered sulfur, powdered pumice, calcineddiatomaceous earth, ground brick, fly ash, sand, calcium carbonatepowder, calcium phosphate powder and other inorganic or mineral powders,chemical fertilizers (e.g. ammonium sulfate, ammonium phosphate,ammonium nitrate, urea and ammonium chloride), and compost. Thesecarriers may be used alone or as a mixture thereof.

[0162] The liquid carrier is that which itself has solubility or whichis without such solubility but is capable of dispersing an activeingredient with the aid of an adjuvant. The following are typicalexamples of the liquid carrier and can be used alone or as a mixturethereof. Water; alcohols such as methanol, ethanol, isopropanol, butanoland ethylene glycol; ketones such as acetone, methyl ethyl ketone,methyl isobutyl ketone, diisobutyl ketone and cyclohexanone; ethers suchas ethyl ether, dioxane, Cellosolve, dipropyl ether andtetrahydro-furan; aliphatic hydrocarbons such as kerosene and mineraloils; aromatic hydrocarbons such as benzene, toluene, xylene, solventnaphtha and alkylnaphthalenes; halogenated hydrocarbons such asdichloroethane, chloroform, carbon tetrachloride and chlorobenzene;esters such as ethyl acetate, diisopropyl phthalate, dibutyl phthalateand dioctyl phthalate; amides such as dimethylformamide,diethylformamide and dimethylacetamide; nitriles such as acetonitrile;and dimethyl sulfoxide.

[0163] The following are typical examples of the adjuvant, which areused depending upon purposes and used alone or in combination in somecases, or need not to be used at all.

[0164] To emulsify, disperse, dissolve and/or wet an active ingredient,a surfactant is used. As the surfactant, there can be exemplifiedpolyoxyethylene alkyl ethers, polyoxyethylene alkylaryl ethers,polyoxyethylene higher fatty acid esters, polyoxyethylene resinates,polyoxyethylene sorbitan mono-laurate, polyoxyethylene sorbitanmonooleate, alkylarylsulfonates, naphthalene-sulfonic acid condensationproducts, ligninsulfonates and higher alcohol sulfate esters.

[0165] Further, to stabilize the dispersion of an active ingredient,tackify it and/or bind it, there may be used adjuvants such as casein,gelatin, starch, methyl cellulose, carboxymethyl cellulose, gum arabic,polyvinyl alcohols, turpentine, bran oil, bentonite andligninsulfonates.

[0166] To improve the flowability of a solid product, there may be usedadjuvants such as waxes, stearates and alkyl phosphates.

[0167] Adjuvants such as naphthalenesulfonic acid condensation productsand polycondensates of phosphates may be used as a peptizer fordispersible products.

[0168] Adjuvants such as silicon oils may also be used as a defoamingagent.

[0169] The content of the active ingredient may be varied as required.In dusts or granules, the suitable content thereof is from 0.01 to 50%by weight. In emulsifiable concentrates or flowable wettable powders, itis also from 0.01 to 50% by weight.

[0170] The agricultural and horticultural insecticide of the presentinvention is used to control a variety of insect pests in the followingmanner. That is, it is applied to a crop on which the insect pests areexpected to appear or a site where the appearance of the insect pests isundesirable, as it is or after being properly diluted with or suspendedin water or the like, in an amount effective for control of the insectpests.

[0171] The applying dosage of the agricultural and horticulturalinsecticide of the present invention is varied depending upon variousfactors such as a purpose, insect pests to be controlled, a growth stateof a plant, tendency of insect pests appearance, weather, environmentalconditions, a preparation form, an application method, an applicationsite and an application time. It may be properly chosen in a range of0.1 g to 10 kg (in terms of the active ingredient) per 10 ares dependingupon purposes.

[0172] The agricultural and horticultural insecticide of the presentinvention may be used in admixture with other agricultural andhorticultural disease or pest controllers in order to expand bothspectrum of controllable diseases and insect pest species and the periodof time when effective applications are possible or to reduce thedosage.

[0173] Typical examples of the present invention are described below,but they should not be construed as limiting the scope of the invention.

EXAMPLES Example 1 (1-1) Production of3-chloro-N-[4-(1,1,2,2-tetrafluoro-ethoxy)-2-methylphenyl]phthalimide

[0174] In 10 ml of acetic acid were dissolved 0.55 g of 3-chlorophthalicanhydride and 0.67 g of 4-(1,1,2,2-tetrafluoroethoxy)-2-methylaniline,and the reaction was carried out with heating under reflux for 3 hours.After completion of the reaction, the solvent was distilled off underreduced pressure and the resulting residue was washed with anether-hexane mixed solvent to obtain 1.1 g of the desired compound.

[0175] Physical property: m.p. 121-122° C. Yield: 95%.

(1-2) Production of3-chloro-N¹-[4-(1,1,2,2-tetrafluoroethoxy)-2-methylphenyl]-N²-isopropylphthalicacid diamide (compound No. 141) and6-chloro-N¹-[4-(1,1,2,2-tetrafluoroethoxy)-2-methylphenyl]-N²-isopropylphthalicacid diamide (compound No. 239)

[0176] In 10 ml of dioxane was dissolved 1.1 g of3-chloro-N-[4-(1,1,2,2-tetrafluoroethoxy)-2-methylphenyl]-phthalimide,followed by adding thereto 0.5 g of isopropylamine, and the reaction wascarried out at 80° C. for 3 hours. After completion of the reaction, thesolvent was distilled off under reduced pressure and the resultingresidue was purified by a silica gel column chromatography using ahexane/ethyl acetate (2/1) mixed solvent as an eluent, to obtain 0.4 gof the desired compound (compound No. 141) having an Rf value of 0.5 to0.7 and 0.5 g of the other desired compound (compound No. 239) having anRf value of 0.2 to 0.4.

[0177] Compound No. 141:

[0178] Physical property: m.p. 202-204° C. Yield: 31%.

[0179] Compound No. 239:

[0180] Physical property: m.p. 199-201° C. Yield: 39%.

Example 2 (2-1) Production ofN-(4-trifluoromethoxyphenyl)-3-nitrophthalimide

[0181] In 50 ml of acetic acid were dissolved 5.97 g of 3-nitrophthalicanhydride and 5.31 g of 4-trifluoromethoxyaniline, and the reaction wascarried out with heating under reflux for 3 hours. After completion ofthe reaction, the solvent was distilled off under reduced pressure andthe resulting residue was washed with an ether-hexane mixed solvent toobtain 10.2 g of the desired compound.

[0182] Physical property: m.p. 149-150° C. Yield: 97%.

(2-2) Production of 3-amino-N-(4-trifluoromethoxy-phenyl)phthalimide

[0183] In a pressure vessel were placed 10.0 g ofN-(4-trifluoromethoxyphenyl)-3-nitrophthalimide, 100 ml of acetic acidand 0.5 g of 5% palladium carbon, and catalytic reduction with hydrogenwas carried out at a hydrogen pressure of 5 kg/cm². After completion ofthe reaction, the catalyst was filtered off and the filtrate wasconcentrated under reduced pressure. The resulting residue was washedwith an ether-hexane mixed solvent to obtain 9.0 g of the desiredcompound.

[0184] Physical property: m.p. 161-162° C. Yield: 98%.

(2-3) Production of 3-bromo-N-(4-trifluoromethoxy-phenyl)phthalimide

[0185] In 20 ml of acetic acid was dissolved 1.6 g of3-amino-N-(4-trifluoromethoxyphenyl)phthalimide, and a solution of 0.35g of sodium nitrite in 5 ml of concentrated sulfuric acid was addeddropwise while maintaining the temperature at 15° C. or lower. Theresulting mixture was stirred at 15° C. or lower for another 20 minutesto obtain a diazonium salt. The diazonium salt was slowly added to amixture of a solution of 0.86 g of cuprous bromide in 50 ml ofhydrobromic acid and 10 ml of toluene which was maintained at 80° C. Theresulting mixture was stirred until foaming ceased. After completion ofthe reaction, the organic layer was washed with an aqueous sodiumthiosulfate solution and an aqueous sodium chloride solution, dried overanhydrous magnesium sulfate, and then distilled under reduced pressureto remove the solvent, and the resulting residue was purified by asilica gel chromatography to obtain 1.3 g of the desired compound.

[0186] Physical property: m.p. 117-118° C. Yield: 67%.

(2-4) Production of3-bromo-N¹-(4-trifluoromethoxyphenyl)-N²-isopropylphthalic acid diamide(compound No. 262) and6-bromo-N¹-(4-trifluoromethoxyphenyl)-N²-isopropylphthalic acid diamide(compound No. 302)

[0187] From 1.3 g of 3-bromo-N-(4-trifluoromethoxy-phenyl)phthalimide,0.5 g of the desired compound (compound No. 262) and 0.7 g of the otherdesired compound (compound No. 302) were obtained in the same manner asin Example 1-2.

[0188] Compound No. 262:

[0189] Physical property: m.p. 208-210° C. Yield: 33%.

[0190] Compound No. 302:

[0191] Physical property: m.p. 210-212° C. Yield: 47%.

Example 3 (3-1) Production ofN-(4-difluoromethoxy-2-methylphenyl)-3-nitrophthalimide

[0192] In 100 ml of acetic acid were dissolved 5.8 g of 3-nitrophthalicanhydride and 5.2 g of 4-difluoromethoxy-2-methylaniline, and thereaction was carried out with heating under reflux for 3 hours. Aftercompletion of the reaction, the solvent was distilled off under reducedpressure and the resulting residue was washed with an ether-hexane mixedsolvent to obtain 10.2 g of the desired compound.

[0193] Physical property: m.p. 163-164° C. Yield: 98%.

(3-2) Production of N¹-( 4-difluoromethoxy-2-methylphenyl)-N²-isopropyl-3-nitrophthalic acid diamide (compound No. 696)

[0194] In 100 ml of dioxane was dissolved 10 g ofN-(4-difluoromethoxy-2-methylphenyl)-3-nitrophthalimide, followed byadding thereto 2.5 g of isopropylamine, and the reaction was carried outfor 3 hours. After completion of the reaction, the solvent was distilledoff under reduced pressure and the resulting residue was washed withether to obtain 4.0 g of the desired compound.

[0195] Physical property: m.p. 148-149° C. Yield: 86%.

(3-3) Production of3-amino-N¹-(4-difluoromethoxy-2-methylphenyl)-N²-isopropylphthalic aciddiamide

[0196] In a pressure vessel were placed 5 g ofN¹-(4difluoromethoxy-2-methylphenyl)-N²-isopropyl-3-nitrophthalic aciddiamide, 50 ml of acetic acid and 0.25 g of 5% palladium carbon, andcatalytic reduction with hydrogen was carried out at a hydrogen pressureof 5 kg/cm². After completion of the reaction, the catalyst was filteredoff and the filtrate was concentrated under reduced pressure. Theresulting residue was washed with an ether-hexane mixed solvent toobtain 4.0 g of the desired compound.

[0197] Physical property: m.p. 148-149° C. Yield: 86%.

(3-4) Production ofN¹-(4-difluoromethoxy-2-methylphenyl)-3-iodo-N²-isopropylphthalic aciddiamide (compound No. 387)

[0198] In 20 ml of acetic acid was dissolved 1.89 g of 3-amino-N¹-(4-difluoromethoxy-2-methylphenyl) -N2-isopropyl-phthalic acid diamide,and 1.5 g of concentrated sulfuric acid was added under ice-cooling.While maintaining the resulting solution at 15° C. or lower, a solutionof 0.35 g of sodium nitrite in 0.5 ml of water was added dropwise. Theresulting solution was stirred at 15° C. or lower for another minutes toobtain a diazonium salt. The diazonium salt was slowly added to amixture of 50 ml of an aqueous solution containing 1.0 g of potassiumiodide and 50 ml of chloroform which was maintained at 40° C. Theresulting mixture was stirred until foaming ceased. After completion ofthe reaction, the organic layer was washed with an aqueous sodiumthiosulfate solution and an aqueous sodium chloride solution, dried overanhydrous magnesium sulfate, and then distilled under reduced pressureto remove the solvent, and the resulting residue was purified by asilica gel chromatography to obtain 0.8 g of the desired compound.

[0199] Physical property: m.p. 207-209° C. Yield: 33%.

Example 4 (4-1) Production of 3-iodo-2-N-isopropyl-phthalamic acid

[0200] A solution of 0.67 g of isopropylamine in 5 ml of acetonitrilewas added dropwise to a solution of 1.37 g of 3-iodophthalic anhydridein 10 ml of acetonitrile under ice-cooling, and the reaction was carriedout with stirring at room temperature for another 5 hours. Aftercompletion of the reaction, the crystals formed in the reaction solutionwere collected by filtration and washed with a small volume ofacetonitrile to obtain 1.45 g of the desired compound.

[0201] Yield: 87%. H-NMR [CDCl₃/TMS, δ values (ppm)] 1.23(6H, d),4.35(1H, m), 5.80(1H, d), 6.85(1H, broad), 7.07(1H, t), 7.93(1H, d),7.96(1H, d).

(4-2) Production of 6-iodo-N-isopropyl-phthalic acid isoimide

[0202] In 10 ml of toluene was dissolved 0.45 g of3-iodo-2-N-isopropyl-phthalamic acid, followed by adding thereto 0.85 gof trifluoroacetic anhydride, and the reaction was carried out withstirring for 30 minutes. After completion of the reaction, the solventwas distilled off under reduced pressure to obtain 0.43 g of the desiredcompound as a crude product. The obtained desired compound was used inthe subsequent reaction without purification.

[0203] Physical property: m.p. 87.5-88.5° C.

(4-3) Production of3-iodo-N¹-(4-pentafluoroethyl-2-methylphenyl)-N²-isopropyl-phthalic aciddiamide (compound No. 372)

[0204] In 10 ml of tetrahydrofuran was dissolved 0.43 g of the6-iodo-N-isopropyl-phthalic acid isoimide obtained - in 4-2, followed byadding thereto 0.30 g of 4-pentafluoro-ethyl-2-methylaniline, and thereaction was carried out with stirring for 1 hour. After completion ofthe reaction, the solvent was removed from the reaction solution bydistillation under reduced pressure, and the resulting residue waswashed with ether-n-hexane to obtain 0.70 g of the desired compound.

[0205] Physical property: m.p. 195-196° C. Yield: 95%.

Example 5 (5-1) Production of ethyl6-nitro-N-(4-chloro-2-methylphenyl)-phthalamate

[0206] In 30 ml of tetrahydrofuran was dissolved 1.29 g of3-nitro-2-ethoxycarbonylbenzoyl chloride, followed by adding thereto0.71 g of 4-chloro-2-methylaniline and 0.56 g of triethylamine, and thereaction was carried out with stirring for 30 minutes. After completionof the reaction, the reaction solution containing the desired compoundwas poured into water and the desired compound was extracted with ethylacetate. The extracted solution was dried over anhydrous magnesiumsulfate and distilled under reduced pressure to remove the solvent, andthe resulting residue was purified by a silica gel column chromatographyto obtain 1.7 g of the desired compound.

[0207] Physical property: m.p. 164-165° C. Yield: 94%.

(5-2) Production of3-nitro-N¹-(4-chloro-2-methylphenyl)-N²-isopropyl-phthalic acid diamide(compound No. 664)

[0208] In 20 ml of dioxane was dissolved 1.7 g of ethyl6-nitro-N-(4-chloro-2-methylphenyl)-phthalamate, followed by addingthereto 1.5 g of isopropylamine, and the reaction was carried out withstirring at 80° C. for 1 hour. After completion of the reaction, thesolvent was removed from the reaction solution containing the desiredcompound, by distillation under reduced pressure, and the resultingresidue was purified by a silica gel column chromatography to obtain 1.5g of the desired compound.

[0209] Physical property: m.p. 202-204° C. Yield: 85%.

Example 6 (6-1) Production of N-isopropyl-3,4-dichlorophthalamic acid

[0210] In 30 ml of tetrahydrofuran was dissolved 2.32 g ofN-isopropyl-3,4-dichlorobenzamide, and 21 ml of s-BuLi (0.96 M/L) wasslowly added while maintaining the temperature at −70° C. The resultingmixture was stirred at −70° C. for 30 minutes, after which the coolingbath was removed. An excess of carbon dioxide was introduced into thereaction solution, and the thus treated solution was stirred at roomtemperature for 30 minutes to carry out the reaction.

[0211] After completion of the reaction, the reaction solution waspoured into water and acidified with diluted hydrochloric acid, and thedesired compound was extracted with ethyl acetate. The extractedsolution was dried over anhydrous magnesium sulfate and distilled underreduced pressure to remove the solvent, and the crystals thus obtainedwere washed with an ether-hexane mixed solvent to obtain 2.4 g of thedesired compound.

[0212] Physical property: m.p. 155-156° C. Yield: 86.9%.

(6-2) Production of N-isopropyl-3,4-dichlorophthalic acid isoimide

[0213] In 10 ml of toluene was dissolved 0.41 g ofN-isopropyl-3,4-dichlorophthalamic acid, followed by adding thereto 0.42g of trifluoroacetic anhydride, and the reaction was carried out withstirring at room temperature for 30 minutes. After completion of thereaction, the solvent was distilled off under reduced pressure to obtain0.39 g of the desired compound as a crude product. The obtained desiredcompound was used in the subsequent reaction without purification.

(6-3) Production of3,4-dichloro-N¹-(4-pentafluoroethyl-2-methylphenyl)-N²-isopropylphthalicacid diamide (compound No. 1222)

[0214] In 10 ml of acetonitrile was dissolved 0.39 g ofN-isopropyl-3,4-dichlorophthalic acid isoimide, followed by addingthereto 0.34 g of 4-pentafluoroethyl-2-methyl-aniline, and the reactionwas carried out with stirring for 2 hours. After completion of thereaction, the reaction solution was maintained at 0° C. for 10 minutesand the crystals precipitated were collected by filtration and washedwith hexane to obtain 0.61 g of the desired compound.

[0215] Physical property: m.p. 208-209° C. Yield: 84.1%.

Example 7 Production of3-chloro-2-isopropylamino-thiocarbonyl-N-(pentafluoroethyl-2-methylphenyl)benzamide(compound No. S-1)

[0216] In 20 ml of tetrahydrofuran was dissolved 1.06 g ofN-(pentafluoroethyl-2-methylphenyl)-3-chlorobenzamide, and 7 ml ofs-BuLi (0.96 M/L) was slowly added while maintaining the temperature at−70° C. The resulting mixture was stirred at −70° C. for 30 minutes,after which the cooling bath was removed. A solution of 0.33 g ofisopropyl isothiocyanate in 5 ml of tetrahydrofuran was poured into thereaction solution, and the resulting solution was stirred at roomtemperature for 30 minutes to carry out the reaction.

[0217] After completion of the reaction, the reaction solution waspoured into water and acidified with diluted hydrochloric acid, and thedesired compound was extracted with ethyl acetate. The extractedsolution was dried over anhydrous magnesium sulfate and distilled underreduced pressure to remove the solvent, and the crystals thus obtainedwere washed with an ether-hexane mixed solvent to obtain 1.2 g of thedesired compound.

[0218] Physical property: m.p. 162-164° C. Yield: 86%.

Example 8 Production of 2-methyl-4-pentafluoroethyl-aniline (compoundNo. ST-3)

[0219]

[0220] In an autoclave were placed 11.7 g (0.05 mole) of2-methyl-4-iodoaniline, 6.4 g of copper powder, 18.5 g ofiodopentafluoroethane and 100 ml of DMSO, and the reaction was carriedout with stirring for 6 hours while maintaining the internal temperatureat 120° C. After completion of the reaction, the reaction mixture wascooled to room temperature, poured into 500 ml of ice water, andthoroughly stirred. Then, the insoluble materials were removed and thedesired compound was extracted with 300 ml of ethyl acetate. The extractsolution was washed with water, dried over anhydrous sodium sulfate andthen concentrated, after which the residue was purified by vacuumdistillation to obtain 9.8 g of the desired compound.

[0221] Physical property: b.p. 95-105C./10 mmHg. Yield: 87%.

Example 9 (9-1). Production of 2-ethyl-4-pentafluoroethylacetanilide

[0222]

[0223] In an autoclave were placed 4.0 g (0.0138 mole) of2-ethyl-4-iodoacetanilide, 1.8 g of copper powder, 5.1 g ofiodopentafluoroethane and 40 ml of DMSO, and the reaction was carriedout with stirring for 6 hours while maintaining the internal temperatureat 120° C. After completion of the reaction, the reaction mixture wascooled to room temperature, poured into 200 ml of ice water, andthoroughly stirred. Then, the insoluble materials were removed and thedesired compound was extracted with 200 ml of ethyl acetate. The extractsolution was washed with water, dried over anhydrous sodium sulfate andthen concentrated, after which the residue was purified by a silica gelcolumn chromatography to obtain 0.7 g (yield: 18%) of the desiredcompound.

(9-2). Production of 2-ethyl-4-pentafluoroethylaniline (compound No.ST-18)

[0224]

[0225] To 10 ml of a 6N aqueous hydrochloric acid solution was added 0.6g (2.1 mmoles) of 2-ethyl-4-pentafluoroethylacetanilide, and thereaction was carried out with heating under reflux for 2 hours. Aftercompletion of the reaction, the reaction solution was ice-cooled andthen neutralized with a 10% aqueous sodium hydroxide solution, and thedesired compound was extracted with ethyl acetate. The extract solutionwas washed with water, dried over anhydrous sodium sulfate and thenconcentrated under reduced pressure to obtain 0.4 g of the desiredcompound.

[0226] Physical property: H-NMR (δ, ppm) 1.29(t, 3H), 2.52(q, 2H),3.95(br, 2H), 6.8(d, 1H), 7.2-7.26(m, 2H). Yield: 80%.

Example 10 Production of 2-chloro-4-pentafluoroethyl-aniline (compoundNo. ST-11)

[0227]

[0228] In an autoclave were placed 5.0 g (19.7 mmoles) of2-chloro-4-iodoaniline, 2.8 g of copper powder, 10.0 g ofiodopentafluoroethane and 50 ml of DMF, and the reaction was carried outwith stirring for 20 hours while maintaining the internal temperature at135° C. After completion of the reaction, the reaction mixture wascooled to room temperature, poured into 200 ml of ice water, andthoroughly stirred. Then, the insoluble materials were removed and thedesired compound was extracted with 200 ml of ethyl acetate. The extractsolution was washed with water, dried over anhydrous sodium sulfate andthen concentrated, after which the residue was purified by a silica gelcolumn chromatography to obtain 4.2 g of the desired compound.

[0229] Physical property: ¹H-NMR (δ, ppm) 4.4(br, 2H), 6.8(d, 1H),7.27(dd, 1H), 7.47(d, 1H). Yield: 87%.

Example 11 Production of 2-trifluoromethyl-4-pentafluoroethylaniline(compound No. ST-22)

[0230]

[0231] In an autoclave were placed 6.0 g (20.9 moles) of2-trifluoro-4-iodoaniline, 2.8 g of copper powder, 11.1 g ofiodopentafluoroethane and 40 ml of DMF, and the reaction was carried outwith stirring for 7 hours while maintaining the internal temperature at135° C. After completion of the reaction, the reaction mixture wascooled to room temperature, poured into 200 ml of ice water, andthoroughly stirred. Then, the insoluble materials were removed and thedesired compound was extracted with 200 ml of ethyl acetate. The extractsolution was washed with water, dried over anhydrous sodium sulfate andthen concentrated, after which the residue was purified by a silica gelcolumn chromatography to obtain 3.9 g of the desired compound.

[0232] Physical property: H-NMR (δ, ppm) 4.52(br, 2H), 6.81(d, 1H),7.27(dd, 1H), 7.48(d, 1H), 7.63(br, 1H). Yield: 67%.

Example 12 (12-1). Production of2-methyl-4-(heptafluoropropan-2-yl)-nitrobenzene

[0233]

[0234] In an autoclave were placed 12.0 g (0.0456 mole) of4-iodo-2-methylnitrobenzene, 11.6 g of copper powder, 40 g of2-iodoheptafluoropropane and 200 ml of DMF, and the reaction was carriedout with stirring for 6 hours while maintaining the internal temperatureat 140° C. After completion of the reaction, the reaction mixture wascooled to room temperature, poured into 600 ml of ice water, andthoroughly stirred. Then, the insoluble materials were removed and thedesired compound was extracted with 300 ml of hexane. The extractsolution was washed with water, dried over anhydrous sodium sulfate andthen concentrated, after which the residue was purified by vacuumdistillation to obtain 11.4 g of the desired compound.

[0235] Physical property: b.p. 120-125° C./10 mmHg. Yield: 82%.

(12-2). Production of 2-methyl-4-(heptafluoropropan-2-yl)-aniline(compound No. ST-4)

[0236]

[0237] In 60 ml of ethanol was dissolved 11.4 g (0.0374 mole) of2-methyl-4-(heptafluoropropan-2-yl)-nitrobenzene, and a solution of 29.5g of SnCl₂.2H₂O in 40 ml of hydrochloric acid was added dropwise theretounder ice-cooling over a period of 30 minutes. After completion of thedropwise addition, the reaction was carried out at room temperature for2 hours. After completion of the reaction, the reaction solution waspoured into 200 ml of ice water and neutralized with a 40% aqueoussodium hydroxide solution under ice-cooling. Then, a 40% aqueous sodiumhydroxide solution was further added thereto until a homogeneoussolution was obtained, and the desired compound was extracted with 100ml of ether. The extract solution was washed with water, dried overanhydrous sodium sulfate and then concentrated, after which the residuewas purified by vacuum distillation to obtain 9.8 g of the desiredcompound.

[0238] Physical property: b.p. 100-110° C./10 mmHg. Yield: 95%.

Example 13 Production of3-bromo-N¹-(4-nonafluorobutyl-2-methylphenyl)-N²-isopropyl-phthalic aciddiamide (Compound No. 281)

[0239] In 10 ml of tetrahydrofuran was dissolved 0.54g of6-bromo-N-isopropyl-phthalic acid isoimide, followed by adding thereto0.30 g of 2-methyl-4-nonafluorobutyl-aniline, and the reaction wascarried out with stirring for 1 hour. After completion of the reaction,the solvent was removed from the reaction solution by distillation underreduced pressure, and the resulting residue was washed withether-n-hexane to obtain 1.1 g of the desired compound.

[0240] Physical property: m.p. 190-191° C. Yield 94%.

[0241] Typical preparation examples and test examples of the presentinvention are described below but they should not be construed aslimiting the scope of the invention.

[0242] In the preparation examples, parts are all by weight.

Formulation Example 1

[0243] Each compound listed in Table 1 50 parts Xylene 40 parts Mixtureof polyoxyethylene 10 parts nonylphenyl ether and calciumalkylbenzenesulfonate

[0244] An emulsifiable concentrate was prepared by mixing uniformly theabove ingredients to effect dissolution.

Formulation Example 2

[0245] Each compound listed in Table 1  3 parts Clay powder 82 partsDiatomaceous earth powder 15 parts

[0246] A dust was prepared by mixing uniformly and grinding the aboveingredients.

Formulation Example 3

[0247] Each compound listed in Table 1 5 parts Mixed powder of bentoniteand clay 90 parts  Calcium lignin sulfonate 5 parts

[0248] Granules were prepared by mixing the above ingredients uniformly,and kneading the resulting mixture together with a suitable amount ofwater, followed by granulation and drying.

Formulation Example 4

[0249] Each compound listed in Table 1 20 parts Mixture of kaolin andsynthetic 75 parts high-dispersion silicic acid Mixture ofpolyoxyethylene  5 parts nonylphenyl ether and calciumalkylbenzenesulfonate

[0250] A wettable powder was prepared by mixing uniformly and grindingthe above ingredients.

Test Example 1 Insecticidal Effect on Diamondback Moth (Plutellaxylostella)

[0251] Adult diamondback moths were released and allowed to oviposit ona Chinese cabbage seedling. Two days after the release, the seedlinghaving eggs deposited thereon was immersed for about 30 seconds in aliquid chemical prepared by diluting a preparation containing eachcompound listed in Table 1 as an active ingredient to adjust theconcentration to 500 ppm. After air-drying, it was allowed to stand in aroom thermostated at 25° C. Six days after the immersion, the hatchedinsects were counted. The mortality was calculated according to thefollowing equation and the insecticidal effect was judged according tothe criterion shown below. The test was carried out with triplicategroups of 10 insects. $\begin{matrix}{Corrected} \\{{mortality}\quad (\%)}\end{matrix} = {\frac{\begin{bmatrix}{{Number}\quad {of}} \\{{hatched}\quad {insects}} \\{{in}\quad {untreated}\quad {group}}\end{bmatrix} - \begin{bmatrix}{{Number}\quad {of}} \\{{hatched}\quad {insects}} \\{{in}\quad {treated}\quad {group}}\end{bmatrix}}{\begin{bmatrix}{{Number}\quad {of}} \\{{hatched}\quad {insects}} \\{{in}\quad {untreated}\quad {group}}\end{bmatrix}} \times 100}$

[0252] Criterion: Effect Mortality (%) A 100 B 99-90 C 89-80 D 79-50

[0253] The results obtained are shown in Table 5.

Test Example 2 Insecticidal Effect on Common Cutworm (Spodoptera Litura)

[0254] A piece of cabbage leaf (cultivar; Shikidori) was immersed forabout 30 seconds in a liquid chemical prepared by diluting a preparationcontaining each compound listed in Table 1 as an active ingredient toadjust the concentration to 500 ppm. After air-drying, it was placed ina plastic Petri dish with a diameter of 9 cm and inoculated withsecond-instar larvae of common cutworm, after which the dish was closedand then allowed to stand in a room thermostated at 25° C. Eight daysafter the inoculation, the dead and alive were counted. The mortalitywas calculated according to the following equation and the insecticidaleffect was judged according to the criterion shown in Test Example 1.The test was carried out with triplicate groups of 10 insects.$\begin{matrix}{Corrected} \\{{mortality}\quad (\%)}\end{matrix} = {\frac{\begin{bmatrix}{{Number}\quad {of}} \\{{alive}\quad {larvae}} \\{{in}\quad {untreated}\quad {group}}\end{bmatrix} - \begin{bmatrix}{{Number}\quad {of}} \\{{alive}\quad {larvae}} \\{{in}\quad {treated}\quad {group}}\end{bmatrix}}{\begin{bmatrix}{{Number}\quad {of}} \\{{alive}\quad {larvae}} \\{{in}\quad {untreated}\quad {group}}\end{bmatrix}} \times 100}$

[0255] The results obtained are shown in Table 5.

Test Example 3 Insecticidal Effect on Rice Leafroller (Cnaphalocrocismedinalis)

[0256] The lamina of a rice plant at the 6 to 8 leaf stage was immersedfor about 30 seconds in a liquid chemical prepared by diluting apreparation containing each compound listed in Table 1 as an activeingredient to adjust the concentration to 500 ppm. After air-drying, thelamina was placed in a plastic Petri dish with a diameter of 9 cm whosebottom had been covered with a wetted filter paper. The lamina wasinoculated with third-instar larvae of rice leafroller, after which thedish was allowed to stand in a room thermostated at 25° C. and having ahumidity of 70%. Four days after the inoculation, the dead and alivewere counted and the insecticidal effect was judged according to thecriterion shown in Test Example 1. The test was carried out withtriplicate groups of 10 insects.

[0257] The results obtained are shown in Table 5. TABLE 5 Test ExampleTest Example Test Example No 1 2 3 1 D D A 2 A C 3 C A 4 A D 7 A 8 A A A9 A A 10 A D D 11 A C C 12 A D 13 D D 14 A 15 A A 16 A 17 A D 18 D A 20A 22 A D 23 A D 24 A D 25 A A 26 A D 27 A A C 28 A 29 A B A 30 A A A 31A 32 A 33 A 34 A C 37 A 41 A A 42 A D A 43 B D 44 A 45 A A 46 A B 47 A DA 48 A B A 49 A A A 50 A A A 51 A A 52 A A A 53 A A 55 A B A 56 A A A 58A A A 59 A 60 A A A 61 A B A 62 A A A 63 A B A 64 A B A 65 A A A 66 A AB 67 A A A 68 A 69 A A 70 A A 71 D 73 A 74 A 75 A A 76 C B 77 A C A 78 AA A 79 A A D 81 A 83 A A A 84 A 86 B B 87 A A 88 A 89 A B A 90 A A B 91A A A 92 A 93 A A A 98 A C 99 A A 100 A A A 101 A 102 A D A 103 A C A109 A A C 110 A A 111 A C B 112 A A A 113 A B A 114 A A A 115 A C A 116A D A 117 A A A 118 A A A 119 A A A 120 A D A 121 A A A 122 A A A 123 AA 124 A A A 125 A B A 126 A A A 127 A A A 128 A D A 129 A A A 130 A A A132 A A A 133 A A A 134 A A 135 A A A 136 A A A 137 A A 138 A A A 139 AA A 140 A A A 141 A A A 142 A A B 143 A A A 144 A A A 145 A A A 146 A AA 147 A C 148 A A A 149 A A A 150 A A A 151 A 152 A A A 153 A D 157 A AA 158 A A A 159 A A A 161 A D A 162 A A B 163 A A A 164 A A 165 A B C167 A A A 168 A 169 A D 170 A D B 171 A D 172 A A D 173 A D D 174 A 175A 176 A D A 177 A A A 178 A A 179 A 180 A A A 181 A 183 A B 185 A 186 D187 A D 188 D D 189 A 190 A 191 A A 192 A 193 A D 194 A 195 A 196 A D197 A A A 198 A C A 199 A 200 A A 201 A B A 202 A 203 A 206 A A 207 A208 A 209 A B 210 A D 211 A A 212 A D A 213 A A A 214 A A A 215 A D 216A A 217 A A 218 A C 219 A D A 220 A A 221 A A A 222 A B A 223 A A A 225A B A 226 A A 227 A 228 B A 229 A D A 230 A C A 231 B A 232 A A 233 A234 A A 235 A A 236 A A A 237 A A 238 A A 239 A A A 240 A 241 A B A 242A B A 243 A A B 244 A C 245 A D 246 A B B 248 A C 249 A D A 250 A D 251A A 252 A 253 A A C 254 A A 255 A A 256 A 257 A B 258 A A 259 A D 261 AA D 262 A A D 263 A A 264 — D A 265 A 266 A A A 267 A A A 268 A A A 269A A A 270 A A A 271 A A A 272 A A A 273 A D D 274 A A A 275 A D A 276 AA A 277 A A A 278 A A A 279 A A A 281 A A A 282 A A A 283 A A A 284 A AA 285 A D A 286 A A A 287 A A A 288 A A A 289 A A A 290 A A A 291 A A A292 A A A 293 A A A 294 A A A 295 D 296 A A A 297 A A B 298 A A A 299 AA A 300 A A 301 A A D 302 A D 303 A D 304 A 305 A A A 306 A A A 307 A D308 A 309 A A 310 A 311 A D 312 A A A 313 A A A 314 A A 315 A A 316 A AA 318 A B A 319 A B B 320 A D 321 A A 322 A B 323 A C A 324 A A 325 A AA 326 A A 327 A A 328 A A A 329 A A A 330 A A 332 A A 333 A D 334 A C C335 A B 336 A D 337 A A 338 A B A 339 A B A 340 A A 341 A A 342 A 343 A345 A B A 346 A C A 347 A B C 348 A A 349 A 350 A A A 351 A A A 352 A353 A A A 354 A A A 355 A C A 356 A A A 360 A D A 361 A A A 362 A A A363 A A A 364 A A D 365 A A A 366 A A A 367 A A A 368 A A A 369 A A A370 A A A 371 A A A 372 A A A 373 A A A 374 A A A 375 A A A 376 A A 377A A 378 A D A 379 A A A 380 A A A 381 A A A 382 A B A 383 A A 384 A C385 A B A 386 A A A 387 A A A 388 A A B 389 A A A 390 A A A 391 A A A392 A A A 393 A A A 394 A A A 395 A A A 396 A A A 397 A A A 398 A 399 AA A 400 A D A 402 A 403 A B A 404 A A A 406 A A A 407 A A A 408 A B A409 A A A 410 A A A 411 A A 412 A C 413 A C 414 A A 415 A 416 A A A 417A A A 418 A 419 A A A 420 A D 421 A B A 422 A 424 A A 427 A D 428 A 429A D 430 A D D 431 A A 432 A A 433 A A 434 A 435 A B A 436 A B A 437 A C438 A B A 439 A A A 440 A C B 441 A B 442 A 443 A D 444 A A 445 B A 446A A A 447 A B C 448 A A 449 A 450 A C 451 A A 452 A A A 453 A D A 454 AA A 455 A B A 456 A A 457 A A B 458 A 459 A 460 A B 461 A 462 A 463 A464 A A 465 A 466 A A 467 A A 468 A A B 469 A A D 470 A C C 471 A A A472 A B 473 A A A 474 A B A 475 A D 476 A A A 477 A C 478 A 479 A A 480A B A 488 A A A 489 A A A 490 A A A 491 A A A 492 A A A 493 A A A 494 AA 495 A A A 496 A A A 498 A A A 499 A A A 500 A B A 501 A A A 502 A A A503 A B A 504 A A A 505 A A A 506 A 507 A B A 508 A B A 509 A A A 510 AB A 511 A A A 512 A A A 513 A A A 514 A A A 515 A C 516 A A A 517 A A A518 A B 519 A A A 520 A 521 A A A 522 A D A 523 A A A 524 A A A 526 A A527 A A A 528 A A 529 A D A 530 A D 531 A A 532 A A 533 A A A 534 A A535 A A 536 A 537 A 538 A A A 539 A 540 A 543 A A 544 A A 545 A A 546 AA 547 A A D 548 A A A 549 A A D 550 A C A 551 A A 552 A B 553 A C A 554A A 555 A B 557 A C B 558 A A A 559 A 560 A 561 A C A 562 A A 563 A A564 A B 565 A A 566 A B 567 A D D 568 A C A 569 A A A 570 A A 571 A C573 A 575 A A 576 A C 577 A A 579 A A A 580 A A 581 A B A 582 A A 584 AD 585 A A 586 A D 587 A 588 A 589 A A 590 A 591 A D 592 A 593 A 594 A595 A A A 596 D D 597 B 598 A 599 A D A 600 A 601 A 602 A A 603 B C 604A D 605 C 606 A D A 607 A A A 608 A 609 A B A 610 A A C 611 A A 612 A D613 A 614 A 615 A 616 A D 617 A A A 618 A A A 619 A A A 621 A 622 A 623A A 624 A 625 A D D 626 A 628 A B A 633 A D 634 A D 635 A D 636 A D A637 A 638 B 639 A 640 A 641 D D 642 A 643 A A 644 A A 645 A 646 A D 647A B 648 A D A 649 A C 650 A 652 A 653 A 654 D 656 A A 657 D 658 A 659 A660 A A 661 B D 662 A 663 A A D 664 A A 665 A A B 666 A D 667 A A A 668A 669 A D A 670 A D 671 A D 672 A 673 A D D 674 A D A 675 A A A 676 A CA 677 A 678 A 679 A A 680 A D 681 A A A 682 A A 683 A A A 684 A A A 686A A A 687 A D D 688 A A 689 A D A 690 A A 691 A D C 692 A D 693 A A 694A A 695 A A A 696 A A A 697 A A 698 A B A 699 A A D 700 A A A 701 A A A703 A A A 704 A A 705 A D A 706 A A 708 D 709 A A 710 A C A 711 A C A712 A A A 713 A B D 714 A A A 715 A A A 716 A A A 717 A A 718 A A 719 AD 720 A 721 A 722 A A 723 D D 724 A B 725 A A 727 A B A 728 A A 729 A A732 A 733 A 735 D 737 A 738 D 740 A A 741 A A A 742 A 743 D 744 C 745 D749 A 750 A A 751 A A 752 A 753 A A D 755 A A 758 A 759 D 765 A 766 A767 A C A 768 A B A 769 A D 770 A A A 771 A C 772 A A 773 A A 774 A A776 B D 777 A D 778 A A 780 A A A 781 A A A 782 A A 783 A A A 785 A 788C C 790 A 791 A A 793 A 795 A B A 796 A 797 A C 798 A 799 A A 800 C 801A A D 802 D 803 A A 808 A 819 A B A 821 A A 822 D D 824 A 825 A 826 A A827 A 830 C 831 D D 832 A 833 A D 835 A 836 A A 837 A 838 A C A 839 A C840 A D 841 A D 842 A A D 845 A 846 A 847 D 848 A 849 A B A 850 A A 851A D A 852 A D 854 A 855 A 856 A D 858 C A 859 D 860 A 861 A 862 A D D863 A B 864 A 865 A 866 D 867 A C 869 A D 870 A 871 A 872 A C 874 A C A875 A 878 C 879 A A 880 D 881 A D 888 D 889 A A 890 A A A 891 A A A 892A A 893 A A A 894 A A A 895 A A A 901 A D A 902 A 903 A A A 904 A 905 AA A 906 A D A 907 A A A 908 A D A 909 A A A 910 A 911 A D 912 A 913 A914 A 915 A A A 916 A 917 A A A 918 A 919 A 920 A 924 A 925 A A 927 A AA 928 A A 929 A A A 930 A A A 931 A A A 932 A A A 933 A A 934 A A A 935A A A 936 A A A 937 A A A 938 A A 939 A A A 940 A A A 941 A A A 942 A AA 943 A C A 944 A A A 945 A A A 946 A A 947 A A A 949 A A A 950 C 951 AA A 952 A A 953 A A A 954 A A 955 A A A 956 A A 957 A A A 958 A A 959 AA 965 A C 966 A B 971 A A A 972 A 973 A A A 974 A A A 975 A A 976 A A A977 A A A 978 A C A 979 A A A 980 A A A 981 A A A 982 A C 983 A A A 984A 985 A A A 986 A A 987 A A A 988 A 989 A A A 990 A A 991 A A A 992 A993 A A 995 A A 996 A A A 997 A A A 998 A A A 999 A A 1000 A D A 1001 AA A 1002 A A A 1003 A A A 1004 A A A 1005 A A A 1006 A 1007 A A A 1008 AA 1009 A A A 1010 A A 1011 A A A 1013 A A A 1014 A A 1015 A D A 1016 A1017 A A A 1018 A D A 1019 A A A 1020 A A A 1021 A A 1022 A A A 1023 A AA 1024 A A A 1025 A 1026 A A 1027 A 1028 A A A 1031 A A A 1032 A A 1033A A A 1034 A 1035 A A A 1036 A A 1037 A A A 1038 A A A 1039 A A A 1040 AA A 1041 A A A 1042 A A A 1043 A A 1044 A A A 1045 A A A 1046 A A A 1047A A 1048 A A 1049 A A A 1050 A A A 1051 A A A 1052 A A 1053 A A A 1054 AA A 1055 A A A 1056 A A A 1057 A A 1058 A A A 1059 A 1060 A A A 1061 A AA 1062 A A A 1063 A 1064 A A 1065 A 1066 A C A 1067 A A A 1068 A A A1069 A A A 1070 A A A 1071 A C A 1072 A 1073 A A A 1074 A A A 1075 A A A1076 A A 1077 A A 1078 A A A 1079 A A A 1080 A A A 1081 A A A 1082 A1083 A 1086 A A 1087 A A A 1088 A A 1089 A A 1099 A A 1100 A C A 1101 AC A 1102 A A A 1103 A A 1104 A A A 1105 A A A 1106 A A 1107 A A 1108 A A1109 A A 1110 A C A 1111 A A 1112 A A A 1113 A A A 1114 A A A 1115 A A A1116 A A A 1117 A A A 1118 A A A 1119 A A A 1120 A A A 1121 A A A 1122 AA A 1123 A A A 1124 A A A 1125 A A A 1126 A A A 1127 A A A 1128 A A A1129 A A A 1130 A A A 1131 A A A 1132 A A 1133 A A 1134 A A 1135 A A1136 A A 1137 A 1138 A 1139 A 1140 A 1141 A A A 1142 A A A 1143 A C A1144 A A A 1145 A A 1146 A C A 1147 A A A 1148 A A A 1149 A A 1150 A A A1151 A A A 1152 A A A 1153 A A A 1154 A C A 1155 A A 1156 A A A 1157 A A1158 A D A 1159 A A A 1160 A A A 1161 A D A 1162 A A A 1163 A A A 1164 AA A 1165 A A A 1166 A A A 1167 A A A 1168 A A A 1169 A A A 1173 A A A1174 A A A 1175 A 1178 A 1179 A A — 1180 A — 1181 A — 1182 A — 1183 A A— 1184 A A — 1185 A C — 1186 A A — 1187 A A — 1188 A A — 1189 A A — 1190A A A 1191 A A A 1192 A A A 1193 A A A 1202 A A A 1203 A D A 1204 A A A1205 A A 1206 A A A 1207 A A A 1208 A A 1209 A D A 1210 A A A 1211 A A A1212 A A A 1221 A A A 1222 A A A 1223 A A A 1224 B 1225 A 1226 A 1227 AA A 1228 A A A 1229 A A A 1230 A A A 1231 A A A 1232 A A A 1233 A A —1234 A A — 1235 A D — 1236 A A — 1237 A A — 1238 A — 1245 A A — 1246 A AA 1247 C 1248 A A A 1249 A 1250 A A A 1251 A A A 1256 A A — 1257 A A —1258 A A — 1259 A — 1260 A — 1261 A A — 1262 A A A 1263 A A A 1264 A A A1266 A A 1277 A A A 1278 A A A 1280 A A A 1281 A A 1283 A — — 1284 A — A1285 A — A 1287 A A A 1288 A 1291 A 1293 A 1294 A A A 1295 A A A 1296 AA A 1297 A A A 1298 A A A 1299 A A A 1300 A A A 1301 A A 1303 A A A 1304A A 1305 A A A 1306 A 1307 A A A 1308 C 1309 A A A 1310 B 1311 A A A1312 A A 1313 A A A 1314 A A A 1315 A A A 1316 A A A 1317 A C A 1318 A A1319 A — — 1321 A — A 1322 A 1323 A A 1325 A A 1327 A 1328 A 1330 A A A1331 A A 1332 A 1333 A A 1335 A C A 1337 A A 1338 A 1339 A A 1340 A A1341 A 1342 A 1343 A A 1345 A 1346 A 1347 A 1348 A 1349 A 1350 A 1351 AA 1352 A A 1353 A A A 1355 A A A 1356 A 1358 A C 1360 A C 1361 A 1362 AA A 1363 A 1364 A A A 1365 A 1366 A A A 1367 A 1368 A 1370 A A 1372 A1373 A 1374 A 1376 A 1379 A 1381 A C 1382 A A A 1383 A A A 1384 A A A1385 A A A 1386 A A A 1387 A A A 1388 A D A 1389 A A A 1390 A A 1392 A A1393 A A 1394 A A 1395 A 1398 A 1399 A A A 1400 A A A 1401 A 1402 A A A1404 A C A 1406 A A A 1409 A A 1410 A A 1411 A A 1412 A 1414 A A A 1415A A 1416 A 1417 A A A 1418 A A A 1419 A A 1420 A A 1421 A 1423 A 1424 AA 1427 A A A 1428 A A A 1429 A A A 1430 A D A 1431 A 1432 A 1434 A 1436A A A 1438 A A A 1439 A C 1440 A 1441 A A 1442 A 1443 A 1445 A A A 1446A 1447 A A A 1448 A A A 1449 A A A 1450 A A A 1451 A 1452 A A A 1453 A1454 A A A 1456 A A 1457 A A 1458 A A A 1459 A A 1460 A C A 1461 A A1464 A A A 1465 A A 1466 A A A 1467 A A A 1468 A C A 1469 A 1470 A A1472 A A A 1473 A A A 1474 A A A 1475 A A A 1476 A 1478 A A A 1479 A A A1480 A 1481 A A A 1482 A A A 1484 A A A 1485 A A A 1486 A A 1487 A A1488 A A 1489 A A A 1490 A A 1491 A A A 1492 A A 1493 A A 1494 A A A1495 A A A 1496 A A A 1497 A A A 1498 A A A 1499 A A A 1500 A A A 1501 AA A 1502 A A A 1503 A C A 1504 A A A 1505 A A A 1506 A A A 1507 A A A1508 A C A 1509 A C A 1510 A A 1511 A 1512 A A A 1513 A 1514 A A 1515 A1516 A A A 1517 A A 1518 A 1519 A A 1520 A 1521 A 1522 A A A 1523 A A1524 A A A 1525 A A A 1526 A A A 1527 A A 1528 A A 1529 A A 1530 A A1531 A A A 1532 A A A 1533 A A A 1534 A A A 1535 A A A 1536 A A A 1537 AA A 1538 A A A 1539 A A A 1540 A A A 1541 A A A 1542 A D A 1543 A A A1544 A A A 1545 A D A 1546 A C A 1547 A A 1548 A A 1549 A D A 1550 A A A1551 A D A 1552 A A A 1553 A A 1554 A A 1555 A A 1556 A A A 1557 A A A1558 A C A 1559 A A A 1560 A A A 1561 A A A 1562 A A A 1563 A A A 1565 AA A 1566 A A A 1567 A A A 1568 A A A 1569 A A A 1570 A 1571 A A A 1572 AA A 1573 A A A 1574 A A A 1575 A A 1576 A D A 1577 A 1578 A A 1579 A1580 A A A 1581 A A A 1582 A A 1583 A A 1584 A A 1585 A A A 1586 A C A1587 A A A 1588 A A 1589 A A 1590 A A A 1594 A A — 1595 A A — 1596 A A —1597 A A — 1598 A A — 1599 A A — 1600 A A — 1601 A A — 1602 A A A 1603 AA A 1604 A A A 1605 A C — 1606 A A — 1607 A A — 1608 A A — 1609 A A —1610 A A — 1611 A — 1612 A A — 1613 A A — 1614 A C A 1615 A A A 1617 A A1618 A C A 1619 A A — 1620 A A 1622 A A A 1623 A C A 1624 A D A 1625 A AA 1626 A A 1627 A A A 1628 A A A 1629 A A A 1632 A A 1633 A A A 1634 A AA 1635 A A A 1636 A D A 1637 A A A 1638 A A A 1639 A A A 1640 A A A 1641A A 1642 A A A 1643 A A 1644 A A A 1645 A A A 1646 A A A 1647 A A A 1648A A A 1649 A A A 1650 A A A 1651 A A A 1652 A A A 1653 A A A 1654 A A A1655 A A A 1656 A A A 1658 A 1659 A A 1660 A A — 1661 A — 1662 A A —1663 A A — 1664 A A — 1665 A A — 1666 A A — 1667 A A — 1668 A A — 1669 AA — 1670 A A — 1671 A A — 1672 A A — 1673 A — 1674 A A — 1679 A A A 1680A A A 1681 A A A 1682 A A — 1683 A — 1684 A A — 1685 A A — 1686 A A —1689 A A — 1690 A A — 1691 A A — 1692 A — 1693 A A — 1694 A — 1695 A A —1696 A A — 1697 A A — 1698 A — 1699 A A — 1700 A D — 1714 A A A 1715 A AA 1716 A A A 1717 A A A 1722 A A A 1723 A A A 1726 A A 1727 A A 1732 A AA 1733 A A A 1737 A C A 1742 A A 1743 A A 1747 A C A 1748 A A 1750 A A1752 A A 1763 A A 1764 A A A 1765 A A A 1766 A A A 1767 A 1768 A A 1770A — A 1772 A — A 1773 A A A 1774 A — A 1775 A — A 1776 A — A 1777 A A A1778 A — A 1799 A A A 1800 A A A 1801 A A A 1802 A 1803 A A A 1804 A1805 A

What is claimed is:
 1. A phthalic acid diamide derivative represented bythe general formula (I),

wherein R¹, R² and R³ may be the same or different, and are each ahydrogen atom, a cyano group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₃-C₆ cycloalkenyl group, a halo-C₃-C₆ cycloalkenylgroup or a group of the formula -A¹-Q_(l), (wherein A¹ is —O—, —S—,—SO₂—, —C(═O)—, a group of the formula —N(R⁴)— (wherein R⁴ is a C₁-C₆alkyl-carbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, or a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different, and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different), a C₁-C₈ alkylene group, a C₃-C₆ alkenylene groupor a C₃-C₆ alkynylene group; (1) when A¹ is —O— or a group of theformula —N(R⁴)— (wherein R⁴ is the same as defined above), then Q is ahydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆alkenyl group, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkyl sulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aphenyl-C₁-C₄ alkyl group or a substituted phenyl-C₁-C₄ alkyl grouphaving at least one substituent, in the phenyl ring, which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different; (2) when A¹ is —S—, —SO₂— or —C(═O)—, then Q is aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a C₁-C₆ alkoxy group, amono-C₁-C₆ alkylamino group, a di-C₁-C₆ alkylamino group which may bethe same or different, a C₁-C₆ alkoxycarbonylamino group, a C₁-C₆alkoxycarbonyl-C₁-C₆ alkylamino group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkyl-sulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenylamino group, a substituted phenylaminogroup having at least one substituent, in the phenyl ring, which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydro-furylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or a pyrazolyl group), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, (3) when A¹ is a C₁-C₈ alkylene group, a C₃-C₆alkenylene group or a C₃-C₆ alkynylene group, then Q is a hydrogen atom,a halogen atom, a cyano group, a nitro group, a halo-C₁-C₆ alkyl group,a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkoxycarbonyl group, a di-C₁-C₆ alkoxyphosphoryl group which may be thesame or different, a di-C₁-C₆ alkoxythiophosphoryl group which may bethe same or different, a diphenylphosphino group, a diphenyl-phosphonogroup, a phenyl group, a substituted phenyl group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), a substitutedhetero-cyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -Z³-R⁵ (wherein Z³ is—O—, —S—, —SO—,—SO₂— or a group of the formula —N(R⁶)— (wherein R⁶ is ahydrogen atom, a C₁-C₆ alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonylgroup, a C₁-C₆ alkoxycarbonyl group, a phenylcarbonyl group, asubstituted phenylcarbonyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkyl-sulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenyl C₁-C₄ alkoxycarbonyl group, or asubstituted phenyl C₁-C₄ alkoxycarbonyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkyl-thio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkyl-sulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different); and R⁵ is a hydrogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenylgroup, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynyl group, a C₃-C₆cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkylcarbonylgroup, a halo C₁-C₆ alkylcarbonyl group, a C₁-C₆ alkoxycarbonyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a phenylC₁-C₄ alkyl group, a substituted phenyl C₁-C₄ alkyl group having atleast one substituent, in the phenyl ring, which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkyl-thio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkyl-sulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and a di-C₁-C₆alkylamino group which may be the same or different, a naphthyl group, asubstituted naphthyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a heterocyclic group (which is the same asdefined above), or a substituted heterocyclic group (wherein theheterocyclic group is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different); l is aninteger of 1 to 4); further, R¹ and R² may form a 4 to 7 membered ringby combining to each other, in which the ring may contain the same ordifferent 1 to 3 hetero atoms selected from the group consisting ofoxygen atom, sulfur atom and nitrogen atom; X may be the same ordifferent, and is a hydrogen atom, a halogen atom, a cyano group, anitro group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, aphenyl group, a substituted phenyl group having at least onesubstituents which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkyl-thio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkyl-sulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined the above), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkyl-sulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A²-R⁷ (wherein A² is—O—, —S—, —SO—, —SO₂—, —C(═O)—, —C(═NOR⁸)— (wherein R⁸ is a hydrogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenylgroup, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a C₃-C₆cycloalkyl group, a phenyl-C_(l)-C₄ alkyl group, or a substitutedphenyl-C₁-C₄ alkyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different), a C₁-C₆alkylene group, a halo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, ahalo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆alkynylene group; (1) when A² is —O—, —S—, —SO— or —SO₂—, then R⁷ is ahydrogen atom, a C₁-C₆ alkyl group, a halo C₁-C₆ alkyl group, a C₃-C₆alkenyl group, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, ahalo-C₃-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₃-C₁cycloalkenyl group, a halo-C₃-C₆ cycloalkenylgroup, a di-C₁-C₆ alkoxy-phosphoryl group which may be the same ordifferent, a di-C₁-C₆ alkoxythiophosphoryl group which may be the sameor different, a phenyl group, a substituted phenyl group having at leastone substituent which may be the same or different and is selected fromthe group consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), a substitutedhetero-cyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituents which may be the same ordifferent and are selected from the group consisting of a halogen atom,a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A³-R⁹ (wherein A³ is—C(═O)—, —SO₂—, a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₃-C₆alkynylene group, or a halo-C₃-C₆ alkynylene group, (i) when A³ is—C(═O)— or —SO₂—, then R⁹ is a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a mono-C₁-C₆ alkylamino group, a di-C₁-C₆alkylamino group which may be the same or different, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),or a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined the above) having at least one substituent which maybe the same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkyl-thio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkyl-sulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and a di-C₁-C₆alkylamino group which may be the same or different, (ii) when A³ is aC₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, a C₂-C₆ alkenylenegroup, a halo-C₂-C₆ alkenylene group, a C₃-C₆ alkynylene group or ahalo-C₃-C₆ alkynylene group, then R⁹ is a hydrogen atom, a halogen atom,a cyano group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group,a C₁-C₆ alkoxycarbonyl group, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, or a group of the formula -A⁴-R¹⁰ (wherein A⁴ is —O—, —S—,—SO—, —SO₂—, —C(═O)—, or a group of the formula —N(R¹¹)— (wherein R¹¹ isa hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆alkenyl group, a C₃-C₆ alkynyl group, a C₃-C₆ cyclo-alkyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different); and R¹⁰ is a hydrogen atom, a C₁-C₆ alkyl group,a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenylgroup, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynyl group, a C₃-C₆cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₃-C₆ cycloalkenylgroup, a halo-C₃-C₆ cycloalkenyl group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined theabove), or a substituted heterocyclic group (wherein the heterocyclicgroup is the same as defined the above) having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different)); (2) whenA² is —C(═O)— or a group of the formula —C(═NOR⁸)— (wherein R⁸ is thesame as defined above), then R⁷ is a C₁-C₆ alkyl group, a halo C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₃-C₆cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxy group, aC₁-C₆ alkyl-thio group, a mono-C₁-C₆ alkylamino group, a di-C₁-C₆alkylamino group which may be the same or different, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenylamino group, a substituted phenylaminogroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, a cyanogroup, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group,a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkyl-thio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkyl-sulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a naphthyl group, a substituted naphthyl group having oneor more substituents which may be the same or different and are selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆. alkoxy group, a halo-C₁-C₆ alkoxy group, aC₁-C₆. alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),or a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined above) having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkyl-sulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, (3) when A² is a C₁-C₆ alkylene group, ahalo-C₁-C₆ alkylene group, C₂-C₆ alkenylene group, a halo-C₂-C₆alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆ alkynylenegroup, then R⁷ is a hydrogen atom, a halogen atom, a C₃-C₆ cyclo-alkylgroup, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), a substitutedhetero-cyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A⁵-R² (wherein A⁵ is—O—, —S—, —SO—, —SO₂— or a group of the formula —N(R¹³)— (wherein R¹³ isa hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a C₂-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆.alkylsulfonyl group, a halo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),or a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined above) having at least one substituents which may bethe same or different and are selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkyl-thio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkyl-sulfinyl sulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and a di-C₁-C₆alkylamino group which may be the same or different); and R¹² is ahydrogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group,a phenyl group, a substituted phenyl group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a C₁-C₆ alkylamino group and a di-C₁-C₆alkylamino group which may be the same or different, a naphthyl group, asubstituted naphthyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a heterocyclic group (which is the same asdefined above), a substituted heterocyclic group (wherein theheterocyclic group is the same as defined above) having at least onesubstituents which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, or a groupof the formula -A⁶-R¹⁴ (wherein A⁶ is —C(═O)—, —SO₂—, a C₁-C₆ alkylenegroup, a halo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, ahalo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆alkynylene group; (i) when A⁶ is —C(═O)— or —SO₂—, then R¹⁴ is a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),or a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined the above) having at least one substituent which maybe the same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different; (ii) when A⁶ is a C₁-C₆ alkylene group, ahalo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, a halo-C₂-C₆alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆ alkynylenegroup, then R¹⁴ is a hydrogen atom, a halogen atom, a cyano group, aC₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, aC₁-C₆ alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and areselected from the group consisting of a halogen atom, a cyano group, anitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a phenoxy group, a substituted phenoxy group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aphenylthio group, a substituted phenylthio group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆- alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different))); n is an integer of 1 to 4; further, X may forma condensed ring (which means naphthalene, tetrahydronaphthalene,indene, indane, quinoline, quinazoline, chroman, isochroman, indole,indoline, benzodioxane, benzodioxole, benzofuran, dihydrobenzofuran,benzothiophene, dihydrobenzothiophene, benzoxazole, benzothiazole,benzimidazole or indazole), by combining together with the adjacentcarbon atoms in the phenyl ring, and said condensed ring may have atleast one substituents, which may be the same or different, and selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group, adi-C₁-C₆ alkylamino group which may be the same or different, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),and a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined above) having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different; Y is the same or different, and is a hydrogenatom, a halogen atom, a cyano group, a nitro group, a C₃-C₆ cycloalkylgroup, a halo-C₃-C₆ cycloalkyl group, a di-C₁-C₆ alkoxyphosphoryl groupwhich may be the same or different, a di-C₁-C₆ alkoxythiophosphorylgroup which may be the same or different, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined theabove), a substituted heterocyclic group (wherein the heterocyclic groupis the same as defined above) having at least one substituent which maybe the same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A²-R⁷ (wherein A² andR⁷ are the same as defined above); m is an integer of 1 to 5; further, Ymay form a condensed ring (the condensed ring is the same as definedabove), by combining together with the adjacent carbon atoms in thephenyl ring, said condensed ring may have at least one substituents,which may be the same or different, and selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group, adi-C₁-C₆ alkylamino group which may be the same or different, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),and a substituted heterocyclic group (wherein said heterocyclic group isthe same as defined above) having at lease one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different; Z¹ and Z² are each represents an oxygen atom or asulfur atom; provided that, (1) when X, R¹ and R³ are hydrogen atoms atthe same time; m is an integer of 2; Y at 2-position is a fluorine atomand Y at 3-position is a chlorine atom; then R² is not ethyl group,isopropyl group, cyclohexyl group, 2-propenyl group, methylthiopropylgroup and a-methylbenzyl group, p2 (2) when X and R³ are hydrogen atomsat the same time; m is an integer of 2; Y at 2-position is a fluorineatom and Y at 3-position is a chlorine atom; then the 4 to 7 memberedring by combining R¹ and R to each other, in which the ring may containthe same or different 1 to 3 hetero atoms selected from the groupconsisting of oxygen atom, sulfur atom and nitrogen atom is notmorpholino group, (3) when X, R¹ and R³ are hydrogen atoms at the sametime; and R² is 1,2,2-trimethylpropyl group; then Y is not a hydrogenatom, (4) when X, R¹ and R³ are hydrogen atoms at the same time; R² is2,2-dimethylpropyl group; and m is an integer of 1; then Y is not2-ethoxy group, and (5) when X, R¹ and R³ are hydrogen atoms at the sametime; and R² is tert-butyl group group; and m is an integer of 1; then Yis not 4-chlorine atom, 2-nitro group, 4-nitro group, 3-methoxy group,4-methoxy group and 2,6-dimethyl groups.
 2. The phthalic acid diamidederivative according to claim 1, wherein R¹, R² and R³ may be the sameor different, and are each a hydrogen atom, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, or a group of the formula -A¹-Q_(l),(wherein A¹ is a C₁-C₈ alkylene group, a C₃-C₆ alkenylene group or aC₃-C₆ alkynylene group; and Q is a hydrogen atom, a halogen atom, acyano group, a nitro group, a halo-C₁-C₆ alkyl group, a C₃-C₆ cycloalkylgroup, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, adi-C₁-C₆ alkoxyphosphoryl group which may be the same or different, adi-C₁-C₆ alkoxythiophosphoryl group which may be the same or different,a diphenylphosphino group, a diphenylphosphono group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydrofurylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or pyrazolyl group), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,or a group of the formula -Z³-R⁵ (wherein Z³ is —O—,—S—, —SO—, —SO₂— ora group of the formula —N(R⁶)— (wherein R⁶ is a hydrogen atom, a C₁-C₆alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,a phenyl C₁-C₄ alkoxycarbonyl group, or a substituted phenyl C₁-C₄alkoxycarbonyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group); and R⁵ is a hydrogen atom, a C₁-C₆alkyl group, a halo C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkylcarbonyl group, a halo C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenyl C₁-C₄alkyl group, a substituted phenyl C₁-C₄ alkyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), or a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group); and lis an integer of 1 to 4); R¹ and R² may form a 4 to 7 membered ring bycombining to each other, in which the ring may contain the same ordifferent 1 to 3 hetero atoms selected from the group consisting ofoxygen atom, sulfur atom and nitrogen atom; X may be the same ordifferent, and is a hydrogen atom, a halogen atom, a cyano group, anitro group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, aphenyl group, a substituted phenyl group having at least onesubstituents which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), a substituted heterocyclic group (whereinthe heterocyclic group is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group,and a halo-C₁-C₆ alkylsulfonyl group, or a group of the formula -A²-R⁷(wherein A² is —O—, —S—, —SO—, —SO₂—, —C(═O)—, —C(═NOR⁸)— (wherein R⁸ isa hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆alkenyl group, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, aC₃-C₆ cycloalkyl group, a phenyl-C₁-C₄ alkyl group, or a substitutedphenyl-C₁-C₄ alkyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group), a C₁-C₆ alkylene group, a halo-C₁-C₆alkylene group, a C₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group,a C₂-C₆ alkynylene group or a halo-C₃-C₆ alkynylene group; (1) when A²is —O—, —S—, —SO— or —SO₂—, then R⁷ is a halo-C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkenyl group, a phenyl group, a substituted phenylgroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, aheterocyclic group (which is the same as defined above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or agroup of the formula -A³-R⁹ (wherein A³ is a C₁-C₆ alkylene group, ahalo-C₁-C₆ alkylene group, a C₃-C₆ alkenylene group, a halo-C₃-C₆alkenylene group, a C₃-C₆ alkynylene group or a halo-C₃-C₆ alkynylenegroup; R⁹ is a hydrogen atom, a halogen atom, a C₃-C₆ cycloalkyl group,a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, or a group of the formula -A⁴-R¹⁰ (wherein A⁴ is—O—, —S—, —SO—, —SO₂— or —C(═O)—, and R¹⁰ is a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), or a substituted heterocyclic group (wherein theheterocyclic group is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group)); (2) when A² is —C(═O)— or a group ofthe formula —C(═NOR⁸)— (wherein R⁸ is the same as defined the above),then R⁷ is a C₁-C₆ alkyl group, a halo C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxy group, a C₁-C₆ alkylthiogroup, a mono-C₁-C₆ alkylamino group, a di-C₁-C₆ alkylamino group whichmay be the same or different, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenylaminogroup, a substituted phenylamino group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group,and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), or a substituted heterocyclic group (whereinthe heterocyclic group is the same as defined the above) having at leastone substituent which may be the same or different and is selected fromthe group consisting of a halogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group,a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, (3) when A² isa C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, C₂-C₆ alkenylenegroup, a halo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or ahalo-C₃-C₆ alkynylene group, then R⁷ is a hydrogen atom, a halogen atom,a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkoxy-carbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined the above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or agroup of the formula -A⁵-R¹² (wherein A⁵ is —O—,—S—, —SO— or —SO₂—; andR¹² is a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), a substituted heterocyclic group (wherein the heterocyclicgroup is the same as defined above) having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group, or a group of the formula -A⁶-R¹⁴(wherein A⁶ is a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂- C₆ alkenylene group, a C₂-C₆alkynylene group, or a halo-C₃-C₆ alkynylene group; and R¹⁴ is ahydrogen atom, a halogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, aC₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a phenoxy group, a substituted phenoxy group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenylthiogroup, a substituted phenylthio group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆-alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), or a substituted heterocyclic group (whereinthe heterocyclic ring is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group))); n is an integer of 1 to 4; further,X may form a condensed ring (which means naphthalene,tetrahydronaphthalene, indene, indane, quinoline, quinazoline, chroman,isochroman, indole, indoline, benzodioxane, benzodioxole, benzofuran,dihydrobenzofuran, benzothiophene, dihydrobenzothiophene, benzoxazole,benzothiazole, benzimidazole or indazole), by combining together withthe adjacent carbon atoms in the phenyl ring, said condensed ring mayhave at least one substituent, which may be the same or different, andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedabove), and a substituted heterocyclic group (wherein the heterocyclicgroup is the same as defined above) having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group; Y is the same or different, and is ahydrogen atom, a halogen atom, a cyano group, a nitro group, ahalo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), a substituted heterocyclicgroup (wherein the heterocyclic group is the same as defined above)having at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or a group ofthe formula -A²-R⁷ (wherein A² and R⁷ are the same as defined above); mis an integer of 1 to 5; further, Y may form a condensed ring (the sameas defined above), by combining together with the adjacent carbon atomsin the phenyl ring, said condensed ring may have at least onesubstituent, which may be the same or different, and is selected fromthe group consisting of a halogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group,a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), and a substituted heterocyclic group (wherein saidheterocyclic group is the same as defined the above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group; and Z¹ and Z² are each represents anoxygen atom or a sulfur atom.
 3. The phthalic acid diamide derivativeaccording to claim 2, represented by the general formula (I-1),

{wherein, R¹, R² and R³ may be the same or different, and are each ahydrogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl groupor a group of the formula -A¹-Q_(l) (wherein, A¹ is a C₁-C₈ alkylenegroup, a C₃-C₆ alkenylene group or a C₃-C₆ alkynylene group; Q is ahydrogen atom, a halogen atom, a cyano group, a nitro group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a di-C₁-C₆alkoxyphosphoryl group which may be the same or different, a di-C₁-C₆alkoxythiophosphoryl group which may be the same or different, adiphenylphosphino group, a diphenylphosphono group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydrofurylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or pyrazolyl group), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,or a group of the formula -Z³-R⁵ (wherein Z³ is —O—, —S—, —SO—, —SO₂— ora group of the formula —N(R⁶)— (wherein R⁶ is a hydrogen atom, a C₁-C₆alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,a phenyl C₁-C₄ alkoxycarbonyl group, or a substituted phenyl C₁-C₄alkoxycarbonyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group); and R⁵ is a hydrogen atom, a C₁-C₆alkyl group, a halo C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkylcarbonyl group, a halo C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenyl C₁-C₄alkyl group, a substituted phenyl C₁-C₄ alkyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), or a substitutedheterocyclic group (wherein the heterocyclic ring is the same as definedabove) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group); and lis an integer of 1 to 4); further, R¹ and R² may form a 4 to 7 memberedring by combining to each other, in which the ring may contain the sameor different 1 to 3 hetero atoms selected from the group consisting ofoxygen atom, sulfur atom and nitrogen atom; X is a hydrogen atom or anitro group; Y¹ and Y³ may be the same or different and are each ahydrogen atom, a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a phenoxy group, asubstituted phenoxy group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a pyridyloxy group, a substituted pyridyloxy grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group; Y²is a halo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenylgroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, ahalo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedabove), a substituted heterocyclic group (wherein the heterocyclic groupis the same as defined above) having at least one substituent which maybe the same or different and is selected from the group consisting of ahalogen atom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and ahalo-C₁-C₆ alkylsulfonyl group, or a group of the formula -A²-R⁷(wherein A² is —O—, —S—, —SO—, SO₂—, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group or a halo-C₃-C₆ alkynylene group and, (1) when A² is—O—, —S—, —SO— or —SO₂—, then R⁷ is a halo-C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkenyl group, a substituted phenyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), a substituted heterocyclicgroup (wherein the heterocyclic ring is the same as defined above)having at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, ora group of the formula -A³-R⁹ (wherein A³ is a halo-C₁-C₆ alkylenegroup, a halo-C₃-C₆ alkenylene group, a C₃-C₆ alkynylene group or ahalo-C₃-C₆ alkynylene group; and R⁹ is a hydrogen atom, a halogen atom,a phenyl group, a substituted phenyl group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group or a group ofthe formula -A⁴-R¹⁰ (wherein A⁴ is —O—,—S— or —SO₂—; and R¹⁰ is a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a phenyl group, a substituted phenyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), a substituted heterocyclicgroup (wherein the heterocyclic ring is the same as defined above)having at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group));(2) when A² is a halo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, ahalo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆alkynylene group, then R⁷ is a hydrogen atom, a halogen atom, ahalo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, ora group of the formula -A⁵-R¹² (wherein A⁵ is —O—, —S—, —SO— or —SO₂—;and R¹² is a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylsulfinylgroup and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (whichis the same as defined the above), a substituted heterocyclic group(wherein the heterocyclic group is the same as defined above) having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group; or a group ofthe formula -A⁶-R¹⁴ (wherein A⁶ is a C₁-C₆ alkylene group, a halo-C₁-C₆alkylene group, a C₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group,a C₂-C₆ alkynylene group or a halo-C₃-C₆ alkynylene group; and R¹⁴ is ahydrogen atom, a halogen atom, a halo-C₃-C₆ cycloalkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and ahalo-C₁-C₆ alkylsulfonyl group, a phenoxy group, a substituted phenoxygroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, ahalo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, a phenylthio group, a substituted phenylthio grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆-alkylsulfonyl group, aheterocyclic group (which is the same as defined the above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group))); further, Y¹ and Y² may form a condensed ring(which means naphthalene, tetrahydronaphthalene, indene, indane,quinoline, quinazoline, chroman, isochroman, indole, indoline,benzodioxane, benzodioxole, benzofuran, dihydrobenzofuran,benzothiophene, dihydrobenzothiophene, benzoxazole, benzothiazole,benzimidazole or indazole) by combining to each other together with theadjacent Y^(3,) said condensed ring may have at least one substituent,which is the same or different, selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined the above), and a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; and Z¹and Z² are each an oxygen atom or a sulfur atom).
 4. The phthalic aciddiamide derivative according to claim 2, represented by the generalformula (I-2),

{wherein, R¹, R² and R³ may be the same or different, and are each ahydrogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl groupor a group of the formula -A¹-Q_(l) (wherein, A¹ is a C₁-C₈ alkylenegroup, a C₃-C₆ alkenylene group or a C₃-C₆ alkynylene group; Q is ahydrogen atom, a halogen atom, a cyano group, a nitro group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a di-C₁-C₆alkoxyphosphoryl group which may be the same or different, a di-C₁-C₆alkoxythiophosphoryl group which may be the same or different, adiphenylphosphino group, a diphenylphosphono group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydro-furylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or pyrazolyl group), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,or a group of the formula -Z³-R⁵ (wherein Z³ is —O—, —S—, —SO—, —SO₂— ora group of the formula —N(R⁶)— (wherein R⁶ is a hydrogen atom, a C₁-C₆alkylcarbonyl group a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,a phenyl C₁-C₄ alkoxycarbonyl group, or a substituted phenyl C₁-C₄alkoxycarbonyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group); and R⁵ is a hydrogen atom, a C₁-C₆alkyl group, a halo C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group and a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenyl C₁-C₄alkyl group, a substituted phenyl C₁-C₄ alkyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy. group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), or a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group); and lis an integer of 1 to 4); further, R¹ and R may form a 4 to 7 memberedring by combining to each other, in which the ring may contain the sameor different 1 to 3 hetero atoms selected from the group consisting ofoxygen atom, sulfur atom and nitrogen atom; X¹ and X² may be the same ordifferent and are each a halogen atom, a cyano group, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; further, X¹and X² may form a condensed ring (which means naphthalene,tetrahydronaphthalene, indene, indane, quinoline, quinazoline, chroman,isochroman, indole, indoline, benzodioxane, benzodioxole, benzofuran,dihydrobenzofuran, benzothiophene, dihydrobenzothiophene, benzoxazole,benzothiazole, benzimidazole or indazole) by combining to each other,and said condensed ring may have at least one substituent, which is thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkyl sulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), and a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; Y is thesame or different, and are each a hydrogen atom, a halogen atom, a cyanogroup, a nitro group, a halo-C₃-C₆ cycloalkyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedabove), a substituted heterocyclic group (wherein the heterocyclic groupis the same as defined above) having at least one substituent which maybe the same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, or a group of -A²-R⁷ (wherein A² is —O—, —S—, —SO—,—SO₂—, —C(═O)—, —C(═NOR )— (wherein R⁸ is a hydrogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆alkenyl group, a C₃-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, aphenyl-C₁-C₄ alkyl group, or a substituted phenyl-C₁-C₄ alkyl grouphaving at least one substituent, in the phenyl ring, which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonylgroup), a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, a C₂-C₆alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylenegroup or a halo-C₃-C₆ alkynylene group; (1) when A² is —O—, —S—, —SO— or—SO₂—, then R⁷ is a halo-C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkenyl group, a phenyl group, a substituted phenyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group,a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), a substituted heterocyclicgroup (wherein the heterocyclic group is the same as defined above)having at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or a group ofthe formula -A³-R⁹ (wherein A³ is a C₁-C₆ alkylene group, a halo-C₁-C₆alkylene group, a C₃-C₆ alkenylene group, a halo-C₃-C₆ alkenylene group,a C₃-C₆ alkynylene group or a halo-C₃-C₆ alkynylene group; R⁹ is ahydrogen atom, a halogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, or a group of the formula -A⁴-R¹⁰ (wherein A⁴ is—O—, —S—, —SO₂—, —SO₂— or —C(═O)—, and R¹⁰ is a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), or a substituted heterocyclic group (wherein theheterocyclic group is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group)); (2) when A² is —C(═O)— or a group ofthe formula —C(═NOR⁸)— (wherein R⁸ is the same as defined the above),then R⁷ is a C₁-C₆ alkyl group, a halo C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxy group, a C₁-C₆ alkylthiogroup, a mono-C₁-C₆ alkylamino group, a di-C₁-C₆ alkylamino group whichmay be the same or different, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenylaminogroup, a substituted phenylamino group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group,and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), or a substituted heterocyclic group (whereinthe heterocyclic group is the same as defined the above) having at leastone substituent which may be the same or different and is selected fromthe group consisting of a halogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group,a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, (3) when A² isa C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, C₂-C₆ alkenylenegroup, a halo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or ahalo-C₃-C₆ alkynylene group, then R⁷ is a hydrogen atom, a halogen atom,a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined the above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or agroup of the formula -A⁵-R¹² (wherein A⁵ is —O—, —S—, —SO— or —SO₂—; andR¹² is a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), a substituted heterocyclic group (wherein the heterocyclicgroup is the same as defined above) having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group, or a group of the formula -A⁶-R¹⁴(wherein A⁶ is a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group, or a halo-C₃-C₆ alkynylene group; and R¹⁴ is ahydrogen atom, a halogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, aC₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a phenoxy group, a substituted phenoxy group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenylthiogroup, a substituted phenylthio group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆- alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), or a substituted heterocyclic group (whereinthe heterocyclic ring is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group))); and m is an integer of 1 to 5;further, Y may form a condensed ring (which is the same as definedabove) by combining together with the adjacent carbon atoms in thephenyl ring, said condensed ring may have at least one substituent,which is the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), and a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; Z¹ andZ² are each an oxygen atom or a sulfur atom}.
 5. The phthalic aciddiamide derivative according to claim 4, represented by the generalformula (I-3),

{wherein, R¹, R² and R³ may be the same or different, and are each ahydrogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl groupor a group of the formula -A¹-Q_(l) (wherein, A¹ is a C₁-C₈ alkylenegroup, a C₃-C₆ alkenylene group or a C₃-C₆ alkynylene group; Q is ahydrogen atom, a halogen atom, a cyano group, a nitro group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a di-C₁-C₆alkoxyphosphoryl group which may be the same or different, a di-C₁-C₆alkoxythiophosphoryl group which may be the same or different, adiphenylphosphino group, a diphenyl-phosphono group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydrofurylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or pyrazolyl group), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,or a group of the formula -Z³ -R⁵ (wherein Z³ is —O—, —S—, —SO₂— or agroup of the formula —N(R⁶)— (wherein R⁶ is a hydrogen atom, a C₁-C₆alkylcarbonyl group a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,a phenyl C₁-C₄ alkoxycarbonyl group, or a substituted phenyl C₁-C₄alkoxycarbonyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group,); and R⁵ is a hydrogen atom, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenyl C₁-C₄alkyl group, a substituted phenyl C₁-C₄ alkyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), or a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group); and lis an integer of 1 to 4); further, R¹ and R² may form a 4 to 7 memberedring by combining to each other, in which the ring may contain the sameor different 1 to 3 hetero atoms selected from the group consisting ofoxygen atom, sulfur atom and nitrogen atom; X¹ and X² may be the same ordifferent and are each a halogen atom, a cyano group, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; further, X¹and X² may form a condensed ring (which means naphthalene,tetrahydronaphthalene, indene, indane, quinoline, quinazoline, chroman,isochroman, indole, indoline, benzodioxane, benzodioxole, benzofuran,dihydrobenzofuran, benzothiophene, dihydrobenzothiophene, benzoxazole,benzothiazole, benzimidazole or indazole) by combining to each other,and said condensed ring may have at least one substituent, which is thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (which is thesame as defined above), and a substituted heterocyclic group (whereinthe heterocyclic group is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group; Y¹ and Y³ may be the same ordifferent, and are each a hydrogen atom, a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aphenoxy group, a substituted phenoxy group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group, a pyridyloxy group, or a substitutedpyridyloxy group having at least one substituent which may be the sameor different and is selected from the group consisting of a halogenatom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, Y² is a hydrogen atom, a halogen atom, a halo-C₃-C₆cycloalkyl group or a group of the formula -A²-R⁷ (wherein A² —O—, —S—,—SO—, —SO₂—, a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group, or a halo-C₃-C₆ alkynylene group, and (1) when A² is—O—,—S—, —SO— or —SO₂—, then R⁷ is a halo-C₃-C₆ cycloalkyl group, asubstituted phenyl group having at least one substituent, which is thesame or different and is selected from the group consisting of a halogenatom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-CC₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, a substituted pyridyloxy group having at least onesubstituent, which is the same or different and is selected from thegroup consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, or a group ofthe formula -A³-R⁹ (wherein A³ is a halo-C₁-C₆ alkylene group, or ahalo-C₃-C₆ alkenylene group; and R⁹ is a hydrogen atom, a halogen atom,a halo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenylgroup having at least one substituent, which is the same or differentand is selected from the group consisting of a halogen atom a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, ora group of the formula -A⁴-R¹⁰ (wherein A⁴ is —O—, —S—, —SO— or —SO₂—;R¹⁰ is a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenylgroup, a halo-C₃-C₆ alkenyl group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a phenyl group, or a substituted phenylgroup having at least one substituent, which is the same or differentand is selected from the group consisting of a halogen atom a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group)),(2) when A² is a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group, a halo-C₃-C₆ alkynylene group, then R⁷ is a hydrogenatom, a halogen atom, a halo-C₃-C₆ cycloalkyl group, a phenyl group, asubstituted phenyl group having at least one substituent, which is thesame or different and is selected from the group consisting of a halogenatom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, or a group of the formula -A⁵-R¹² (wherein A⁵ is—O—, —S—, —SO— or —SO₂—; and R¹² is a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenyl grouphaving at least one substituent, which is the same or different and isselected from the group consisting of a halogen atom, a halo-C₁-C₆ alkylgroup, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, ora group of the formula -A⁶-R¹⁴ (wherein A⁶ is a C₁-C₆ alkylene group, ahalo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, a halo-C₂-C₆alkenylene group; and R¹⁴ is a hydrogen atom, a halogen atom, ahalo-C₃-C₆ cycloalkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfonyl group, a phenyl group, a substituted phenyl group havingat least one substituent, which is the same or different and is selectedfrom the group consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenoxygroup, a substituted phenoxy group having at least one substituent,which is the same or different and is selected from the group consistingof a halogen atom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group,a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and ahalo-C₁-C₆ alkylsulfonyl group, a phenylthio group, or a substitutedphenylthio group having at least one substituent, which is the same ordifferent and is selected from the group consisting of a halogen atom, ahalo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group)); further, Y¹ and Y² may form a condensed ring (thecondensed ring is the same as defined above) by combining to each othertogether with Y³, and said condensed ring may have at least onesubstituent, which is the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a phenyl group, and a substituted phenylgroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; Z¹ andZ² are each an oxygen atom or a sulfur atom}.
 6. An agricultural andhorticultural insecticides, which is characterized by containing, as theeffective ingredient, a phthalic acid diamide derivative represented bythe general formula (I),

wherein R¹, R² and R³ may be the same or different, and are each ahydrogen atom, a cyano group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₃-C₆ cycloalkenyl group, a halo-C₃-C₆ cycloalkenylgroup or a group of the formula -A¹-Q_(l) (wherein A¹ is —O—,—S—, —SO₂—,—C(═O)—, a group of the formula —N(R⁴)— (wherein R⁴ is a C₁-C₆alkyl-carbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, or a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different, and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different), a C₁-C₈ alkylene group, a C₃-C₆ alkenylene groupor a C₃-C₆ alkynylene group; (1) when A¹ is —O— or a group of theformula —N(R⁴)— (wherein R⁴ is the same as defined above), then Q is ahydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆alkenyl group, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkyl sulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aphenyl-C₁-C₄ alkyl group or a substituted phenyl-C₁-C₄ alkyl grouphaving at least one substituent, in the phenyl ring, which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different; (2) when A¹ is —S—, —SO₂— or —C(═O)—, then Q is aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a C₁-C₆ alkoxy group, amono-C₁-C₆ alkylamino group, a di-C₁-C₆ alkylamino group which may bethe same or different, a C₁-C₆ alkoxycarbonylamino group, a C₁-C₆alkoxycarbonyl-C₁-C₆ alkylamino group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenylamino group, a substituted phenylaminogroup having at least one substituent, in the phenyl ring, which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-CC₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkyl-sulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydrofurylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or a pyrazolyl group), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C ₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, (3) when A¹ is a C₁-C₈ alkylene group, a C₃-C₆alkenylene group or a C₃-C₆ alkynylene group, then Q is a hydrogen atom,a halogen atom, a cyano group, a nitro group, a halo-C₁-C₆ alkyl group,a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkoxycarbonyl group, a di-C₁-C₆ alkoxyphosphoryl group which may be thesame or different, a di-C₁-C₆ alkoxythiophosphoryl group which may bethe same or different, a diphenylphosphino group, a diphenylphosphonogroup, a phenyl group, a substituted phenyl group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -Z³-R⁵ (wherein Z³ is—O—, —S—, —SO—, —SO₂— or a group of the formula —N(R⁶)— (wherein R⁶ is ahydrogen atom, a C₁-C₆ alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonylgroup, a C₁-C₆ alkoxycarbonyl group, a phenylcarbonyl group, asubstituted phenylcarbonyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenyl C₁-C₄ alkoxycarbonyl group, or asubstituted phenyl C₁-C₄ alkoxycarbonyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different); and R⁵ is a hydrogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenylgroup, a C₃-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₃-C₆cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkylcarbonylgroup, a halo C₁-C₆ alkylcarbonyl group, a C₁-C₆ alkoxycarbonyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₃-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a phenylC₁-C₄ alkyl group, a substituted phenyl C₁-C₄ alkyl group having atleast one substituent, in the phenyl ring, which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-CC₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),or a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined above) having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different); l is an integer of 1 to 4); further, R¹ and R²may form a 4 to 7 membered ring by combining to each other, in which thering may contain the same or different 1 to 3 hetero atoms selected fromthe group consisting of oxygen atom, sulfur atom and nitrogen atom; Xmay be the same or different, and is a hydrogen atom, a halogen atom, acyano group, a nitro group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a phenyl group, a substituted phenyl group having atleast one substituents which may be the same or different and isselected from the group consisting of a halogen atom, a cyano group, anitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkyl-sulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a naphthyl group, a substituted naphthyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-CC₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined the above), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A²-R⁷ (wherein A² is—O—, —S—, —SO—, —SO₂—, —C(═O)—, —C(═NOR⁸)— (wherein R⁸ is a hydrogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenylgroup, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a C₃-C₆cycloalkyl group, a phenyl-C₁-C₄ alkyl group, or a substitutedphenyl-C₁-C₄ alkyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different), a C₁-C₆alkylene group, a halo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, ahalo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆alkynylene group; (1) when A² is —O—, —S—, —SO— or —SO₂—, then R⁷ is ahydrogen atom, a C₁-C₆ alkyl group, a halo C₁-C₆ alkyl group, a C₃-C₆alkenyl group, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, ahalo-C₃-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₃-C₆ cycloalkenyl group, a halo-C₃-C₆ cycloalkenylgroup, a di-C₁-C₆ alkoxyphosphoryl group which may be the same ordifferent, a di-C₁-C₆ alkoxythiophosphoryl group which may be the sameor different, a phenyl group, a substituted phenyl group having at leastone substituent which may be the same or different and is selected fromthe group consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituents which may be the same ordifferent and are selected from the group consisting of a halogen atom,a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A³-R⁹ (wherein A³ is—C(═O)—, —SO₂—, a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₃-C₆alkynylene group, or a halo-C₃-C₆ alkynylene group, (i) when A³ is—C(═O)— or —SO₂—, then R⁹ is a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a mono-C₁-C₆ alkylamino group, a di-C₁-C₆alkylamino group which may be the same or different, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-CC₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),or a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined the above) having at least one substituent which maybe the same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, (ii) when A³ is a C₁-C₆ alkylene group, ahalo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, a halo-C₂-C₆alkenylene group, a C₃-C₆ alkynylene group or a halo-C₃-C₆ alkynylenegroup, then R⁹ is a hydrogen atom, a halogen atom, a cyano group, aC₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a cyano group, anitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, or a group of the formula -A⁴-R¹⁰ (wherein A⁴ is —O—,—S—,—SO—, —SO₂—, —C(═O)—, or a group of the formula —N(R¹¹)— (wherein R¹¹ isa hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆alkenyl group, a C₃-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),or a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined above) having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different); and R¹⁰ is a hydrogen atom, a C₁-C₆ alkyl group,a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenylgroup, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynyl group, a C₃-C₆cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₃-C₆ cycloalkenylgroup, a halo-C₃-C₆ cycloalkenyl group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined theabove), or a substituted heterocyclic group (wherein the heterocyclicgroup is the same as defined the above) having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different)); (2) whenA² is —C(═O)— or a group of the formula —C(═NOR⁸)— (wherein R⁸ is thesame as defined above), then R⁷ is a C₁-C₆ alkyl group, a halo C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₃-C₆cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxy group, aC₁-C₆ alkylthio group, a mono-C₁-C₆ alkylamino group, a di-C₁-C₆alkylamino group which may be the same or different, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a phenylamino group, a substituted phenylaminogroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, a cyanogroup, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group,a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a naphthyl group, a substituted naphthyl group having oneor more substituents which may be the same or different and are selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, (3) when A² is a C₁-C₆ alkylene group, ahalo-C₁-C₆ alkylene group, C₂-C₆ alkenylene group, a halo-C₂-C₆alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆ alkynylenegroup, then R⁷ is a hydrogen atom, a halogen atom, a C₃-C₆ cycloalkylgroup, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A⁵-R¹² (wherein A⁵ is—O—,—S—, —SO—, —SO₂— or a group of the formula —N(R¹³)— (wherein R¹³ isa hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a C₂-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),or a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined above) having at least one substituents which may bethe same or different and are selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₁-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup , a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different); and R¹² is a hydrogen atom, a C₃-C₆ cycloalkylgroup, a halo-C₃-C₆ cycloalkyl group, a phenyl group, a substitutedphenyl group having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, acyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₃-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),a substituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituents which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A⁶-R¹⁴ (wherein A⁶ is—C(═O)—, —SO₂—, a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group or a halo-C₃-C₆ alkynylene group; (i) when A⁶ is—C(═O)— or —SO₂—, then R¹⁴ is a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a phenyl group, a substituted phenyl group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-CC₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined the above) having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different; (ii) when A⁶ is a C₁-C₆ alkylene group, ahalo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, a halo-C₂-C₆alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆ alkynylenegroup, then R¹⁴ is a hydrogen atom, a halogen atom, a cyano group, aC₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, aC₁-C₆ alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and areselected from the group consisting of a halogen atom, a cyano group, anitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a phenoxy group, a substituted phenoxy group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-CC₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aphenylthio group, a substituted phenylthio group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a. halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆-alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different))); n is an integer of 1 to 4; further, X may forma condensed ring (which means naphthalene, tetrahydronaphthalene,indene, indane, quinoline, quinazoline, chroman, isochroman, indole,indoline, benzodioxane, benzodioxole, benzofuran, dihydrobenzofuran,benzothiophene, dihydrobenzothiophene, benzoxazole, benzothiazole,benzimidazole or indazole), by combining together with the adjacentcarbon atoms in the phenyl ring, and said condensed ring may have atleast one substituents, which may be the same or different, and selectedfrom the group consisting of a halogen atom, a cyano group, a nitrogroup, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenylgroup, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group, adi-C₁-C₆ alkylamino group which may be the same or different, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),and a substituted heterocyclic group (wherein the heterocyclic group isthe same as defined above) having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkyl-sulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and a di-C₁-C₆alkylamino group which may be the same or different; Y is the same ordifferent, and is a hydrogen atom, a halogen atom, a cyano group, anitro group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, adi-C₁-C₆ alkoxyphosphoryl group which may be the same or different, adi-C₁-C₆ alkoxythiophosphoryl group which may be the same or different,a phenyl group, a substituted phenyl group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a cyano group, a nitro group, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, a naphthylgroup, a substituted naphthyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group and adi-C₁-C₆ alkylamino group which may be the same or different, aheterocyclic group (which is the same as defined the above), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a cyano group, a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-CC₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-CC₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, or a group of the formula -A²-R⁷ (wherein A² andR⁷ are the same as defined above); m is an integer of 1 to 5; further, Ymay form a condensed ring (the condensed ring is the same as definedabove), by combining together with the adjacent carbon atoms in thephenyl ring, said condensed ring may have at least one substituents,which may be the same or different, and selected from the groupconsisting of a halogen atom, a cyano group, a nitro group, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, ahalo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆ alkylamino group, adi-C₁-C₆ alkylamino group which may be the same or different, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different, a naphthyl group, a substituted naphthyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a cyano group,a nitro group, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₂-C₆ alkynyl group, ahalo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxygroup, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a mono-C₁-C₆alkylamino group and a di-C₁-C₆ alkylamino group which may be the sameor different, a heterocyclic group (which is the same as defined above),and a substituted heterocyclic group (wherein said heterocyclic group isthe same as defined above) having at lease one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a cyano group, a nitro group, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₂-C₆ alkenyl group, a halo-C₂-C₆ alkenylgroup, a C₂-C₆ alkynyl group, a halo-C₂-C₆ alkynyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, amono-C₁-C₆ alkylamino group and a di-C₁-C₆ alkylamino group which may bethe same or different; Z¹ and Z² are each represents an oxygen atom or asulfur atom.
 7. The agricultural and horticultural insecticidesaccording to claim 6, wherein R¹, R² and R³ may be the same ordifferent, and are each a hydrogen atom, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, or a group of the formula -A¹-Q_(l)(wherein A¹ is a C₁-C₈ alkylene group, a C₃-C₆ alkenylene group or aC₃-C₆ alkynylene group; and Q is a hydrogen atom, a halogen atom, acyano group, a nitro group, a halo-C₁-C₆ alkyl group, a C₃-C₆ cycloalkylgroup, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, adi-C₁-C₆ alkoxyphosphoryl group which may be the same or different, adi-C₁-C₆ alkoxythiophosphoryl group which may be the same or different,a diphenylphosphino group, a diphenylphosphono group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydro-furylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or pyrazolyl group), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,or a group of the formula -Z³-R⁵ (wherein Z³ is —O—,—S—, —SO—, —SO₂— ora group of the formula —N(R⁶)— (wherein R⁶ is a hydrogen atom, a C₁-C₆alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,a phenyl C₁-C₄ alkoxycarbonyl group, or a substituted phenyl C₁-C₄alkoxycarbonyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group,); and R⁵ is a hydrogen atom, a C₁-C₆alkyl group, a halo C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkylcarbonyl group, a halo C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenyl C₁-C₄alkyl group, a substituted phenyl C₁-C₄ alkyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), or a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group); and lis an integer of 1 to 4), R¹ and R² may form a 4 to 7 membered ring bycombining to each other, in which the ring may contain the same ordifferent 1 to 3 hetero atoms selected from the group consisting ofoxygen atom, sulfur atom and nitrogen atom; X may be the same ordifferent, and is a hydrogen atom, a halogen atom, a cyano group, anitro group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, aphenyl group, a substituted phenyl group having at least onesubstituents which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), a substituted heterocyclic group (whereinthe heterocyclic group is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group,and a halo-C₁-C₆ alkylsulfonyl group, or a group of the formula -A²-R⁷(wherein A² is —O—,—S—, —SO—, 13 SO₂—, —C(═O)—, —C(═NOR⁸)— (wherein R⁸is a hydrogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₃-C₆ alkenyl group, a halo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group,a C₃-C₆ cycloalkyl group, a phenyl-C₁-C₄ alkyl group, or a substitutedphenyl-C₁-C₄ alkyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group), a C₁-C₆ alkylene group, a halo-C₁-C₆alkylene group, a C₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group,a C₂-C₆ alkynylene group or a halo-C₃-C₆ alkynylene group; (1) when A²is —O—, —S—, —SO— or —SO₂—, then R⁷ is a halo-C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkenyl group, a phenyl group, a substituted phenylgroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, aheterocyclic group (which is the same as defined above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or agroup of the formula -A³-R⁹ (wherein A³ is a C₁-C₆ alkylene group, ahalo-C₁-C₆ alkylene group, a C₃-C₆ alkenylene group, a halo-C₃-C₆alkenylene group, a C₃-C₆ alkynylene group or a halo-C₃-C₆ alkynylenegroup; R⁹ is a hydrogen atom, a halogen atom, a C₃-C₆ cycloalkyl group,a halo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, or a group of the formula -A⁴-R¹⁰ (wherein A⁴ is—O—,—S—, —SO—, —SO₂— or —C(═O)—, and R¹⁰ is a C₁-C₆ alkyl group, ahalo-CC₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), or a substituted heterocyclic group (wherein theheterocyclic group is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group)); (2) when A² is —C(═O)— or a group ofthe formula —C(═NOR⁸)— (wherein R⁸ is the same as defined the above),then R⁷ is a C₁-C₆ alkyl group, a halo C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxy group, a C₁-C₆ alkylthiogroup, a mono-C₁-C₆ alkylamino group, a di-C₁-C₆ alkylamino group whichmay be the same or different, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenylaminogroup, a substituted phenylamino group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group,and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), or a substituted heterocyclic group (whereinthe heterocyclic group is the same as defined the above) having at leastone substituent which may be the same or different and is selected fromthe group consisting of a halogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group,a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, (3) when A² isa C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, C₂-C₆ alkenylenegroup, a halo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or ahalo-C₃-C₆ alkynylene group, then R⁷ is a hydrogen atom, a halogen atom,a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined the above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or agroup of the formula -A⁵-R¹² (wherein A⁵ is —O—,—S—, —SO— or —SO₂—; andR¹² is a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), a substituted heterocyclic group (wherein the heterocyclicgroup is the same as defined above) having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkyl-sulfonyl groupand a halo-C₁-C₆ alkylsulfonyl group, or a group of the formula -A⁶-R¹⁴(wherein A⁶ is a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group, or a halo-C₃-C₆ alkynylene group; and R¹⁴ is ahydrogen atom, a halogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, aC₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a phenoxy group, a substituted phenoxy group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenylthiogroup, a substituted phenylthio group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆- alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), or a substituted heterocyclic group (whereinthe heterocyclic ring is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group))); n is an integer of 1 to 4; further,X may form a condensed ring (which means naphthalene,tetrahydronaphthalene, indene, indane, quinoline, quinazoline, chroman,isochroman, indole, indoline, benzodioxane, benzodioxole, benzofuran,dihydrobenzofuran, benzothiophene, dihydrobenzothiophene, benzoxazole,benzothiazole, benzimidazole or indazole), by combining together withthe adjacent carbon atoms in the phenyl ring, said condensed ring mayhave at least one substituent, which may be the same or different, andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedabove), and a substituted heterocyclic group (wherein the heterocyclicgroup is the same as defined above) having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group; Y is the same or different, and is ahydrogen atom, a halogen atom, a cyano group, a nitro group, ahalo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), a substituted heterocyclicgroup (wherein the heterocyclic group is the same as defined above)having at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or a group ofthe formula -A²-R⁷ (wherein A² and R⁷ are the same as defined above); mis an integer of 1 to 5; further, Y may form a condensed ring (the sameas defined above), by combining together with the adjacent carbon atomsin the phenyl ring, said condensed ring may have at least onesubstituent, which may be the same or different, and is selected fromthe group consisting of a halogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group,a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), and a substituted heterocyclic group (wherein saidheterocyclic group is the same as defined the above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group; and Z¹ and Z² are each represents anoxygen atom or a sulfur atom.
 8. The agricultural and horticulturalinsecticides according to claim 7, containing as the effectiveingredient, a phthalic acid diamide derivative represented by thegeneral formula (I-1),

{wherein, R¹, R² and R³ may be the same or different, and are each ahydrogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl groupor a group of the formula -A¹-Q_(l) (wherein, A¹ is a C₁-C₈ alkylenegroup, a C₃-C₆ alkenylene group or a C₃-C₆ alkynylene group; Q is ahydrogen atom, a halogen atom, a cyano group, a nitro group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a di-C₁-C₆alkoxyphosphoryl group which may be the same or different, a di-C₁-C₆alkoxythiophosphoryl group which may be the same or different, adiphenylphosphino group, a diphenylphosphono group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydrofurylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or pyrazolyl group), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,or a group of the formula -Z³-R⁵ (wherein Z³ is —O—,—S—, —SO—, —SO₂— ora group of the formula —N(R⁶)— (wherein R⁶ is a hydrogen atom, a C₁-C₆alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,a phenyl C₁-C₄ alkoxycarbonyl group, or a substituted phenyl C₁-C₄alkoxycarbonyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group); and R⁵ is a hydrogen atom, a C₁-C₆alkyl group, a halo C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkylcarbonyl group, a halo C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenyl C₁-C₄alkyl group, a substituted phenyl C₁-C₄ alkyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), or a substitutedheterocyclic group (wherein the heterocyclic ring is the same as definedabove) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group); and lis an integer of 1 to 4); further, R¹ and R² may form a 4 to 7 memberedring by combining to each other, in which the ring may contain the sameor different 1 to 3 hetero atoms selected from the group consisting ofoxygen atom, sulfur atom and nitrogen atom; X is a hydrogen atom or anitro group; Y¹ and Y³ may be the same or different and are each ahydrogen atom, a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a phenoxy group, asubstituted phenoxy group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a pyridyloxy group, a substituted pyridyloxy grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group; Y²is a halo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenylgroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, ahalo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedabove), a substituted heterocyclic group (wherein the heterocyclic groupis the same as defined above) having at least one substituent which maybe the same or different and is selected from the group consisting of ahalogen atom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and ahalo-C₁-C₆ alkylsulfonyl group, or a group of the formula -A²-R⁷(wherein A² is —O—, —S—, —SO—, —SO₂—, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group or a halo-C₃-C₆ alkynylene group and, (1) when A² is—O—, —S—, —SO— or —SO₂—, then R⁷ is a halo-C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkenyl group, a substituted phenyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), a substituted heterocyclicgroup (wherein the heterocyclic ring is the same as defined above)having at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, ora group of the formula -A³-R⁹ (wherein A³ is a halo-C₁-C₆ alkylenegroup, a halo-C₃-C₆ alkenylene group, a C₃-C₆ alkynylene group or ahalo-C₃-C₆ alkynylene group; and R⁹ is a hydrogen atom, a halogen atom,a phenyl group, a substituted phenyl group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group or a group ofthe formula -A⁴-R¹⁰ (wherein A⁴ is —O—,—S— or —SO₂—; and R¹⁰ is a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a phenyl group, a substituted phenyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₃-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), a substituted heterocyclicgroup (wherein the heterocyclic ring is the same as defined above)having at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group));(2) when A² is a halo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, ahalo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or a halo-C₃-C₆alkynylene group, then R⁷ is a hydrogen atom, a halogen atom, ahalo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-c6 alkylsulfonyl group, ora group of the formula -A⁵-R¹² (wherein A⁵ is —O—, —S—, —SO— or —SO₂—;and R¹² is a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylsulfinylgroup and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (whichis the same as defined the above), a substituted heterocyclic group(wherein the heterocyclic group is the same as defined above) having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group; or a group ofthe formula -A⁶-R¹⁴ (wherein A⁶ is a C₁-C₆ alkylene group, a halo-C₁-C₆alkylene group, a C₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group,a C₂-C₆ alkynylene group or a halo-C₃-C₆ alkynylene group; and R¹⁴ is ahydrogen atom, a halogen atom, a halo-C₃-C₆ cycloalkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and ahalo-C₁-C₆ alkylsulfonyl group, a phenoxy group, a substituted phenoxygroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, ahalo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, a phenylthio group, a substituted phenylthio grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆-alkylsulfonyl group, aheterocyclic group (which is the same as defined the above), or asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group))); further, Y¹ and Y² may form a condensed ring(which means naphthalene, tetrahydronaphthalene, indene, indane,quinoline, quinazoline, chroman, isochroman, indole, indoline,benzodioxane, benzodioxole, benzofuran, dihydrobenzofuran,benzothiophene, dihydrobenzothiophene, benzoxazole, benzothiazole,benzimidazole or indazole) by combining to each other together with theadjacent Y³, said condensed ring may have at least one substituent,which is the same or different, selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined the above), and a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; and Z¹and Z² are each an oxygen atom or a sulfur atom}.
 9. The agriculturaland horticultural insecticides according to claim 7, containing as theactive ingredient, a phthalic acid diamide derivative represented by thegeneral formula (I-2),

{wherein, R¹, R² and R³ may be the same or different, and are each ahydrogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl groupor a group of the formula -A¹-Q_(l) (wherein, A¹ is a C₁-C₈ alkylenegroup, a C₃-C₆ alkenylene group or a C₃-C₆ alkynylene group; Q is ahydrogen atom, a halogen atom, a cyano group, a nitro group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a di-C₁-C₆alkoxyphosphoryl group which may be the same or different, a di-C₁-C₆alkoxythiophosphoryl group which may be the same or different, adiphenylphosphino group, a diphenylphosphono group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydrofurylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or pyrazolyl group), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,or a group of the formula -Z³-R⁵ (wherein Z³ is —O—, —S—, —SO—, —SO₂— ora group of the formula —N(R⁶)— (wherein R⁶ is a hydrogen atom, a C₁-C₆alkylcarbonyl group a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,a phenyl C₁-C₄ alkoxycarbonyl group, or a substituted phenyl C₁-C₄alkoxycarbonyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group); and R⁵ is a hydrogen atom, a C₁-C₆alkyl group, a halo C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group and a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenyl C₁-C₄alkyl group, a substituted phenyl C₁-C₄ alkyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), or a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₃-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group); and tis an integer of 1 to 4); further, R¹ and R² may form a 4 to 7 memberedring by combining to each other, in which the ring may contain the sameor different 1 to 3 hetero atoms selected from the group consisting ofoxygen atom, sulfur atom and nitrogen atom; X¹ and X² may be the same ordifferent and are each a halogen atom, a cyano group, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; further, X¹and X² may form a condensed ring (which means naphthalene,tetrahydronaphthalene, indene, indane, quinoline, quinazoline, chroman,isochroman, indole, indoline, benzodioxane, benzodioxole, benzofuran,dihydrobenzofuran, benzothiophene, dihydrobenzothiophene, benzoxazole,benzothiazole, benzimidazole or indazole) by combining to each other,and said condensed ring may have at least one substituent, which is thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkyl sulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), and a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; Y is thesame or different, and are each a hydrogen atom, a halogen atom, a cyanogroup, a nitro group, a halo-C₃-C₆ cycloalkyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedabove), a substituted heterocyclic group (wherein the heterocyclic groupis the same as defined above) having at least one substituent which maybe the same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, or a group of -A²-R⁷ (wherein A² is —O—, —S—, —SO—,—SO₂—, —C(═O)—, —C(═NOR⁸)— (wherein R⁸ is a hydrogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆alkenyl group, a C₃-C₆ alkynyl group, a C₃-C₆ cycloalkyl group, aphenyl-C₁-C₄ alkyl group, or a substituted phenyl-C₁-C₄ alkyl grouphaving at least one substituent, in the phenyl ring, which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonylgroup), a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, a C₂-C₆alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylenegroup or a halo-C₃-C₆ alkynylene group; (1) when A² is —O—,—S—, —SO— or—SO₂—, then R⁷ is a halo-C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkenyl group, a phenyl group, a substituted phenyl group having atleast one substituent which may be the same or different and is selectedfrom the group consisting of a halogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group,a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), a substituted heterocyclicgroup (wherein the heterocyclic group is the same as defined above)having at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or a group ofthe formula -A³-R⁹ (wherein A³ is a C₁-C₆ alkylene group, a halo-C₁-C₆alkylene group, a C₃-C₆ alkenylene group, a halo-C₃-C₆ alkenylene group,a C₃-C₆ alkynylene group or a halo-C₃-C₆ alkynylene group; R⁹ is ahydrogen atom, a halogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, or a group of the formula -A⁴-R¹⁰ (wherein A⁴ is—O—, —S—, —SO—, —SO₂— or —C(═O)—, and R¹⁰ is a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, a halo-C₃-C₆ alkenylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), or a substituted heterocyclic group (wherein theheterocyclic group is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group)); (2) when A² is —C(═O)— or a group ofthe formula —C(═NOR⁸)— (wherein R⁸ is the same as defined the above),then R⁷ is a C₁-C₆ alkyl group, a halo C₁-C₆ alkyl group, a C₂-C₆alkenyl group, a halo-C₂-C₆ alkenyl group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a C₁-C₆ alkoxy group, a C₁-C₆ alkylthiogroup, a mono-C₁-C₆ alkylamino group, a di-C₁-C₆ alkylamino group whichmay be the same or different, a phenyl group, a substituted phenyl grouphaving at least one substituent which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenylaminogroup, a substituted phenylamino group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group,and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), or a substituted heterocyclic group (whereinthe heterocyclic group is the same as defined the above) having at leastone substituent which may be the same or different and is selected fromthe group consisting of a halogen atom, a C₁-C₆ alkyl group, ahalo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group,a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, (3) when A² isa C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, C₂-C₆ alkenylenegroup, a halo-C₂-C₆ alkenylene group, a C₂-C₆ alkynylene group or ahalo-C₃-C₆ alkynylene group, then R⁷ is a hydrogen atom, a halogen atom,a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined the above), a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, or agroup of the formula -A⁵-R¹² (wherein A⁵ is —O—,—S—, —SO— or —SO₂—; andR¹² is a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a phenylgroup, a substituted phenyl group having at least one substituent whichmay be the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which is the same as definedthe above), a substituted heterocyclic group (wherein the heterocyclicgroup is the same as defined above) having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group, or a group of the formula -A⁶-R¹⁴(wherein A⁶ is a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group, or a halo-C₃-C₆ alkynylene group; and R¹⁴ is ahydrogen atom, a halogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, aC₁-C₆ alkylthio group, a halo-CC₁-C₆ alkylthio group, a C₁-C₆alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a phenoxy group, a substituted phenoxy group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenylthiogroup, a substituted phenylthio group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆- alkylsulfonyl group, a heterocyclic group (which is thesame as defined the above), or a substituted heterocyclic group (whereinthe heterocyclic ring is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group))); and m is an integer of 1 to 5;further, Y may form-a condensed ring (which is the same as definedabove) by combining together with the adjacent carbon atoms in thephenyl ring, said condensed ring may have at least one substituent,which is the same or different and is selected from the group consistingof a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, aC₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group,a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆alkylsulfonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), and a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₃-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; Z¹ andZ² are each an oxygen atom or a sulfur atom}.
 10. The agricultural andhorticultural insecticides according to claim 9, containing as theeffective ingredient, a phthalic acid diamide derivative represented bythe general formula (I-3),

{wherein, R¹, R² and R³ may be the same or different, and are each ahydrogen atom, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl groupor a group of the formula -A¹-Q_(l) (wherein, A¹ is a C₁-C₈ alkylenegroup, a C₃-C₆ alkenylene group or a C₃-C₆ alkynylene group; Q is ahydrogen atom, a halogen atom, a cyano group, a nitro group, ahalo-C₁-C₆ alkyl group, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆cycloalkyl group, a C₁-C₆ alkoxycarbonyl group, a di-C₁-C₆alkoxyphosphoryl group which may be the same or different, a di-C₁-C₆alkoxythiophosphoryl group which may be the same or different, adiphenylphosphino group, a diphenylphosphono group, a phenyl group, asubstituted phenyl group having at least one substituent which may bethe same or different and is selected from the group consisting of ahalogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆alkylsulfonyl group, a heterocyclic group (which means pyridyl group,pyridine-N-oxide group, pyrimidinyl group, furyl group, tetrahydrofurylgroup, thienyl group, tetrahydrothienyl group, tetrahydropyranyl group,tetrahydrothiopyranyl group, oxazolyl group, isoxazolyl group,oxadiazolyl group, thiazolyl group, isothiazolyl group, thiadiazolylgroup, imidazolyl group, triazolyl group or pyrazolyl group), asubstituted heterocyclic group (wherein the heterocyclic group is thesame as defined above) having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and halo-C₁-C₆ alkylsulfonyl group,or a group of the formula -Z³-R⁵ (wherein Z³ is —O—, —S—, —SO—, —SO₂— ora group of the formula —N(R⁶)— (wherein R⁶ is a hydrogen atom, a C₁-C₆alkylcarbonyl group a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenylcarbonyl group, a substitutedphenylcarbonyl group having at least one substituent which may be thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group,a phenyl C₁-C₄ alkoxycarbonyl group, or a substituted phenyl C₁-C₄alkoxycarbonyl group having at least one substituent, in the phenylring, which may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group); and R⁵ is a hydrogen atom, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenyl group, ahalo-C₃-C₆ alkenyl group, a C₃-C₆ alkynyl group, a halo-C₃-C₆ alkynylgroup, a C₃-C₆ cycloalkyl group, a halo-C₃-C₆ cycloalkyl group, a C₁-C₆alkylcarbonyl group, a halo-C₁-C₆ alkylcarbonyl group, a C₁-C₆alkoxycarbonyl group, a phenyl group, a substituted phenyl group havingat least one substituent which may be the same or different and isselected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenyl C₁-C₄alkyl group, a substituted phenyl C₁-C₄ alkyl group having at least onesubstituent, in the phenyl ring, which may be the same or different andis selected from the group consisting of a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group, a heterocyclicgroup (which is the same as defined above), or a substitutedheterocyclic group (wherein the heterocyclic group is the same asdefined above) having at least one substituent which may be the same ordifferent and is selected from the group consisting of a halogen atom, aC₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group); and lis an integer of 1 to 4); further, R¹ and R² may form a 4 to 7 memberedring by combining to each other, in which the ring may contain the sameor different 1 to 3 hetero atoms selected from the group consisting ofoxygen atom, sulfur atom and nitrogen atom; X¹ and X² may be the same ordifferent and are each a halogen atom, a cyano group, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aC₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkyl-sulfinyl group, a C₁-C₆alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; further, X¹and X² may form a condensed ring (which means naphthalene,tetrahydronaphthalene, indene, indane, quinoline, quinazoline, chroman,isochroman, indole, indoline, benzodioxane, benzodioxole, benzofuran,dihydrobenzofuran, benzothiophene, dihydrobenzothiophene, benzoxazole,benzothiazole, benzimidazole or indazole) by combining to each other,and said condensed ring may have at least one substituent, which is thesame or different and is selected from the group consisting of a halogenatom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup, a halo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinylgroup, a C₁-C₆ alkylsulfonyl group, a halo-C₁-C₆ alkylsulfonyl group, aphenyl group, a substituted phenyl group having at least one substituentwhich may be the same or different and is selected from the groupconsisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆ alkylgroup, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group, a heterocyclic group (which is thesame as defined above), and a substituted heterocyclic group (whereinthe heterocyclic group is the same as defined above) having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group; Y¹ and Y³ may be the same ordifferent, and are each a hydrogen atom, a halogen atom, a C₁-C₆ alkylgroup, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthio group, aphenoxy group, a substituted phenoxy group having at least onesubstituent which may be the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group anda halo-C₁-C₆ alkylsulfonyl group, a pyridyloxy group, or a substitutedpyridyloxy group having at least one substituent which may be the sameor different and is selected from the group consisting of a halogenatom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, Y² is a hydrogen atom, a halogen atom, a halo-C₃-C₆cycloalkyl group or a group of the formula -A²-R⁷ (wherein A² —O—, —S—,—SO—, —SO₂—, a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group, or a halo-₃-C₆ alkynylene group, and (1) when A² is—O—, —S—, —SO— or —SO₂—, then R is a halo-C₃-C₆ cycloalkyl group, asubstituted phenyl group having at least one substituent, which is thesame or different and is selected from the group consisting of a halogenatom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, a substituted pyridyloxy group having at least onesubstituent, which is the same or different and is selected from thegroup consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, or a group ofthe formula -A³-R⁹ (wherein A³ is a halo-C₁-C₆ alkylene group, or ahalo-C₃-C₆ alkenylene group; and R⁹ is a hydrogen atom, a halogen atom,a halo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenylgroup having at least one substituent, which is the same or differentand is selected from the group consisting of a halogen atom a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, ora group of the formula -A⁴-R¹⁰ (wherein A⁴ is —O—, —S—, —SO— or —SO₂—;R¹⁰ is a C₁-C₆ alkyl group, a halo-C₁-C₆ alkyl group, a C₃-C₆ alkenylgroup, a halo-C₃-C₆ alkenyl group, a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a phenyl group, or a substituted phenylgroup having at least one substituent, which is the same or differentand is selected from the group consisting of a halogen atom a halo-C₁-C₆alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group)),(2) when A² is a C₁-C₆ alkylene group, a halo-C₁-C₆ alkylene group, aC₂-C₆ alkenylene group, a halo-C₂-C₆ alkenylene group, a C₂-C₆alkynylene group, a halo-C₃-C₆ alkynylene group, then R⁷ is a hydrogenatom, a halogen atom, a halo-C₃-C₆ cycloalkyl group, a phenyl group, asubstituted phenyl group having at least one substituent, which is thesame or different and is selected from the group consisting of a halogenatom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group, or a group of the formula -A⁶-R¹⁴ (wherein A⁵ is—O—, —S—, —SO— or —SO₂—; and R¹⁴ is a C₃-C₆ cycloalkyl group, ahalo-C₃-C₆ cycloalkyl group, a phenyl group, a substituted phenyl grouphaving at least one substituent, which is the same or different and isselected from the group consisting of a halogen atom, a halo-C₁-C₆ alkylgroup, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆ alkylthio group, ahalo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, ora group of the formula -A⁶-R¹⁴ (wherein A⁶ is a C₁-C₆ alkylene group, ahalo-C₁-C₆ alkylene group, a C₂-C₆ alkenylene group, a halo-C₂-C₆alkenylene group; and R¹⁴ is a hydrogen atom, a halogen atom, ahalo-C₃-C₆ cycloalkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆alkylsulfonyl group, a phenyl group, a substituted phenyl group havingat least one substituent, which is the same or different and is selectedfrom the group consisting of a halogen atom, a halo-C₁-C₆ alkyl group, ahalo-C₁-C₆ alkoxy group, a halo-CC₁-C₆ alkylthio group, a halo-C₁-C₆alkylsulfinyl group and a halo-C₁-C₆ alkylsulfonyl group, a phenoxygroup, a substituted phenoxy group having at least one substituent,which is the same or different and is selected from the group consistingof a halogen atom, a halo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group,a halo-C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and ahalo-C₁-C₆ alkylsulfonyl group, a phenylthio group, or a substitutedphenylthio group having at least one substituent, which is the same ordifferent and is selected from the group consisting of a halogen atom, ahalo-C₁-C₆ alkyl group, a halo-C₁-C₆ alkoxy group, a halo-C₁-C₆alkylthio group, a halo-C₁-C₆ alkylsulfinyl group and a halo-C₁-C₆alkylsulfonyl group)); further, Y¹ and Y² may form a condensed ring (thecondensed ring is the same as defined above) by combining to each othertogether with Y³, and said condensed ring may have at least onesubstituent, which is the same or different and is selected from thegroup consisting of a halogen atom, a C₁-C₆ alkyl group, a halo-C₁-C₆alkyl group, a C₁-C₆ alkoxy group, a halo-C₁-C₆ alkoxy group, a C₁-C₆alkylthio group, a halo-C₁-C₆ alkylthio group, a C₁-C₆ alkylsulfinylgroup, a halo-C₁-C₆ alkylsulfinyl group, a C₁-C₆ alkylsulfonyl group, ahalo-C₁-C₆ alkylsulfonyl group, a phenyl group, and a substituted phenylgroup having at least one substituent which may be the same or differentand is selected from the group consisting of a halogen atom, a C₁-C₆alkyl group, a halo-C₁-C₆ alkyl group, a C₁-C₆ alkoxy group, ahalo-C₁-C₆ alkoxy group, a C₁-C₆ alkylthio group, a halo-C₁-C₆ alkylthiogroup, a C₁-C₆ alkylsulfinyl group, a halo-C₁-C₆ alkylsulfinyl group, aC₁-C₆ alkylsulfonyl group and a halo-C₁-C₆ alkylsulfonyl group; Z¹ andZ² are each an oxygen atom or a sulfur atom}.
 11. A method forcontrolling undesirable insect pests for a useful crop, characterized bytreating an objective crop with an effective amount of the agriculturaland horticultural insecticides according to claim
 6. 12. Afluorine-containing aniline compound represented by the general formula(ST-I):

wherein R^(a) is a halogen atom, a C₁-C₆ alkyl group, a C₁-C₆ alkoxygroup or a trifluoromethyl group, and each of R^(b), R^(c) and R^(d) isa hydrogen atom or a C₂-C₆ perfluoroalkyl group, provided that at leastone of R^(b), R^(c) and R^(d) is not a hydrogen atom, and that R^(c) isneither a pentafluoroethyl group nor a n-heptafluoropropyl group whenR^(a) is a fluorine atom and each of R^(b) and R^(d) is a hydrogen atom.13. A fluorine-containing aniline compound according to claim 12,wherein R^(a) is a C₁-C₆ alkyl group.
 14. A fluorine-containing anilinecompound according to claim 12, wherein R^(a) is a chlorine atom or abromine atom.
 15. A fluorine-containing aniline compound according toclaim 12, wherein R^(a) is a fluorine atom, each of R^(b) and R^(d) is ahydrogen atom, and R^(c) is a heptafluoropropan-2-yl group.